Electronic processes in organic crystals and polymers
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書誌事項
Electronic processes in organic crystals and polymers
（Monographs on the physics and chemistry of materials, 56）
Oxford University Press, 1999
2nd ed
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注記
Includes bibliographical references and indexes
内容説明・目次
内容説明
The first edition of Pope and Swenberg's Electronic Processes of Organic Crystals, published in 1982, became the classic reference in the field. It provides a tutorial on the experimental and related theoretical properties of aromatic hydrocarbon crystals and includes emerging work on polymers and superconductivity. This new edition has been expanded to cover the major theoretical and experimental advances over the last fifteen years. It contains a unified
description of what is known in almost every aspect of the field. The basic phenomena covered in the first edition included fluorescence, exciton and charge carrier generation, transport, recombination, and photoemission; the new edition adds solitons, polarons, bipolarons, spin waves, and charge density
waves. It provides in-depth coverage of such model polymers such as polyacetylene, polydiacetylene, poly (phenylene-vinylene), polyanilines, polysilanes, and fullerenes. It also provides detailed treatments of the expanding areas of electroluminescence, non-linear optics, organic magnets, organic superconductors, and Langmuir-Blodgett films. In addition, it contains a chapter on major applications, including LED's, photocopiers, photoconductors, batteries, transistors, liquid crystals,
photorefractive devices, and sensors. As in the first volume, the authors take informed positions in controversial areas. This book will be an essential reference for organic material scientists, whether they are experienced researchers or just entering the field. It will also be a reliable guide to anyone
interested in this rapidly growing field
目次
Part I
I. OPTICAL PROPERTIES OF ORGANIC MOLECULES AND CRYSTALS
A. Introduction
B. Molecular excited states
C. Spectral properties
D. Excited states of aggregates of molecules
E. Generation of excitons
F. Motion of excitons in molecular systems
G. Exciton processes
II. SINGLE POSITIVE OR NEGATIVE CARRIERS IN ORGANIC CRYSTALS
A. Introduction
B. Isolated molecules with excess charges
C. Crystals with excess positive or negative charges
D. Defects and trapped charge
E. Charge injection mechanisms at surfaces
F. Carrier transport
G. Steady current flow
H. Thermally stimulated current flow
I. Chemical effects accompanying the discharge of electrons and holes at electrolytic surfaces
J. Photovoltaic effect
III. PRODUCTION OF CARRIER PAIRS IN THE BULK
A. Carrier generation mechanisms
B. Carrier recombination
IV. PHOTOEMISSION FROM ORGANIC MOLECULAR CRYSTALS
A. Introduction
B. Detection of photoemission
C. Theory of photoemission from solids
D. Photoemission from organic molecular crystals
E. Multiquantum processes as studied by photoemission spectroscopy
F. Photophoretic spectroscopy
V. MATERIALS WITH HIGH DARK CONDUCTIVITY
A. Introduction
B. Radical-ion salt crystals
C. Charge transfer complexes
D. General properties of one-dimensional crystals
E. Polymeric sulfur nitride (SN)[x
F. Superconducting organic radical-ion salts
VI. MISCELLANEOUS SYSTEMS
A. Introduction
B. Dyes
C. Phthalocyanines
D. Polydiacetylenes
E. Polymers
F. Liquids
Part II
VII. ELECTRONIC PROCESSES IN POLYACETYLENE (PA)
A. Theory
B. Electronic structure
C. Confinement effects
D. Transport
E. Photoexcitation
F. Identity of the charge carriers
G. Summary
VIII. ELECTRONIC PROCESSES IN POLYDIACETYLENE (PDA)
A. Excitons
B. Carriers
C. Summary of energy levels in PDA-TS
IX. ELECTRONIC PROCESSES IN POLY(p-PHENYLENE-VINYLENE) (PPV)
A. Structure and Morphology
B. Excited States
C. Ladder polymers
D. Summary
X. ELECTRONIC PROCESSES IN POLYANILINE (PAni)
A. Solitons
B. Excitons
C. Polarons
D. Bipolarons
E. Pernigraniline base (PNB)
F. Leucoemeraldine base (LB)
G. Model for photexcitations
H. Summary of photoexcitations
I. Polyanilene salts
XI. ELECTRONIC PROCESSES IN POLYSILANE (PS)
A. Poly(methylphenylsilane) (PMPS)
B. Exciton-exciton annihilation
C. Poly(di-n-hexylsilane) (PDHS)
D. Exciton dynamics in PDHS
E. Electroabsorption spectra
F. Summary
XII. ELECTRONIC PROCESSES IN FULLERENES (C[6[0)
A. Geometry
B. Preparation
C. Chemical bonding
D. Electronic structure
E. Band gap
F. Charge-transfer states
G. Carrier mobility
H. Photogeneration and recombination
XIII. CARRIER GENERATION AND RECOMBINATION
A. Carrier generation
B. Carrier recombination
XIV. CARRIER TRANSPORT
A. Molecular crystals
B. Molecular doped polymers (MDPs)
C. Problems associated with existing MDP theories
D. Validity of Einstein's relationship in polymeric systems
E. Quasimetallic transport
XV. SPACE-CHARGE AND EMISSION-LIMITED CURRENTS
A. Contacts
B. Mobility
C. Trapping
XVI. ORGANIC MAGNETS (OM)
A. Molecular basics
B. Mechanisms involved in stabilizing ferromagnetism
C. Basic magnetic parameters, phenomena, and theory
D. Model spin systems
E. Magnetic properties of organic conductors
Appendix 1: Special Topics
Appendix 2: Glossary
XVII. SUPERCONDUCTIVITY AND OTHER COLLECTIVE STATES
A. Nested Fermi surfaces (FS)
B. Charge density waves (CDWs)
C. Spin density waves (SDWs)
D. Spin-Peierls transition (S-P)
E. Superconductivity
F. Magnetic-field effects
G. Can ferromagnetism and superconductivity coexist?
H. Luttinger liquids
XVIII. NONLINEAR OPTICAL AND PHOTOREFRACTIVE PROPERTIES (NLO)
A. Nonlinear optical susceptibility
B. Photorefractive effect (PRE)
C. Dendrimers
XIX. MOLECULAR ELECTRONICS
A. Langmuir-Blodgett (L-B) films
B. L-B films as rectifiers
C. NLO L-B films
XX. APPLICATIONS
A. Electrophotography (XER)
B. Photorefraction, hole burning, and nonlinear optics (HOL)
C. Electroluminescence (EL)
D. Transistors
E. Sensors
F. Liquid crystals
G. Batteries
Credits
Author Index
Subject Index
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