Electrochemistry
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書誌事項
Electrochemistry
Chapman & Hall, c1994
2nd ed
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注記
Includes bibliographical references (p. 427-432) and indexes
内容説明・目次
内容説明
It has been fashionable to describe electrochemistry as a discipline at the interface between the branches of chemistry and many other sciences. A perusal of the table of contents will affirm that view. Electrochemistry finds applications in all branches of chemistry as well as in biology, biochemistry, and engineering; electrochemistry gives us batteries and fuel cells, electroplating and electrosynthesis, and a host of industrial and technological applications which are barely touched on in this book. However, I will maintain that electrochemistry is really a branch of physical chemistry. Electrochemistry grew out of the same tradition which gave physics the study of electricity and magnetism. The reputed founders of physical chemistry-Arrhenius, Ostwald, and van't Hoff-made many of their contributions in areas which would now be regarded as electrochemistry. With the post-World War II capture of physical chemistry by chemical physicists, electrochemists have tended to retreat into analytical chemistry, thus defining themselves out of a great tradition. G. N. Lewis defined physical chemistry as "the study of that which is interesting." I hope that the readers of this book will find that electrochemistry qualifies.
目次
- Preface
- Electrode potentials: Introduction
- Electrochemical cell thermodynamics
- Some uses of standard potentials
- Measurement of cell potentials
- Reference and indicator electrodes
- Ion-selective electrodes
- Chemical analysis by potentiometry
- Batteries and fuel cells
- References
- Problems
- The electrified interface: The electric double layer
- Some properties of colloids
- Electrokinetic pheonomena
- Eletrophoresis and related phenomena
- Electrode double layer effects
- Debye-Huckel theory
- References
- Problems
- Electrolytic conductance: Conductivity
- Conductance applications
- Diffusion
- Membrane and liquid junction potentials
- References
- Problems
- Voltammetry of reversible systems: Diffusion-limited potentials
- Experimental techniques
- A survey of electroanalytical methods
- Cyclic voltammetry
- Polarography
- Polarographic variations
- The rotating-disk electrode
- Microelectrodes
- Applications
- References
- Problems
- Mechanisms of electrode processes: Introduction
- Spectroelectrochemistry
- Steady-state voltammetry
- Chronoamperometry and chronopotentiometry
- Cyclic voltammetry
- References
- Problems
- Electron-transfer kinetics: Kinetic of electron transfer
- Current-overpotential curves
- Electron-transfer rates from voltammetry
- Faradaic impedence
- References
- Problems
- Electrolysis: Bulk electrolysis
- Analytical applications of electrolysis
- Electrosynthesis
- Industrial electrolysis processes
- Corrosion
- References
- Problems
- Appendices: Bibliography
- Symbols and units
- Electrochemical data
- Laplace transform methods
- Digital simulation methods
- Answers to selected problems
- Author index
- Subject index.
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