Branched polymers

著者

• Roovers, J.
• Charleux, B.

書誌事項

Branched polymers

volume editor, J. Roovers ; with contributions by B. Charleux ... [et al.]

（Advances in polymer science, 142, 143）

Springer-Verlag, c1999

• 1
• 2

注記

v. 2:With contributions by W. Burchard ... [et al.]

Includes bibliographical references and index

内容説明・目次

巻冊次

1 ISBN 9783540649236

内容説明

While books have been written on many topics of Polymer Science, no compre hensive treatise on long chain branching has ever been composed. This series of reviews in Volume 142 and 143 of Advances in Polymer Science tries to fill this gap by highlighting active areas of research on branched polymers. Long chain branching is a phenomenon observed in synthetic polymers and in some natural polysaccharides. It has long been recognized as a major mole cular parameter of macromolecules. Its presence was first surmised by H. Stau dinger and G. V. Schuh (Ber. 68, 2320, 1935). Interestingly, their method of iden tification by means of the abnormal relation between intrinsic viscosity and molecular weight has survived to this day. Indeed, the most sophisticated method for analysis of long chain branching uses size exclusion fractionation with the simultaneous recording of mass, molecular weight and intrinsic visco sity of the fractions. In the 1940s and 1950s, random branching in polymers and its effect on their properties was studied by Stockmayer, Flory, Zimm and many others. Their work remains a milestone on the subject to this day. Flory dedicated several chapters of his "Principles of Polymer Chemistry" to non linear polymers. Especially important at that time was the view that randomly branched polymers are inter mediates to polymeric networks. Further developments in randomly branched polymers came from the introduction of percolation theory. The modern aspec ts of this topic are elaborated here in the chapter by W. Burchard.

目次

Synthesis of Branched Polymers by Cationic Polymerization.- Asymmetric Star Polymers: Synthesis and Properties.- Poly(macromonomers): Homo- and Copolymerization.- Dendrimers and Dendrimer-Polymer Hybrids.

巻冊次

2 ISBN 9783540650058

内容説明

While books have been written on many topics of Polymer Science,no comp- hensive treatise o n l ong-chain b ranching has e ver b een c omposed.This se ries o f reviews in Volume 142 an d 143 o f Advances in P olymer Science tries to fill this gap by highlighting active areas of research on branched polymers. Long-chain branching is a p henomenon observed in s ynthetic polymers and in some natural polysaccharides.It has l ong been r ecognized as a ma jor molecular parameter of macromolecules.Its presence was first surmised by H.Staudinger and G.V.Schulz (Ber.68,2320,1935).Interestingly,their method of identifica- on b y m eans o f the a bnormal r elation b etween in trinsic viscosity an d mo lecular weight has s urvived to this day.Indeed,the most sophisticated method for a- lysis o f long-chain b ranching use s size ex clusion fractionation with the simul- neous recording of mass,molecular weight and intrinsic viscosity of the fr- tions.

目次

Hyperbranched Polymers.- Conformational Properties of Branched Polymers: Theory and Simulations.- Solution Properties of Branched Macromolecules.- Entangled Dynamics and Melt Flow of Branched Polymers.

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詳細情報

• NII書誌ID(NCID): BA39189576
• ISBN:
  • 3540649239
  • 3540650059
• 出版国コード: gw
• タイトル言語コード: eng
• 本文言語コード: eng
• 出版地: Berlin
• ページ数/冊数: 2 v.
• 大きさ: 25 cm
• 親書誌ID:
  • BA00303935