Formation of silicon nitride from the 19th to the 21st century

Bibliographic Information

Formation of silicon nitride from the 19th to the 21st century

Raymond C. Sangster

(Materials science foundations, 22-24)

Trans Tech Publications, c2005

Other Title

Formation of silicon nitride from the 19th to the 21st century : A comprehensive summary and guide to the world literature

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Description and Table of Contents

Description

The elements: Si, N, O, C and H, have strong chemical affinities for one another. Under the correct conditions, Si-N bonding will occur in almost any Si-N-(O/C/H), and many related, reaction systems; although Si-O and Si-C are formidable competitors to Si-N. The most favored Si-N compound is stoichiometric Si3N4. It comes in three common varieties. How they interrelate, how one finds them and (above all ) how one makes them - and how sometimes they just happen to form - are the subjects of this book, with due attention being paid to closely related matters.

Table of Contents

Dedication Preface CONTENTS Acronyms and Abbreviations Part A. In the Beginning. Chapter A-1. From the Cosmic to the Mundane Chapter A-2. Book Purpose and Design, Writing Conventions Chapter A-3. Historical Comments re Silicon Nitride Studies Chapter A-4. Natural Occurrence of Si3N4 Chapter A-5. Major Reviews on Formation of Silicon Nitride Part B. Technical Context of Silicon Nitride Formation Chapter B-1. The Si-N System Chapter B-2. Si3N4 Phases and Crystallography Chapter B-3. Phase Chemistry of a-Si3N4 - "-Si3N4 - $-Si3N4 Chapter B-4. High Pressure Phase Chemistry of Si3N4 Chapter B-5. Silicon Nitride Solid Solutions Chapter B-6. Phase Diagram Sources for Si3N4 & SiAlON Ceramic Systems Chapter B-7. Thermodynamics of Si3N4 Chapter B-8. Self-Diffusion in Si3N4 Chapter B-9. Compositional and Phase Analysis of Si3N4 Chapter B-10. Si3N4 Toxicology and Safety Chapter B-11. Engineering Aspects of Silicon Nitride Production Chapter B-12. General Comments on Formation Chemistry of Silicon Nitride Pat C. Si3N4 Products, Uses and Markets Chapter C-1. Survey of Applications and Markets for Si3N4 Materials Chapter C-2. Sintered Silicon Nitride Ceramics Chapter C-3. Overview of Production of Silicon Nitride Powders Chapter C-4. Overview of Si3N4 Whiskers, Fibers, and Filaments Chapter C-5. Overview: Si3N4 Films, Coatings, Membranes, Massive CVD Chapter C-6. Si3N4 Products by Transformation of Si3N4 Source Materials Illustrative Applications I: SRBSN in Automotive Technology. Part D. Si3N4 by Reaction of Si(cr) Surfaces and N-Species Chapter D-1. Comments re Si(s,R,g)/N-Species Preparative Reactions Chapter D-2. Si3N4 from Si(cr/Surface) /N2(g) Chapter D-3. Si3N4 from Si(cr)/Activated Nitrogen Chapter D-4. Si(cr)/N-Ions I. Basic Phenomena of Si3N4 Formation Chapter D-5. Si(cr)/N-Ions II. Ion Plating of Si3N4 Surface Films Chapter D-6. Si(cr)/N-Ions III. Ion Implantation of Buried Si3N4 Layers Part E. Si3N4 Powder Formation from Si(Powder)/N2(g) Chapter E-1. Basic Phenomena in Si3N4 Formation via Si(Powder)/N2(g) Chapter E-2. Si3N4 Powder from Si(powder)/N2/(Impurities & Additives) Chapter E-3. Preparation of Si3N4 Powder via Si(powder)/N2 Illustrative Applications II: SRBSN in Modern Diesel Engines. Part F. Fabrication of Reaction Bonded Silicon Nitride Chapter F-1. RBSN Introduction and Summation Chapter F-2. Reaction Bonded Silicon Nitride Basics Chapter F-3. RBSN Si Powder Effects and Processing Chapter F-4. RBSN Green Shape Effects, Forming, Presintering, Machining Chapter F-5. RBSN Nitridation Chapter F-6. RBSN Product-Process Observations Chapter F-7. RBSN Coating and Impregnation Chapter F-8. Variant Versions of Reaction Bonded Si3N4 Chapter F-9. Doped/Filled/Reinforced RBSN Ceramics Chapter F-10. SRBSN: Post-Sintering of RBSN Part G. Si3N4 from Si/N2 Under Vigorous Conditions Chapter G-1. Si3N4 Formation via Si(R)/N2 Reactions Chapter G-2. Si(powder)/N2(g) Combustion Synthesis of Si3N4 Chapter G-3. SHS Production of Si3N4 Powders, Whiskers and Fibers Chapter G-4. Si3N4 by Si/N2 Reactive Sputtering Chapter G-5. Si3N4 via Si/N2 Reaction in Thermal Plasmas Chapter G-6. Si3N4 Formation via Si(g)/N2, N, N-Plasma, N-Ion Reactions Chapter G-7. Si3N4 Formation via Si+/(N-Plasma, N-Ion) Reactions Chapter G-8. Mechano(-electro)chemical Nitridation of Si Powder Part H. Si3N4 Formation by Reaction of Si with N-Compounds Chapter H-1. Introduction to Si/N-Compound Reactions Chapter H-2. Si3N4 Formation by Thermal Reactions of Si(s)/NH3(g) Chapter H-3. Si3N4 via Stimulated Reactions of Si(s)/NH3(g) Chapter H-4. Si3N4 Formation in other Si/NH3 Reaction Systems Chapter H-5. Si(powder)/NH3(g) Powder Production in Thermal Plasmas Chapter H-6. Si3N4 from Si(s) Plus N-N Bonded and other N-Compounds Part I. Si3N4 by Nitridation of Si-O Based Materials Chapter I-1. Si3N4 Formation via Sio(g,s)/(N2,NH3)/(H2,C,CH4) Chapter I-2. Si3N4 via C-Free Nitridation of SiOxHy, SiO2, Si2N2O Chapter I-3. SiO2/C/N2: Si3N4 by Carbothermal Nitridation of SiO2 Chapter I-4. Si3N4 via other SiO2 Carbothermal Nitridation Systems Chapter I-5. SiO2 Carbothermal Nitridation Impurity/Additive Effects Chapter I-6. Si3N4 via Carbonitridation of Si-O Containing Materials Part J. Si3N4 Formation Si-N Based Materials Chapter J-1. Introduction to Si3N4 from Si-N Based Materials Chapter J-2. Si3N4 Formation by Reactions of Si-N Materials Chapter J-3. Si3N4 from Pyrolysis/Nitridation of Si-N-H Materials, General Chapter J-4. Si3N4 Preparation by Pyrolysis of Si(NH)2 Chapter J-5. Si3N4 via Decomposition of Other Si-N-X Compounds Part K. Comparative Overview and Summary of Si3N4 CVD Chapter K-1. Chemical Vapor Deposition of Si3N4: Fundamentals Chapter K-2. Methods for CVD of Si3N4 Thin Films Part L. Si3N4 by CVD Nitridation of Si-H Compounds Chapter L-1. Preamble: Si3N4 CVD from Silanes Chapter L-2. Si3N4 Chemical Vapor Deposition from SiH4/N2 Chapter L-3. Si3N4 from SiH4/NH3 Thermal Reactions Chapter L-4. Si3N4 Formation via Stimulated CVD from SiH4/NH3 Chapter L-5. SiH4/NH3(g) Formation of Si3N4 Powder Chapter L-6. Si3N4 Formation from SiH4/N2H4(/NH3,N2,H2) Chapter L-7. Si3N4 via Other SiHx CVD Nitridation Systems Part M. Si3N4 by CVD Nitridation of Si Halides and Halosilanes Chapter M-1. Preamble Re Si3N4 CVD from Si Halides and Halosilanes Chapter M-2. Si3N4 via CVD Nitridation of Silicon Fluorides Chapter M-3. Si3N4 Formation via SiCl4/(N2,NH3)(/H2,Ar,He) Reactions Chapter M-4. Si3N4 from SiCl4/NH3 Reactions in Thermal Plasmas Chapter M-5. Si3N4 Formation in Other SiClx Nitridation Systems Chapter M-6. Si3N4 by Nitridation CVD from SiHCl3 Chapter M-7. Si3N4 Formation via SiH2Cl2 Nitridation Chapter M-8. Si3N4 by CVD Nitridation of SiH3Cl, SiBr4, SiHBr3, SiI4 Part N. Si3N4 Formation in Si-C-N Systems Chapter N-1. Si3N4 from Si-C-N-H(-Cl) CVD Reaction Systems Chapter N-2. Si3N4 via Pyrolysis/Nitridation of SiC and Si-C-N Materials Chapter N-3. Si3N4 from Pyrolysis/Nitridation of Organosilicon Polymers Part O. Si3N4 Formation in Si-N-X Systems, X = B, P, S, Fe, Other Chapter O-1. Si3N4 Formation in Si-N-(B, P, S) Systems Chapter O-2. Si3N4In Situ Formation in Iron and Steel Alloys Chapter O-3. Si3N4 Preparation by Reactions of Fe-Si Alloys and N2 Chapter O-4. Si3N4 Formation in Non-Fe Metal-Silicon-Nitrogen Systems Index About the Author

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Details

  • NCID
    BA74985354
  • ISBN
    • 0878494928
  • Country Code
    sz
  • Title Language Code
    eng
  • Text Language Code
    eng
  • Place of Publication
    Uetikon-Zuerich, Switzerland
  • Pages/Volumes
    x, 948 p.
  • Size
    25 cm
  • Parent Bibliography ID
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