Chiral sulfur reagents : applications in asymmetric and stereoselective synthesis
著者
書誌事項
Chiral sulfur reagents : applications in asymmetric and stereoselective synthesis
（New directions in organic and biological chemistry）
CRC Press, c1997
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注記
Includes bibliographical references and index
内容説明・目次
内容説明
Over the last three decades, more than 40 different classes of chiral (mirror-image) sulfur compounds have been described, and a number of useful procedures and applications have been developed for their use. Emphasizing modern methodologies, Chiral Sulfur Reagents demonstrates the great potential of enantionmerically pure sulfur reagents in transmitting chirality to other centers. Each chapter highlights the synthesis and synthetic uses of a particular class of chiral sulfur reagent, followed by examples of the most important experimental procedures.
目次
Structure-Chirality Relationship in Organic Sulfur Compounds
Chiral Sulfinic Acid Derivatives
Sulfinic Esters
Chiral Sulfinamides and N-Alkylidenesulfinamides
Chiral Sulfoxides
a-Sulfinyl Carbanions (THAT "a" IS A GREEK "a" SO "alpha" --> USE SYMBOL FONT)
Dialkyl and Alkyl Aryl Sulfoxides
Allyl Sulfoxides
Alkyl and Arylsulfenylmethyl Sulfoxides
a-Sulfinyl-, a-Sulfonyl, and a-Sulfoximino Sulfoxides (ALL 3 OF THOSE ARE GREEK "a" SO USE SYMBOL FONT)
a-Halogeno Sulfoxides (THAT "a" IS A GREEK "a" SO "alpha" --> USE SYMBOL FONT)
a-Phosphoryl Sulfoxides and a-Sulfinyl Phosphonium Salts (THOSE "a"s are GREEK "a" SO "alpha" --> USE SYMBOL FONT)
b-Oxosulfoxides (THAT "b" IS A GREEK "b" SO "beta" --> USE SYMBOL FONT) and Related Derivatives
Acyclic a,b-Unsaturated Sulfoxides (THAT "a" IS A GREEK "a" and the "b" is a Greek "b" --> USE SYMBOL FONT)
Cycloalkenone Sulfoxides
Chiral Sulfilimines and Sulfoximines
Synthesis of Chiral Sulfilimines
Synthesis of Chiral Sulfoximines
Chiral Sulfilimines and Sulfoximines in Asymmetric Synthesis
Examples of Experimental Procedures
Chiral "Onium" Derivatives of Sulfur and Chiral Sulfur Ylides
Preparation of Chiral Sulfur Onium Salts and Ylides
Synthetic Application of Chiral Sulfur "Onium" Salts and Ylides
Examples of Experimental Procedures
References
Index
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