The chemical bond in inorganic chemistry : the bond valence model
著者
書誌事項
The chemical bond in inorganic chemistry : the bond valence model
（International Union of Crystallography monographs on crystallography, 12）
Oxford University Press, 2002
- : pbk
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注記
Includes bibliographical references (p. [253]-270) and index
内容説明・目次
- 巻冊次
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ISBN 9780198508700
内容説明
This book describes the bond valence model, a description of acid-base bonding which is becoming increasingly popular particularly in fields such as materials science and mineralogy where solid state inorganic chemistry is important. Recent improvements in crystal structure determination have allowed the model to become more quantitative. Unlike other models of inorganic chemical bonding, the bond valence model is simple, intuitive, and predictive, and can be used for analysing crystal structures and the conceptual modelling of local as well as extended structures. This is the first book to explore in depth the theoretical basis of the model and to show how it can be applied to synthetic and solution chemistry. It emphasizes the separate roles of the constraints of chemistry and of three-dimensional space by analysing the chemistry of solids. Many applications of the model in physics, materials science, chemistry, mineralogy, soil science, surface science, and molecular biology are reviewed. The final chapter describes how the bond valence model relates to and represents a simplification of other models of inorganic chemical bonding.
目次
- 1. HISTORICAL INTRODUCTION
- 2. THE IONIC BOND
- 4. ANION AND CATION BONDING STRENGTHS
- 10. SPACE AND SPACE GROUPS
- 13. APPLICATIONS
- 巻冊次
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: pbk ISBN 9780199298815
内容説明
The bond valence model is an evolution of Pauling's electrostatic valence principle first enunciated in 1929. Recent improvements in crystal structure determination have allowed the model to become more quantitative. Unlike other models of inorganic chemical bonding, the bond valence model is simple, intuitive, quantitative and predictive, and requires only a pocket calculator. It can be used for analysing crystal structures and the conceptual modelling of local as well as extended structures. This is the first book to explore the theoretical basis of the model and to show how it can be applied to synthetic and solution chemistry. In analysing the chemistry of solids, the book emphasizes the separate roles of the constraints of chemistry and the constraints of 3-dimensional space. It reviews many of the applications of the model in physics, materials science, chemistry, mineralogy, soil science, surface science and molecular biology. The final chapter describes how the bond valence model relates to, and represents a simplification of, other models of inorganic chemical bonding.
目次
- 1. Historical introduction
- I: THEORY
- 2. The ionic bond
- 3. The bond valence model
- II: CHEMISTRY
- Anion and cation bonding strengths
- 5. Liquids
- 6. Cation coordination number
- 7. Hydrogen bonds
- 8. Electronically distorted structures
- 9. Physical properties of bonds
- III: SOLIDS
- 10. Space and space groups
- 11. Modelling inorganic structures
- 12. Lattice induced strain
- IV: APPLICATIONS AND IMPLICATIONS
- 13. Applications
- 14. Chemical implications of the bond valence model
- A. Bond valence parameters
- B. Space group spectra
- C. Solution of the network equations
- D. Cation and anion bonding strengths
- References to the ICSD and the CSD
- References
- List of symbols
- Index
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