Ligand-field parameters

著者

書誌事項

Ligand-field parameters

[by] M. Gerloch and R.C. Slade

Cambridge University Press, 1973

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注記

Bibliography: p. 229-232

内容説明・目次

内容説明

This volume was originally published in 1973. The nature of the non-symmetry determined aspects of ligand-field theory receives inadequate treatment in most texts. This book is concerned with the nature of the ligand-field parameters used to describe the electronic properties of transition metal complexes having cubic and lower symmetries. These radial parameters constitute the non-symmetry-determined part of ligand-field theory. Symmetry-based properties are discussed here only to emphasize the separate roles of splitting factors and symmetry. The reader is assumed to be familiar with the usual approach to ligand-field theory and with elementary group theory.

目次

  • 1. Symmetry versus splitting parameters
  • 2. The crystal-field formalism
  • 3. Interelectron repulsion parameters
  • 4. Radical parameters for angularly-distorted systems
  • 5. Radical parametres for quadrate symmetry
  • 6. The nature and calculation of 10Dq
  • 7. A crystal-field approach to radical parameters
  • 8. Semi-empirical molecular-orbital approaches
  • 9. The Nephelauxetic effect.

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詳細情報

  • NII書誌ID(NCID)
    BA32145175
  • ISBN
    • 0521201373
  • LCCN
    72093139
  • 出版国コード
    uk
  • タイトル言語コード
    eng
  • 本文言語コード
    eng
  • 出版地
    Cambridge [Eng.]
  • ページ数/冊数
    xii, 235 p.
  • 大きさ
    24 cm
  • 分類
  • 件名
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