The heavier d-block metals : aspects of inorganic and coordination chemistry
著者
書誌事項
The heavier d-block metals : aspects of inorganic and coordination chemistry
（Oxford chemistry primers, 73）（Oxford science publications）
Oxford University Press, 1999
- : pbk
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注記
Includes bibliographical references (p. [88]) and index
内容説明・目次
内容説明
This book addresses the chemistry of the second and third row d-block metals, assuming a knowledge of the chemistry of the first row metals.
Chapter 1 looks at the metals and summarizes occurrence, physical properties and uses.
Chapter 2 considers periodic trends in properties.
Chapter 3 considers aqueous solution chemistry, species present (with comparisons of the first row metal ions) and redox properties.
Chapter 4 surveys structure: the range of coordination numbers shown by second and third row metals is often a topic for discussion in University courses.
Chapter 5 looks at electronic spectra and magnetic properties, making comparisons with the first row the main objective of the chapter. Detailed mathematical treatments are not given.
Chapter 6 considers metal-metal bonding, and the classes of compound that contain triple and quadruple bonds; the role of bridging ligands is introduced.
Chapter 7 looks at selected clusters with a pi donar ligands (e.g. metal halo species) in which metal-metal bonding is important.
Chapter 8 introduces the area of polyoxometallates, closing with a short discussion of the wide range of applications.
The book contains many references to encourage wider reading by the student; in addition to textbooks of relevance, the author has included many recent literature citations, and a section called "Metals in Action" which gives citations which show the heavier metals at work in, for example, catalytic converters and molecular wires.
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