Handbook of metathesis
著者
書誌事項
Handbook of metathesis
Wiley-VCH
2nd ed
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内容説明・目次
内容説明
Covering the complete breadth of the olefin metathesis reaction.
The second edition of the ultimate reference in this field is completely updated and features more than 80% new content, with the focus on new developments in the field, especially in industrial applications. No other book covers the topic in such a comprehensive manner and in such high quality, and this new edition retains the three-volume format: Catalyst Development, Applications in Organic Synthesis and Polymer Synthesis.
Edited by a Nobel laureate in the field, and with a list of contributors that reads like a "Who's-Who" of metathesis, this is an indispensable one-stop reference for organic, polymer and industrial chemists, as well as chemists working with organometallics.
Individual volumes also available separately to purchase
Volume 1: Catalyst Development - http://www.wiley.com/WileyCDA/WileyTitle/productCd-3527339485.html
Volume 2: Applications in Organic Synthesis - http://www.wiley.com/WileyCDA/WileyTitle/productCd-3527339493.html
Volume 3: Polymer Synthesis - http://www.wiley.com/WileyCDA/WileyTitle/productCd-3527339507.html
目次
VOLUME ONE -
CATALYST DEVELOPMENT AND MECHANISM
Preface
High-Oxidation State Molybdenum and Tungsten Complexes Relevant to Olefin Metathesis
Alkane Metathesis
Diastereocontrol in Olefin Metathesis: The Development of Z-Selective Ruthenium Catalysts
Ruthenium Olefin Metathesis Catalysts Supported by Cyclic Alkyl Aminocarbenes (CAACs)
Supported Catalysts and Nontraditional Reaction Media
Insights from Computational Studies on d0 Metal-Catalyzed Alkene and Alkyne Metathesis and Relation Reactions
Computational Studies of Ruthenium-Catalyzed Olefin Metathesis
Intermediates in Olefin Metathesis
Factors Affecting Initiation Rates
Degenerate Metathesis
Mechanisms of Olefin Metathesis Catalyst Decomposition and Methods of Catalyst Reactivation
Solvent and Additive Effects on Olefin Metathesis
Metathesis Product Purification
Ruthenium Indenylidene Catalysts for Alkene Metathesis
VOLUE TWO -
APPLICATIONS IN ORGANIC SYNTHESIS
Preface
General Ring-Closing Metathesis
Cross-Metathesis
Vignette: Extending the Application of Metathesis in Chemical Biology -
The Development of Site-Selective Peptide and Protein Modifications
Ruthenium-Catalyzed Tandem Metathesis/Non-Metathesis Processes
Enyne Metathesis
Alkyne Metathesis
Catalyst-Controlled Stereoselective Olefin Metathesis
Two Vignettes: RCM in Natural Product Total Synthesis
Metathesis of Silicon-Containing Olefins
Ring-Closing Metathesis in the Large-Scale Synthesis of Pharmaceuticals
Metathesis Strategies in Diversity-Oriented Synthesis
Olefin Metathesis: Commerical Applications and Future Opportunities
Index
VOLUME THREE -
POLYMER SYNTHESIS
Preface
Synthesis of Homopolymers and Copolymers
ROMP in Dispersed Media
Telechelic Polymers
Supramolecular Polymers
Synthesis of Materials with Nanostructured Periodicity
Synthesis of Nanoparticles
Synthesis of Biodegradable Copolymers
Biologically Active Polymers
Combination of ROMP with Click Chemistry
Self-Healing Polymers
Functional Supports and Materials
Latent Ruthenium Catalysts for ROMP
ADMET Polymerization
Biorenewable Polymers
Polymerization of Substituted Acetylenes
Index
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