Transition metal compounds in organic synthesis
著者
書誌事項
Transition metal compounds in organic synthesis
(Comprehensive organometallic chemistry III / editors-in-chief, D. Michael P. Mingos, Robert H. Crabtree, v. 10-11 . Applications ; 2)
Elsevier, 2007
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注記
v. 10 / volume editor, Iwao Ojima
v. 11 / volume editor, Tamejiro Hiyama
Includes bibliographical references and index
内容説明・目次
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1 ISBN 9780080446004
内容説明
Along with volume 11, this volume reviews how transition metal organometallic compounds are used in organic synthesis. Chapters cover one element and are sub-divided by type of reaction to be readily accessible by organic chemists. Classes of reactions reviewed include C-H, C-C, C-O, C-N and C-E bond formation (E= Si, Sn, B, Te, S, P)
目次
C-H Bond Formation C-H Bond Formation by Asymmetric and Stereoselective Hydrogenation C-H Bond Formation: Through Isomerization Synthetic Reactions via C-H Bond Activation Synthetic Reactions via C-H Bond Activation: C-C and C-E Bond Formation Synthetic Reactions via C-H Bond Activation: Carbene and Nitrene C-H Insertion Synthetic Reactions via C-H Bond Activation: Oxidation of C-H Bonds C-C Bond Formation (Part 1) by Addition Reactions C-C Bond Formation (Part 1) by Addition Reactions: through Carbometallation Mediated by Group 4-7 Metals C-C Bond Formation (Part 1) by Addition Reactions: through Carbometallation Catalyzed by Group 8-11 Metals C-C Bond Formation through Conjugate Addition of C-M to C=C-C=O and C=C-NO2 C-C Bond Formation Through Addition of C-M to C=O, C=N, and CN Bonds Metal-catalyzed Reductive Carbocyclization (C=C, CC, C=O Bonds) C-C Bond Formation through Reaction of CO2 with CC and C=C-C=C C-C Bond Formation (Part 1) by Addition Reactions: Alder-ene Reaction C-C Bond Formation (Part 1) by Addition Reactions: Higher-order Cycloadditions C-O and C-N Bond Formation C-O Bond Formation through Transition Metal-mediated Etherification C-N Bond Formation through Amination C-E Bond Formation (E = Si, Sn, B, Te, S, P) C-E Bond Formation through Element-Element Addition to Carbon-Carbon Multiple Bonds C-E Bond Formation through Hydrosilylation of Alkynes and Related Reactions C-E Bond Formation through Asymmetric Hydrosilylation of Alkenes C-E Bond Formation through Hydroboration and Hydroalumination Index
- 巻冊次
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2 ISBN 9780080446011
内容説明
Along with volume 10, this volume reviews how transition metal organometallic compounds are used in organic synthesis. Chapters are organised by reaction type to be readily accessible by organic chemists. Classes of reactions reviewed include C-C bond formation, reaction of double bonds, metathesis reactions, carbonylation and polymer synthesis.
目次
C-C Bond Formation (Part 2) By Cross-Coupling 11.01 C-C Bond Formation by Cross-coupling 11.02 Reductive Coupling Reactions Promoted by Low-valent Early Transition Metals and Lanthanoids C-C Bond Formation (Part 2) By Substitution Reactions 11.03 C-C Bond Formation (Part 2) by Substitution Reactions: Allylic Alkylation 11.04 C-C Bond Formation (Part 2) by Substitution Reactions: Substitution at Propargylic and Benzylic Positions Synthetic Reactions of MTC and MTN Bonds 11.05 Synthetic Reactions of MTC and MTN Bonds: Ylide Formation, Rearrangement, and 1,3-Dipolar Cycloaddition Metathesis Reactions 11.06 Olefin Cross-Metathesis 11.07 Ring-closing Olefin Metathesis for Organic Synthesis 11.08 Ene-Yne and Alkyne Metathesis Simultaneous C-C and Other Bond Formation 11.09 Sequential Formation of More than One C-C and Other Bonds by Multiple Heck-type Reactions 11.10 Pauson-Khand Reaction 11.11 Silane-initiated Carbocyclization Catalyzed by Transition Metal Complexes Carbonylation 11.12 Carbonylative Cross-coupling and Carbocyclization 11.13 Hydroformylation, Other Hydrocarbonylations, and Oxidative Alkoxycarbonylation 11.14 Silylformylation 11.15 Amidocarbonylation, Cyclohydrocarbonylation, and Related Reactions Transition Metal Catalysts in Polymer Synthesis 11.16 Polymerization of Acetylenes 11.17 Polymerization of Epoxides 11.18 Ring-opening Metathesis Polymerization (ROMP) 11.19 Cross-coupling Polymerization 11.20 Polymerization of Alkenes Index
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