Spectroscopy of molecular rotation in gases and liquids

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書誌事項

Spectroscopy of molecular rotation in gases and liquids

A.I. Burshtein and S.I. Temkin

Cambridge University Press, 1994

大学図書館所蔵 件 / 全15件

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注記

Includes bibliographical references and index

内容説明・目次

内容説明

Spectroscopic studies can reveal a wealth of information about the rotational and vibrational behaviour of the constituent molecules of gases and liquids. This 1994 book reviews the fundamental concepts and important models which underpin such studies, dealing in particular with the phenomenon of spectral collapse, which accompanies the transition from rare gas to dense liquid. Throughout, discussion of the various quantum mechanical and semiclassical theories is interwoven with analysis of experimental results. These include data from optical, NMR, ESR and acoustic investigations. The book concludes with a discussion of the latest theories describing the mechanism of rotational diffusion in liquid solutions. This comprehensive review of theoretical models and techniques will be invaluable to graduate students and researchers interested in molecular dynamics and spectroscopy.

目次

  • Introduction
  • 1. Rotational relaxation
  • 2. Orientational relaxation in dense media
  • 3. Transformation of isotropic scattering spectra
  • 4. Quantum theory of spectral collapse
  • 5. Rotational relaxation. Kinetic and spectral manifestations
  • 6. Impact theory of orientational relaxation
  • 7. Rotation and libration in a fluctuating cell
  • Appendices
  • References.

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