Chemical thermodynamics : basic theory and methods
著者
書誌事項
Chemical thermodynamics : basic theory and methods
Wiley, c1994
5th ed
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注記
"A Wiley-Interscience publication."
Includes bibliographical references and index
内容説明・目次
内容説明
Using the classical (phenomenological) approach to thermodynamics as opposed to the statistical approach, this text applies theory to chemical, biological and geological problems. The essential mathematical tools and computational techniques are reviewed. This edition contains additional problems, chapters on the thermodynamics of the electrochemical cell, Eh/pH diagrams, a revised chapter on the estimation of thermodynamic properties and treatment of the latest work in electrolyte solutions.
目次
Partial table of contents: Mathematical Preparation for Thermodynamics. Enthalpy, Enthalpy of Reaction, and Heat Capacity. Application of the First Law to Gases. The Second Law of Thermodynamics. Equilibrium and Spontaneity for Systems at Constant Temperature: The Free Energy Functions. Application of the Gibbs Free Energy Function to Some Phase Changes. The Third Law of Thermodynamics. Application of the Gibbs Free Energy Function to Chemical Changes. Thermodynamics of Systems of Variable Composition. Mixtures of Gases. The Ideal Solution. Dilute Solutions of Nonelectrolytes. Activities and Standard States for Nonelectrolytes. Calculation of Partial Molar Quantities from Experimental Data: Volume and Enthalpy. Determination of Nonelectrolyte Activities. Activity, Activity Coefficients, and Osmotic Coefficients of Strong Electrolytes. Index.
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