Reagents for direct functionalization of C-H bonds
著者
書誌事項
Reagents for direct functionalization of C-H bonds
（Handbook of reagents for organic synthesis, [8]）
John Wiley & Sons, c2007
- : hdk
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注記
Includes bibliographical references and indexes
内容説明・目次
内容説明
A concise and informative collection of articles on the synthesis of organic, biological and medicinal materials. Key Features:* Detailed information on 200 reagents to be used for the functionalization of C-H bonds in the carbon backbone of organic molecules* A systematic approach to the use of organometallic compounds in organic synthesis* Articles will stress chemical aspects such as yield, conversion, specifity [enantio, stereo, regio, chemo], and where applicable, catalyst loading/turnover
目次
Preface ix
Introduction 1
Recent Review Articles and Monographs 9
Allyl Triflone 11
2-Amino-3-Picoline 12
1,2-Benziodoxoyl-3(1H)-one Derivatives 17
2,2-Bis{lcub}[2-[4(S)-tert-butyl-1,3-oxazinyl]{rcub} propane 20
Bis(cyclopentadienyl)methylzirconium Tetraphenylborate-Tetrahydrofuran 26
Bis[dimethyl([micro]-dimethyl sulfide)-platinum(II)] 28
N-Bromosuccinimide 30
Carbon Tetrabromide 41
Carbon Tetraiodide 43
4-(4-Chlorophenyl)-3-hydroxy-2(3H) thiazolethione 45
Chromium(VI) Oxide 48
Chromium(VI) Oxide-3,5-Dimethylpyrazole 53
Chromium(VI) Oxide-Dipyridine 54
Chromyl Acetate 57
Copper(I){lcub}Hydrotris(3,4,5-tribromo)pyrazolylborate{rcub}(acetonitrile) 60
Copper(I),[Hydrotris[3-(2,4,6-trimethylphenyl)-1H-pyrazolato-N[subscript 1]] borato(1-)-N[subscript 2],N[prime][subscript 2]N[tprime][subscript 2] 63
Copper(II) Acetate 64
Copper(II) Chloride 71
Di-(-)-(1R,2S)-2-phenyl-l-cyclohexyl Diazenedicarboxylate 79
(Diacetoxyiodo)benzene 80
Dibenzoyl Peroxide 89
Di-t-butyl Chromate 99
Di-t-butyl Peroxide 102
Dimethyl Diazomalonate 107
Dimethyldioxirane 113
Dipotassium Tetrachloroplatinate(II) 119
Dirhodium(II) bis-{lcub}1,3-[N,N[prime]-di(4-Dodecyl-Benzenesulfonyl)-(2S,2[prime] S),(5R,5[prime] R)-5,5[prime]-Prolinate]Benzene{rcub} 120
Dirhodium(II) Tetra(caprolactamate) 122
Dirhodium(II) Tetrakis(perfluorobutyrate) 124
Dirhodium(II) Tetrakis(trifluoroacetate) 126
Dirhodium(II) Tetrakis(triphenylacetate) 129
Dirhodium(II) Tetraacetamide 132
Dirhodium(II) Tetraacetate 134
Dirhodium(II) Tetrakis[Alkyl 2-oxaazetidine-4(S)-carboxylate] 144
Dirhodium(II) Tetrakis[1-[[(4-dodecylphenyl]sulfonyl]-prolinate] 146
Dirhodium(II) Tetrakis[methyl 1-(3-phenylpropanoyl)-2-oxaimidazolinidinecarboxylate] 154
Dirhodium(II) Tetrakis [methyl 2-oxapyrrolidine-carboxylate] 157
Dirhodium(II) Tetrakis [methyl 2-oxooxazolidine-4(S)-carboxylate] 160
Dirhodium(II) Tetrakis[N-phthaloyl-(S)-tert-leucinate] 162
Dirhodium(II) Tetraoctanoate 166
Disodium Tetrachloroplatinate(II) 169
Ethyl Azidoformate 171
Gallium Trichloride 181
1-Hydroxy-1,2-benziodoxol-3(1H)-one 187
Hypofluorous Acid 190
Hypofluorous Acid, Acetonitrile Complex 191
Iridium(V) Pentahydrobis(isopropylphosphine) 197
Iron(II) Bis(pyridine)bis(2-pyridinecarboxylato-N1,O[subscript 2]) 198
Iron(II) Perchlorate 202
Iron(II) Phthalocyanine 202
Iron(II) 1,3,2-Benzodioxaborol-2-yldicarbonyl ([eta][superscript 5]-2,4-cyclopentadien-1-yl) 204
Mercury(0) 207
Methyl Phenyldiazoacetate 209
Methyl(trifluoromethyl)dioxirane 214
Oxaziridine, 3-Fluoro-3-(heptafluoropropyl)-2-(nonafluorobutyl) 221
Palladium(II) Acetate 229
Pinacol Diborane 253
Pinacolborane 260
Platinum(II) Chloride 263
Rhenium(VII) Methyltrioxo 271
Rhenium(VII) Aquamethyloxodiperoxy 276
Rhenium(VII) Methyloxodiperoxy 283
Rhodium(I) bis Cyclooctene Chloride Dimer 287
Rhodium(I) Carbonyl(chloro)bis(triphenylphosphine) 293
Rhodium(I) Chlorotris(triphenylphosphine) 303
Ruthenium (0) Dodecacarbonyl, Triangulo 315
Ruthenium(II) Dichlorotris(triphenylphosphine) 318
Ruthenium(II), bis[N,N-bis-[(2-pyridyl-[kappa]N)methyl]-2-pyridinemethanamine-N1,N2] di-[micro]-chloride 322
Ruthenium(III) Chloride 324
Ruthenium(III) N,N[prime],N[Prime],-Trimethyl-1,4,7-triazacyclononane + Ruthenium(II) cis-diaquabis(6,6[prime]-dichloro-2,2[prime]-bipyridine)bistriflate 328
Ruthenium(VIII) Oxide 331
Selenium(IV) Oxide 341
Silver(I) [tris[3,5-bis(trifluoromethyl)-1H-pyrazolato-N1]hydroborato(1-)-N2, N2[prime], N2[tprime]-tetrahydrofuran 343
Triethylborane 347
Trifluoromethyl Sulfonyl Ethynyl Benzene 362
Triisopropylsilylethynyl Triflone 363
Tungsten(II) Tricarbonyl(4,6-dimethyl-1,3,2-benzodioxaborol-2-yl)[(1,2,3,4,5,-[eta])-1,2,3.4,5-pentamethyl-2,4-cyclopentadien-l-yl) 364
Tungstoboric Acid, Tetrakis(tetrabutylammonium) Salt 366
Vanadium(VI) Dioxobis(pyrazine-2-carboxylate) Tetrabutylammonium 371
Vanadium(V) Diaquaoxoperoxy (2-pyridinecarboxylate-[kappa]N1, [kappa]02) 375
List of Contributors 379
Reagent Formula Index 387
Subject Index 391
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