Handbook on the physics and chemistry of rare earths

著者

• Gschneidner, Karl A.
• Eyring, LeRoy
• Lander, Gerry H.
• Bünzli, J.-C. G.
• Pecharsky, Vitalij K.

書誌事項

Handbook on the physics and chemistry of rare earths

editors, Karl A. Gschneidner, Jr., LeRoy Eyring

North-Holland , Sole distributors for the USA and Canada, Elsevier Science, 1978-

• : set
• v. 5
• v. 6
• v. 7
• v. 8
• v. 9
• v. 12
• v. 13
• v. 14
• v. 15
• cumulative index, vols. 1-15
• v. 16
• v. 20
• v. 21
• v. 22
• v. 23
• v. 24
• v. 25
• v. 26
• v. 27
• v. 28
• v. 32
• v. 33
• v. 34
• v. 35
• v. 36
• v. 38
• v. 39
• v. 40
• v. 41
• v. 42
• v. 43
• v. 44
• v. 45
• v. 46
• v. 47
• v. 48
• v. 49
• v. 50
• v. 51
• v. 52
• v. 53
• v. 54
• v. 55
• v. 56

注記

Vol. 32 editors: Karl A. Gschneidner, Jr., LeRoy Eyring, Gerry H. Lander

Vols. 33-41 editors: Karl A. Gschneidner, Jr., Jean-Claude G. Bünzli, Vitalij K. Pecharsky

Vol. 42-56 editors: Jean-Claude G. Bünzli, Vitalij K. Pecharsky

Vol. 43-45, 48-56: "Including actinides"

Cumulative index volume includes errata to vols. 1-15

Includes bibliographical references and indexes

子書誌有り

内容説明・目次

巻冊次

v. 26 ISBN 9780444501851

内容説明

Over twenty years since the appearance of volume 1 of this prestigious series, the rare earths continue to perplex, if not mystify us. There is no doubt that in the next breakthrough to a higher level of human understanding of nature, the rare earth elements and their compounds will play an important part in its elaboration. The reviews contained in this 26th volume continue this quest.Three of the chapters deal with various aspects of the magnetic behaviours of the lanthanide metals and some of their compounds, while the fourth is concerned with the photoelectron spectroscopy of the anomalous f (heavy fermion) systems in cerium and uranium compounds.The first chapter presents information and results gleaned from X-ray scattering studies on the magnetic lanthanide metals, intra lanthanide alloys, a few intermetallic compounds, intra lanthanide superlayers and thin films.Chapter two is concerned with the use of static pressure and alternating mechanical stresses and their effects to study the magnetic properties of the lanthanide metals, alloys and compounds.This is followed by an examination of magnetic systems which are close to the critical conditions for the appearance of magnetic ordering. The authors note that itinerant electron metamagnetism was predicted over 35 years ago, but that the major advances were only discovered over the past decade.One of the prime research tools for understanding 4f and 5f systems is photoelectron spectroscopy and early work is this field was plagued by the lack of single crystals, the poor quality of polycrystalline samples and inadequate theories to interpret photoelectron spectra. This has however changed, and new developments are reviewed in the last chapter.

目次

Preface. X-ray scattering studies of lantanide magnetism (D.F. McMorrow, D. Gibbs, J. Bohr). Static and dynamic stresses (A.M. Tishin, Yu. I. Spichkin, J. Bohr). Itinerant electron metamagnetism of Co sublattice in the lanthanide-cobalt intermetallics (N.H. Duc, T. Goto). Photoelectron spectroscopy in heavy fermion systems: emphasis on single crystals (A.J. Arko et al.). Author index. Subject index.

巻冊次

v. 27 ISBN 9780444503428

内容説明

This was the last volume in this distinguished series of handbooks published in the twentieth century. It contains three chapters dealing with rare earth alloys and intermetallic compounds. Chapter one deals with ternary rare earth-germanium alloys, their phase diagrams and the crystal structures of the intermediate phases. In particular the group VIII metals are discussed, of which the first member of each row (iron, ruthenium and osmium) forms only half the number of compounds as the other two members, cobalt and nickel and their congeners. The author also observes that the ternary alloy systems of the rare earths and germanium with the s and p elements have hardly been investigated. The chapter ends with a discussion on the general trends and unusual features observed in the various sets of ternary phase diagrams. Chapters two describes in detail the various structure types that have been adopted by the rare earth-germanium ternary intermetallic compounds. The correlations, crystal chemistry and interrelationships of the 135 structure types are discussed. This paper also reviews quaternary compounds and superstructures. The final chapter deals with scandium alloys and intermetallic compounds, binary, ternary and higher order systems. The authors summarize the various phase diagrams of scandium systems and present the crystal structure properties of the various intermediate phases. The chapter finishes with a presentation of physical property data on scandium intermetallic phases. The results are divided into three groups - compounds which have a magnetic ground state, a superconducting ground state and those with neither a magnetic or a superconducting ground state.

目次

Preface. Contents of volumes 1-26. 173. Ternary rare-earth-germanium systems (P.S. Salamakha, O.L. Sologub, O.I. Bodak). 174. Crystal structures and crystal chemistry of ternary rare-earth germanides (P.S. Salamakha). 175. Scandium alloy systems and intermetallics (B.Ya. Kotur, E. Gratz). Author index. Subject index.

巻冊次

v. 28 ISBN 9780444503466

内容説明

Even at the beginning of the new millenium the rare earths still remain, to a certain extent, a mystery. The chapters in this volume will help to unravel some of these. In the filling of the 4f electronic orbitals the lanthanides defy the elementary aufbau principle that underlies the periodic sequence of the elements, and the authors of the first chapter introduce the readers to the basic physics of the orbital collapse leading to that failure. Furthermore an explanation is offered in terms of double-well potentials. The phenomenon is illustrated using the valence transitions observed in some of the rare earth atoms, including Sm group metals and the higher oxides of cerium, praseodymium and terbium. In the second chapter the synthesis and structure of the many types of rare earth halides are described. They have been described as simple, complex, binary, ternary and multinuclear complex, and other categories needed to deal with the most studied of the rare earth compounds. The structure types are skillfully illustrated to show the elementary architecture of each type. In chapter three the authors discuss the science and applications of rare earth super ionic conductors as solid electrolytes. Conduction by oxygen and fluorine anions as well as hydrogen and other cations associated with these electrolytes is emphasized. They deal with extrinsic and intrinsic types together with their associated structures and structural types including structural defects. The chapter concludes with an outline of the many applications of solid electrolytes. Chapter four introduces the reader to the principles that underlie thermoluminescence and its application to dosimetry and provides detailed information on the R-activated phosphors that support dosimetry. This is a selective review of detailed literature based on the areas making most progress. The final chapter elaborates on the data gained by the studies and interpretation around the analytical separation of the individual rare earth elements utilizing chromatographic techniques. The authors describe the fundamental chemistry that underpins contemporary analytical separation techniques for lanthanide separation and analysis. This is done after a description of the rich assortment of separation methods in use has been introduced.

目次

Preface. Electronic excitation in atomic species (J.-P. Connerade, R.C. Karnatak). Simple and complex halides (G. Meyer, M.S. Wickleder). Solid electrolytes (R.V. Kumar, H. Iwahara). Activated thermoluminescent (TL) dosimeters and related radiation detectors (A. Halperin). Analytical separations of the lanthanides: basic chemistry and methods (K.L. Nash, M.P. Jensen). Author index. Subject index.

巻冊次

v. 32 ISBN 9780444507624

内容説明

This volume of the handbook covers a variety of topics with three chapters dealing with a range of lanthanide magnetic materials, and three individual chapters concerning equiatomic ternary ytterbium intermetallic compounds, rare-earth polysulfides, and lanthanide organic complexes. Two the chapters also include information of the actinides and the comparative lanthanide/actinide behaviors.

目次

Preface. 205. Giant magnetostriction in lanthanide-transition metal thin films (N.H.Duc). 206. SR studies of rare earth and actinide magnetic materials (G.M. Kalvius, D.R. Noakes, O. Hartmann). 207. Structure-property-relationships of ternary equiatomic YbTX intermetallics (R. Poettgen, D. Kussmann, D. Johrendt). 208. Rare earth-based permanent magnets (K. Kobayashi, S. Hirosawa) 209. Polysulfides (I. G. Vasilyeva). 210. Half-sandwich tetrapyrole complexes of rare earths and actinides (J. Jiang, D.K.P. Ng, K.Kasuga, et al).

巻冊次

v. 33 ISBN 9780444513236

内容説明

This volume of the Handbook illustrates the rich variety of topics covered by rare earth science. Three chapters are devoted to the description of solid state compounds: skutterudites (Chapter 211), rare earth -antimony systems (Chapter 212), and rare earth-manganese perovskites (Chapter 214). Two other reviews deal with solid state properties: one contribution includes information on existing thermodynamic data of lanthanide trihalides (Chapter 213) while the other one describes optical properties of rare earth compounds under pressure (Chapter 217). Finally, two chapters focus on solution chemistry. The state of the art in unraveling solution structure of lanthanide-containing coordination compounds by paramagnetic nuclear magnetic resonance is outlined in Chapter 215. The potential of time-resolved, laser-induced emission spectroscopy for the analysis of lanthanide and actinide solutions is presented and critically discussed in Chapter 216.

目次

Preface. 211. Filled Skutterudites (B.C. Sales). 212. Rare Earth-Antimony Systems (O.L. Sologub, P.S. Salamakha). 213. Thermodynamic Properties of the Lanthanide (III) Halides (R.I.M. Konings, A. Kovacs). 214. Rare Earth-Manganese Perovskites (J.B. Goodenough). 215. Paramagnetic NMR Lanthanide Induced Shift for Extracting Solution Structure (C. Piguet, C. Geraldes). 216. Lanthanide and Actinide Solution Chemistry Studied by Time-resolved Laser-induced Spectrocopy (TRLS) (I. Billard). 217. Optical Studies of Non-metallic Rare Earth Compounds Under Pressure (Th. Troester).

巻冊次

v. 34 ISBN 9780444515872

内容説明

This volume of the Handbook adds five new chapters to the science of rare earths. Two of the chapters deal with intermetallic compounds. An overview of ternary systems containing rare earths, transition metals and indium - Chapter 218 - opens the volume. It is followed by Chapter 219 sorting out relationships between superconductivity and magnetism. The next two chapters are dedicated to complex compounds of rare earths: Chapter 220 describes structural studies using circularly polarized luminescence spectroscopy of lanthanide systems, while Chapter 221 examines rare-earth metal-organic frameworks, also known as coordination polymers. The final Chapter 222 deals with the catalytic activity of rare earths in site-selective hydrolysis of DNA and RNA.

目次

218. Rare earth-transition metal-indides (Ya. Kalychak, V. Zaremba, R. Poettgen, M. Lukachuk, and R.-D. Hoffmann)219. Unconventional superconductivity and magnetism in lanthanide and actinide intermetallic compounds (P. Thalmeier and G. Zwicknagl)220. Circularly polarized luminescence spectroscopy from lanthanide systems (J.P. Riehl and G. Muller)221. Lanthanide-containing coordination polymers (O. Guillou and C. Daiguebonne)222. Cutting DNA and RNA (M. Komiyama)

巻冊次

v. 35 ISBN 9780444520289

内容説明

The rare earths play a unique role in science. These seventeen related elements afford a panoply of subtle variations deriving from the systematic development of their electronic configurations, allowing a test of theory with excellent resolution. In contrast they find widespread use in even the most mundane processes such as steel making, for polishing materials and gasoline cracking catalysts. In between are exotic uses such as TV screen phosphors, lasers, high strength permanent magnets and chemical probes.This multi-volume handbook covers the entire rare earth field in an integrated manner. Each chapter is a comprehensive up-to-date, critical review of a particular segment of the field. The work offers the researcher and graduate student alike, a complete and thorough coverage of this fascinating field.

目次

Preface Contents Contents of Volumes 1-34 Index of Contents of Volumes 1-35 223. Rare-earth Materials for Solid Oxide Fuels (SOFC) (Natsuko Sakai, Katsuhiko Yamaji, Teruhisa Horita, Yue Ping Xiong and Harumi Yokokawa) 224. Oxo-selenates of Rare Earth Elements (Mathias S. Wickleder) 225. Rare-earth Beta-diketonates (Koen Binnemans) 226. Molecular Recognition and Sensing via Rare Earth Complexes (Prof. Satoshi Shinoda, Dr. Hiroyuki Miyake, and Prof. Hiroshi Tsukube) Author Index Subject Index

巻冊次

v. 36 ISBN 9780444521422

内容説明

This volume of the Handbook on the Physics and Chemistry of Rare Earth begins with a Dedication to late Professor LeRoy Eyring who had been a committed co-editor of the first 32 volumes of this series. This is followed by four chapters, the first two pertaining to solid state physics and materials science, while the last two chapters describe organic (and inorganic) reactions mediated by tetravalent cerium-based oxidants and by divalent samarium-based reductants. Chapter 227 is devoted to the description of the crystal chemistry and physical properties of rare-earth bismuthides, a class of compounds showing large similarities with the rare-earth antimonides previously reviewed in volume 33 of this series. The fascinating optical and electric properties of rare-earth hydride films displaying a switchable mirror effect as a function of hydrogen pressure, i.e. from a shiny metallic state to a transparent insulating film with increasing pressure, are described in Chapter 228, along with their fabrication methods. Many chemical reactions take advantage of the tetravalent/trivalent Ce(IV)/Ce(III) redox couple and many of its potential applications are presented in Chapter 229, from analytical procedures, to electrosynthesis, and organic and industrial (polymerization) reactions. The last review (Chapter 230) focuses on the synthesis and use of divalent samarium-based reductants in organic and inorganic reactions, mainly on those containing iodide and pentamethylcyclopentadienyl ligands.

目次

Preface Contents Contents of Volumes 1-35Index of Contents of Volumes 1-36Dedication to Professor LeRoy Eyring227. Bismuthides (A. Mar)228. Switchable Metal Hydride Films (I. Aruna, L.K. Malhotra, and B.R. Mehta)229. Applications of tetravalent cerium compounds (K. Binnemans)230. Samarium(II) Based Reductants (Robert A. Flowers II, and Edamana Prasad)Author IndexSubject Index

巻冊次

v. 38 ISBN 9780444521439

内容説明

This continuing authoritative series deals with the chemistry, materials science, physics and technology of the rare earth elements. Volume 38 of the Handbook on the Physics and Chemistry of Rare Earth incorporates a recapitulation of the scientific achievements and contributions made by the late Professor LeRoy Eyring (1919-2005) to the science of the lanthanide oxides in which the lanthanide element has a valence equal to or greater than three.

目次

Preface Contents Contents of Volumes 1-37 Index of Contents of Volumes 1-38 236. Lanthanide Higher Oxides: The Contributions of LeRoy Eyring (Zhenchuan Kang) 237. Rare Earth-Transition Metal-Plumbides (R. Poettgen and U.C. Rodewald) 238. Higher Borides (T. Mori) 239. Rare Earth Nickel Boro-Carbides (K.-H. Mueller, M. Schneider, G. Fuchs and S.L. Drechsler) 240. Polyoxometallates (M.T. Pope) Author Index Subject Index

巻冊次

v. 40 ISBN 9780444532206

内容説明

This continuing authoritative series deals with the chemistry, materials science, physics and technology of the rare earth elements in an integrated manner. Each chapter is a comprehensive, up-to-date, critical review of a particular segment of the field. The work offers the researcher and graduate student a complete and thorough coverage of this fascinating field.

目次

• 244. Magnetic Circular Dichroism of Lanthanides (Ch.Goerller-Walrand and L. Fluyt)
• 245. Cluster Compounds of Rare-Earth Elements (Z. Zheng)
• 246. Molecular Chemistry of the Rare- Earth Elements in Uncommon Low-Valent States (F. Nief)
• 247. Self-assembled Lanthanide Helicates: From Basic Thermodynamics to Applications (C. Piguet and J.-C. G. Bunzli)

巻冊次

v. 39 ISBN 9780444532213

内容説明

This continuing authoritative series deals with the chemistry, materials science, physics and technology of the rare earth elements in an integrated manner. Each chapter is a comprehensive, up-to-date, critical review of a particular segment of the field. The work offers the researcher and graduate student a complete and thorough coverage of this fascinating field.REVIEW:"Highly experienced authors have written each review usually at a level suitable for advanced postgraduate students and research workers from a variety of fields. With the great richness of information involving references to other review articles written from different points of view, the books are an important reference source and should be on the shelves of most libraries." -- Journal of Applied Crystallography

目次

Preface Contents Contents of Volumes 1-38 Index of Contents of Volumes 1-39 241. The Dual, Localized or Band-like, Character of the 4f States (W.M. Temmerman, L. Petit, A. Svane, Z. Szotek, M. Lueders, P. Strange, J.B. Staunton, I.D. Hughes, and B.L. Gyorffy) 242. Perovskite-like Aluminates and Gallates (L. Vasylechko, A. Senyshyn, and U. Bismayer) 243. Luminescence of Polyoxometallolanthanates (T. Yamase) Author Index Subject Index

巻冊次

v. 41 ISBN 9780444535900

内容説明

This continuing authoritative series deals with the chemistry, materials science, physics and technology of the rare earth elements in an integrated manner. Each chapter is a comprehensive, up-to-date, critical review of a particular segment of the field. The work offers the researcher and graduate student a complete and thorough coverage of this fascinating field.

巻冊次

v. 42 ISBN 9780444543165

内容説明

This continuing authoritative series deals with the chemistry, materials science, physics and technology of the rare earth elements in an integrated manner. Each chapter is a comprehensive, up-to-date, critical review of a particular segment of the field. The work offers the researcher and graduate student a complete and thorough coverage of this fascinating field.

目次

Thermodynamic Properties of Lanthanide Fluorides and Chlorides, by Alexandr Chervonnyi Thermal and Electronic Properties of Rare Earth Compounds at High Pressure, by Gendo Oomi and Yoshiya Uwatoko

巻冊次

v. 43 ISBN 9780444595362

内容説明

The rare earths represent a group of chemical elements, the lanthanides, together with scandium and yttrium, which exhibit similar chemical properties. They are strategically important to developed and developing nations as they have a wide variety of applications in catalysis, the defense industry, aerospace, the materials and life sciences and in sustainable energy technologies. The Handbook on the Physics and Chemistry of the Rare Earths is a continuing authoritative series that deals with the science and technology of the rare earth elements in an integrated manner. Each chapter is a comprehensive, up-to-date, critical review of a particular segment of the field. The work offers the researcher and graduate student a complete and thorough coverage of this fascinating field.

目次

Lanthanidomesogens, Koen Binnemans Ionic liquids: new hopes for efficient lanthanide/actinide extraction and separation? Isabelle Billard Recycling of rare earths from scrap, M. Tanaka, T. Oki, K. Koyama, H. Narita, T. Oishi Structural properties of lanthanides at ultra high pressure, Gopi K. Samudrala and Yogesh K. Vohra Thermodynamic properties of scandium, yttrium and the lanthanide metals, John William Arblaster

巻冊次

v. 44 ISBN 9780444627117

内容説明

The rare earths represent a group of chemical elements, the lanthanides, together with scandium and yttrium, which exhibit similar chemical properties. They are strategically important to developed and developing nations because they have several applications in catalysis, the defense industry, aerospace, the materials and life sciences and in sustainable energy technologies. The Handbook on the Physics and Chemistry of the Rare Earths is a continuing authoritative series that deals with the science and technology of the rare earth elements in an integrated manner. Each chapter is a comprehensive, up-to-date, critical review of a particular segment of the field. The work offers the researcher and graduate student a complete and thorough coverage of this fascinating field.

目次

259 Catalytic Behavior of Rare Earth Borohydride Complexes in Polymerization of Polar Monomers, Sophie Guillaume, Laurent Maron and Peter Roesky 260 Structures and Properties of Rare Earth Molten Salts, Yasuhiko Iwadate 261 Lanthanide in Solar Energy Conversion, Jean-Claude G. Bunzli, and Anne-Sophie Chauvin 262 Magnetocaloric effects in R5(SiGe)4 Compounds, Vitalij K. Pecharsky, Karl Gschneidner Jr. and Yaroslav Mudick

巻冊次

v. 45 ISBN 9780444632562

内容説明

The Handbook on the Physics and Chemistry of Rare Earths is an ongoing series covering all aspects of rare earth science-chemistry, life sciences, materials science, and physics. The main emphasis of the Handbook is on rare earth elements [Sc, Y and the lanthanides (La through Lu)] but information is also included, whenever relevant, on the closely related actinide elements. The individual chapters are comprehensive, broad, up-to-date critical reviews written by highly experienced invited experts. The series, which was started in 1978 by Professor Karl A. Gschneidner Jr., combines and integrates both the fundamentals and applications of these elements and now publishes two volumes a year.

目次

263 Gas-Phase Ion Chemistry of Rare Earths and Actinide, Joaquim Marcalo and J.K. Gibson264 Rare-Earth-Metal Complexes and Cluster Complexes. A Unifying Concept, Gerd Meyer265 Optical Refrigeration, Markus Hehlen266 Rare Earth Arene-bridged Complexes Obtained by Reduction of Organometallic Precursors, Paula L. Diaconescu and Wenliang Huang

巻冊次

v. 46 ISBN 9780444632609

内容説明

The Handbook on the Physics and Chemistry of Rare Earths is a continuous series of books covering all aspects of rare earth science - chemistry, life sciences, materials science, and physics. The main emphasis of the Handbook is on rare earth elements [Sc, Y and the lanthanides (La through Lu)] but whenever relevant, information is also included on the closely related actinide elements. The individual chapters are comprehensive, broad, up-to-date critical reviews written by highly experienced invited experts. The series, which was started in 1978 by Professor Karl A. Gschneidner Jr., combines and integrates both the fundamentals and applications of these elements and now publishes two volumes a year.

目次

Rare earth doped crystals for quantum information processing, Goldner and FerrierDeep-sea mud in the Pacific Ocean as a new mineral source of rare earths, Kato and Nakamura

巻冊次

v. 47 ISBN 9780444634818

内容説明

Handbook on the Physics and Chemistry of Rare Earths is a continuing series of books covering all aspects of rare earth science, including chemistry, life sciences, materials science, and physics. The handbook emphasizes rare earth elements [Sc, Y and the lanthanides (La through Lu)] but, when relevant, information also is included about the closely related actinide elements. The individual chapters are comprehensive, broad, up-to-date critical reviews written by highly experienced invited experts. The series, which was started in 1978 by Professor Karl A. Gschneidner, Jr., combines and integrates both the fundamentals and applications of these elements and now publishes two volumes a year.

目次

Organic chromophores-based sensitization of NIR-emitting lanthanides: towards highly efficient halogenated environments, by I.Hernandez and W.P. GillinEuropium chalcogenide nanoparticles, by Yasuchika Hasegawa and Takayuki NakanishiHybrid materials of the f elements part I: the lanthanides, by Korey P. Carter and Christopher L. CahillMicroscopic thermodynamic descriptors for rationalizing lanthanide complexation processes, by Claude PiguetNear-IR triggered photon upconversion: imaging, detection and therapy, by Diana C. Rodriguez-Burbano, Rafik Naccache, and John Capobianco

巻冊次

v. 48 ISBN 9780444634832

内容説明

Handbook on the Physics and Chemistry of Rare Earths is a continuous series of books covering all aspects of rare earth science, including chemistry, life sciences, materials science, and physics. The main emphasis of the handbook is on rare earth elements [Sc, Y and the lanthanides (La through Lu)], but whenever relevant, information is also included on the closely related actinide elements. The individual chapters are comprehensive, broad, up-to-date, critical reviews written by highly experienced invited experts. The series, which was started in 1978 by Professor Karl A. Gschneidner Jr., combines and integrates both the fundamentals and applications of these elements, now publishing two volumes a year.

目次

• Persistent Phosphors Philippe F. Smet Quaternary R2X3dPbXdZX2 (X5S, Se
• Z5Si, Ge, Sn) Chalcogenides 109 Marek Daszkiewicz, Hybrid Materials of the f-Elements Part II: The Uranyl Cation 163 Christopher L. Cahill Progress in the Separation Processes for Rare Earth Resources Wuping Liao

巻冊次

v. 49 ISBN 9780444636997

内容説明

Handbook on the Physics and Chemistry of Rare Earths is a continuous series of books covering all aspects of rare earth science, including chemistry, life sciences, materials science, and physics. The book's main emphasis is on rare earth elements [Sc, Y, and the lanthanides (La through Lu], but whenever relevant, information is also included on the closely related actinide elements. Individual chapters are comprehensive, broad, up-to-date critical reviews written by highly experienced, invited experts. The series, which was started in 1978 by Professor Karl A. Gschneidner Jr., combines and integrates both the fundamentals and applications of these elements and publishes two volumes a year.

目次

Contributors Preface Contents of Volumes 1-48 Index of Contents of Volumes 1-49 Chapter 278: Rare Earth-Doped Phosphors for White Light-Emitting Diodes Chapter 279: REE Mineralogy and Resources Chapter 280: Quantum Critical Matter and Phase Transitions in Rare Earths and Actinides Chapter 281: Lanthanides in Luminescent Thermometry Index

巻冊次

v. 50 ISBN 9780444638519

内容説明

Handbook on the Physics and Chemistry of Rare Earths: Including Actinides is a continuous series of books covering all aspects of rare earth science, including chemistry, life sciences, materials science, and physics. The book's main emphasis is on rare earth elements [Sc, Y, and the lanthanides (La through Lu], but whenever relevant, information is also included on the closely related actinide elements. Individual chapters are comprehensive, broad, up-to-date, critical reviews written by highly experienced, invited experts. The series, which was started in 1978 by Professor Karl A. Gschneidner Jr., combines, and integrates, both the fundamentals and applications of these elements with two published volumes each year.

目次

1. SystematicsKarl A. Gschneidner Jr.2. The Rare Earths as Critical MaterialsAlexander H. King, Roderick G. Eggert and Karl A. Gschneidner Jr.3. Theory of Rare-Earth Electronic Structure and SpectroscopyMichael F. Reid4. Ab Initio Calculations on Excited States of Lanthanide Containing MaterialsLuis Seijo and Zoila Barandiaran5. Magnetic Bistability in Lanthanide-Based Molecular Systems: The Role of Anisotropy and Exchange InteractionsDante Gatteschi, Roberta Sessoli and Lorenzo Sorace6. Lanthanide Luminescence: From a Mystery to Rationalization, Understanding and ApplicationsJean-Claude G. Bunzli7. Thermoelectric Properties of Zintl AntimonidesNasrin Kazem and Susan M. Kauzlarich8. Ceria-Based Materials in Catalysis: Historical Perspective and Future TrendsEleonora Aneggi, Marta Boaro, Sara Colussi, Carla de Leitenburg and Alessandro Trovarelli9. Lanthanide Metal-Organic Frameworks for Luminescent ApplicationsYuanjing Cui, Jun Zhang, Banglin Chen and Guodong Qian10. Rare Earth Coordination Chemistry in Action: Exploring the Optical and Magnetic Properties of the Lanthanides in Bioscience Whilst Challenging Current TheoriesDavid Parker11. Lanthanide Nanoparticles: Promising Candidates for Magnetic Resonance Imaging Contrast EnhancementXiao-Yu Zheng, Ling-Dong Li, Ling-Dong Sun and Chun-Hua Yan12. Expanding the +2 Oxidation State to the Rare-Earth Metals, Uranium, and Thorium in Molecular ComplexesDavid H. Woen and Williams J. Evans13. Coordination Chemistry in Rare Earth Containing Ionic Liquids Denis Prodius and Anja-Verena Mudring

巻冊次

v. 52 ISBN 9780444638779

内容説明

Handbook on the Physics and Chemistry of Rare Earths: Including Actinides, Volume 52, is a continuous series of books covering all aspects of rare earth science, including chemistry, life sciences, materials science and physics. The book's main emphasis is on rare earth elements [Sc, Y, and the lanthanides (La through Lu], but whenever relevant, information is also included on the closely related actinide elements. Individual chapters are comprehensive, broad, up-to-date, critical reviews written by highly experienced, invited experts. The series, which was started in 1978 by Professor Karl A. Gschneidner Jr., combines, and integrates, both the fundamentals and applications of these elements with two published volumes each year.

目次

1. Alloy Systems and Compounds Containing Rare Earth Metals and Carbon Volodymyr Babizhetskyy, Bogdan Kotur, Volodymyr Levytskyy and Herwig Michor

巻冊次

v. 51 ISBN 9780444638786

内容説明

Handbook on the Physics and Chemistry of Rare Earths: Including Actinides, Volume 51, is a continuous series of books covering all aspects of rare earth science, including chemistry, life sciences, materials science and physics. This latest release includes chapters on the Effect of Pressure on the Interplay Between Orbital and Magnetic Ordering, Kondo Effect, Valence Fluctuation, and Superconductivity in Rare-Earth Compounds and a section on Rare-Earth: Doped Waveguide Amplifiers and Lasers. The book's main emphasis is on rare earth elements [Sc, Y, and the lanthanides (La through Lu], but whenever relevant, information is also included on the closely related actinide elements. Individual chapters in the ongoing series consist of comprehensive, broad, up-to-date, critical reviews written by highly experienced, invited experts. The series, which was started in 1978 by Professor Karl A. Gschneidner Jr., combines, and integrates, both the fundamentals and applications of these elements with two published volumes each year.

目次

1. Effect of Pressure on the Interplay Between Orbital and Magnetic Ordering, Kondo Effect, Valence Fluctuation, and Superconductivity in Rare-Earth CompoundsYoshiya Uwatoko, Hiroki Takahashi and Gendo Oomi2. Rare-Earth-Doped Waveguide Amplifiers and LasersMarkus Pollnau3. Lanthanide Macrocyclic Complexes: Structure, Thermodynamics, Kinetics, and ApplicationsC. Allen Chang

巻冊次

v. 53 ISBN 9780444641571

内容説明

Handbook on the Physics and Chemistry of Rare Earths: Including Actinides, Volume 53, is a continuous series covering all aspects of rare earth science, including chemistry, life sciences, materials science and physics. The book focuses on rare earth elements [Sc, Y, and the lanthanides (La through Lu], but when relevant, information is included on the related actinide elements. Individual chapters are comprehensive, up-to-date, critical reviews written by highly experienced, invited experts, with this release including chapters on a Comparison of the Electronic Properties of Lanthanides with Formally Isoelectronic Actinides, Redox catalysis with redox-inactive rare-earth ions in artificial photosynthesis, and more. The series, which was started in 1978 by Professor Karl A. Gschneidner Jr., combines, and integrates, both the fundamentals and applications of these elements with two published volumes each year.

目次

Dedication to Karl Gschneidner Jr. R. William McCallum 1. Comparison of the Electronic Properties of f 7, f 8, and f 9 Lanthanides With Formally Isoelectronic Actinides Matthew L. Marsh, Frankie D. White, Shane S. Galley and Thomas E. Albrecht-Schmitt 2. Nonradiative Deactivation of Lanthanoid Luminescence by Multiphonon Relaxation in Molecular Complexes Elisabeth Kreidt, Christian Kruck and Michael Seitz 3. Crystal Structure and Chemical Bonding in Gallides of Rare-Earth Metals Anatolii Fedorchuk and Yuri Grin 4. Structural, Electronic, and Physical Properties of Solid-State Rare Earth Boride Carbides Volodymyr Babizhetskyy, Josef Bauer, Regis Gautier, Kurt Hiebl, Arndt Simon and Jean-Francois Halet

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v. 54 ISBN 9780444641595

内容説明

Handbook on the Physics and Chemistry of Rare Earths: Including Actinides, Volume 54, is a continuous series of books covering all aspects of rare earth science, including chemistry, life sciences, materials science and physics. The book's main emphasis is on rare earth elements [Sc, Y, and the lanthanides (La through Lu], but whenever relevant, information is also included on the closely related actinide elements. Individual chapters are comprehensive, broad, up-to-date, critical reviews written by highly experienced, invited experts. The series, which was started in 1978 by Professor Karl A. Gschneidner Jr., combines, and integrates, both the fundamentals and applications of these elements.

目次

1. Reactivity of Actinide Imido Complexes Caleb J. Tatebe, Kristen E. Gettys and Suzanne C. Bart 2. Structural and Physical Properties of Remeika Phases Roman Gumeniuk 3. Rare Earth Separations: Kinetics and Mechanistic Theories Gabriela A. Picayo and Mark P. Jensen

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v. 55 ISBN 9780444642974

内容説明

Handbook on the Physics and Chemistry of Rare Earths: Including Actinides, Volume 55, the latest release in a continuous series of books covering all aspects of rare earth science, including chemistry, life sciences, materials science and physics, presents comprehensive, broad, up-to-date, critical reviews written by highly experienced, invited experts. The series, which was started in 1978 by Professor Karl A. Gschneidner Jr., combines and integrates both the fundamentals and applications of these elements, with this release including chapters on Low Coordinate f-element Complexes and Organometallic Lanthanide SMMs.

目次

1. Low coordinate rare earth and actinide complexesFabrizio Ortu and David P. Mills2. Electronic structure and magnetic properties of rare-earth organometallic sandwich compoundsRichard Collins, James P. Durrant, Mian He and Richard A. Layfield3. Recent advances in chemistry of transuranium elements in non-aqueous mediaFrankie D. White and Matthew L. Marsh

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v. 56 ISBN 9780444642998

内容説明

Handbook on the Physics and Chemistry of Rare Earths: Including Actinides, Volume 56, is a continuous series of books covering all aspects of rare earth science, including chemistry, life sciences, materials science and physics. The book's main emphasis is on rare earth elements [Sc, Y, and the lanthanides (La through Lu], but whenever relevant, information is also included on the closely related actinide elements. Individual chapters in this release include Lanthanide Molecules for Spin-based Quantum Technologies, Modeling Intramolecular Energy Transfer in Lanthanide Chelates: A Critical Review and Recent Advances, and Superconducting Uranium-Based Materials.

目次

309. Lanthanide molecules for spin-based quantum technologies Guillem Aromi and Olivier Roubeau 310. Modeling intramolecular energy transfer in lanthanide chelates: A critical review and recent advances Albano N. Carneiro Neto, Ercules E. S. Teotonio, Gilberto F. de Sa, Hermi F. Brito, Janina Legendziewicz, Luis D. Carlos, Maria Claudia F. C. Felinto, Paula Gawryszewska, Renaldo T. Moura Jr., Ricardo L. Longo, Wagner M. Faustino and Oscar L. Malta 311. Uranium-based superconducting materials Eteri Svanidze

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v. 20 ISBN 9780444820143

内容説明

Volume 20 completes the second decade of volumes in this series and focuses on the physical aspects of metallic compounds. Research efforts on metallic rare earth compounds started in earnest about 50 years ago and received a significant boost with the discovery of the RCo5 permanent magnets about 12 years later. During this time much has been learned about the structure as well as the electrical, magnetic and thermal properties of approximately 2500 binary rare earth metallic compounds. However, if one considers the possible true ternary compounds and possible pseudo-binary ternary alloys formed by mixing two binary compounds, there is still a wealth of knowledge to be obtained from these still-to-be discovered materials. This volume makes a start in this direction.Chapter one deals with the Fermi surfaces of rare earth (Y, La, Ce,Pr, Nd, Sm, Gd and Yb) intermetallic compounds. It begins with an introduction to the relevant theories required to describe the electrons near the Fermi surface and then to the basic experimental techniques to study these surfaces. The main portion of the chapter is devoted to a comparison of the experimental results with the band structure calculations for a large number of compounds.Chapter two examines the world of thin films of rare earth metals, alloys and compounds. The three main topics covered are the pure metals themselves, metallic alloys and compounds, and metalloid compounds. The next chapter is devoted to hydrogen in metals and their binary compounds RH2 and RH3. One of the critical problems is the purity of the starting rare earth metal itself because phase relations can be greatly affected by impurities and attention istherefore paid to the preparation of specimens and the phase diagrams. Structural properties, kinetics and thermodynamic behavior, as well as electronic, magnetic and thermal properties are reviewed as well. Also examined is the profound influence of hydrogen on the magnetic properties by the mediation of RKKY interaction in these materials. The final chapter is an update on the magnetic behaviors of lanthanide intermetallic compounds, anarea which has seen many new developments in the last 15 years. The chapter is divided into two main parts. Part one is devoted to 3d magnetism where both the 3d metal and lanthanide element contribute to the magnetic behavior, and the second part is concerned with lanthanide magnetism itself.

目次

Preface. Contents of volumes 1-19. 135. Fermi surfaces of intermetallic compounds (Y. Onuki, A. Hasegawa). 136. The intricate world of rare earth thin films: metals, alloys, intermetallic, chemical compounds (M. Gasgnier). 137. Hydrogen in rare earth metals including RH2+x phases (P. Vajda). 138. Magnetic properties of intermetallic compounds (D. Gignoux, D. Schmitt).

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v. 21 ISBN 9780444821782

内容説明

The contributions to this volume focus on selected chemical aspects of rare-earth materials. The topics covered range from a basic treatment of crystalline electric-field effects and chemical interactions in organic solvents, to separation processes, electrochemical beaviors which impact corrosion, oxidation resistance, chemical energy storage and sensor technology, and to analytical procedures.Underlying the most subtle chemical and optical properties of these elements and their compounds in the condensed state are the crystal field effects. This phenomenon in non-metallic compounds is discussed in chapter six. The volume opens with a review of important new solvent extraction procedures as well as emerging alternative separation processes such as photochemical separation, precipitation stripping and supercritical extraction. Scientific and industrial procedures are illustrated. In a further chapter eight major analytical techniques of obtaining accurate trace analysis are examined, tabulated and assessed. The most effective procedures of each are also reviewed. Chapter two considers a wide variety of methods using rare-earth solutions and slats to modify advantageously the costly deterioration of metals and alloys. This topic is expanded in the following chapter, paying particular attention to protection against high-temperature oxidation, sulfidization and hot-salt corrosion. The following two chapters are concerned with the versatility of the rare earths in addressing current technical problems such the use of rare-earth intermetallics, principally LaNi3-based materials, to provide the skyrocketing need for environmetally friendly, usually portable, battery power. The final chapter is a review of the solvation, interaction and coordination of rare-earth salts in a variety of organic solvents including dimethylacetamide, dimethylsulfoxide, various alcohols, acetonitrile and propylenecarbonate under strict anhydrous conditions. A contrast of these interactions with those in which water is present with organic solvents is also made.

目次

Preface. Contents of volumes 1-20. 139. Separation chemistry (R.G. Bautista). 140. Corrosion prevention and control (B.W. Hinton). 141. High-temperature corrosion protection (N.E. Ryan). 142. Rare earth intermetallics for metal-hydrogen batteries (T. Sakai, M. Matsuoka, C. Iwakura). 143. Chemical sensors (G.-y. Adachi, N. Imanaka). 144. Crystal field in non-metallic (rare-earth) compounds (D. Garcia, M. Faucher). 145. Solvation and anion interaction in organic solvents (J.-C.G. Buzli, A. Milicic-Tang). 146. Trace determination of lanthanides in high-purity rare-earth oxides (V. Bhagavathy, T. Prasada Rao, A.D. Damodaran). Author index. Subject index.

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v. 22 ISBN 9780444822888

内容説明

This volume covers various physical aspects of a wide range of rare-earth materials. Magnetic phenomena dominate the contents of the first four chapters which deal with thin films and layered structures, and intermetallic and nonmetallic compounds. The remaining two chapters deal with coherent emission and electronic structure calculations of lanthanide molecules.The first chapter covers the state-of-the-art of the synthesis and properties of thin films of the rare-earth metals and layered superstructures of two rare-earth metals. The following chapter is a review of rare-earth-transition metal nanoscale multilayers and describes the recent advances in our understanding of magnetic structure, interfacial magnetism, and origin of perpendicular magnetic anisotropy of lanthanide-transition-metal nanoscale multilayers. The next chapter deals with one of the important series of rare-earth intermetallic compounds, those which possess the ThNm12-type structure. The authors of the following chapter review the specific magnetic and magnetoelastic properties of certain crystals, which are determined by the localized electronic magnetic moments of the lanthanide ions in the crystal lattice and their interactions with each other and surrounding ions. The chapter on coherent emission differs from other reviews on the subject in that it concentrates on the broader issues. Here the emphasis is on superradiance, superfluorescence, amplification of spontaneous emission by other stimulated emision than the laser effect and coherent spontaneous emission. The final chapter describes the progress that has been made in electronic structure calculations of lanthanide-containing molecules, especially in the last 10 years.

目次

Preface. 147. Synthesis and properties of single-crystal nanostructures (C.P. Flynn, M.B. Salamon). 148. Nanoscale rare earth-transition metal multilayers: magnetic structure and properties (Z.S. Shan, D.H. Sellmyer). 149. The ThNm12-type compounds of rare earths and actinides: structure, magnetic and related properties (W. Suski). 150. Magnetic properties of nonmetallic lanthanide compounds (L.K. Aminov, B.Z. Malkin, M.A. Teplov). 151. Coherent emission in rare-earth materials (F. Auzel). 152. Electronic structure calculations for milecules containing lanthanide atoms (M. Dolg, H. Stoll).

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v. 23 ISBN 9780444825070

内容説明

This volume of the Handbook examines the widely varying range of rare-earth-element involvement on this planet.Chapter one is a summary of recent developments in the use of chemical shifts included in reagents of paramagnetic lanthanide complexes. One of the more important developments that has evolved from the research in this area is the use of lanthanide complexes in magnetic resonance imaging (MRI) in the medical field.The following chapter discusses the theory and application of the consequences of antenna-to-ion energy transfer and its relationship to supramolecular chemistry. Applications of these complexes in fluorimmunoassays and DNA hybridization assays are also discussed.The rationalization of crystal field parametrization is considered in a pedagogical context in the next chapter, thus continuing an ongoing treatment of the spectroscopic properties of the rare-earth elements in the Handbook. The authors emphasize the symmetry aspects of the crystal field and the parametrization of the energy level scheme.In the next chapter the authors present a systematic and encyclopedic discussion on the phosphides of the binary, ternary and quaternary rare earths. Their coverage includes preparation, phase diagrams, structure, as well as chemical and physical properties. The crystallochemical regularities, the nature of the interaction between components in ternary systems, and structural relationships also constitute important aspects of this review.Metal-containing vapor species such as the simple rare-earth halide vapors and vapor complexes MX-RX3 and MX2-RX3 are finding increasing use in halogen lamps and energy storage media for high-power laser systems and for development of recycling/separation processes. This process is considered in the next chapter, in which particular attention is paid to thermodynamic and structural trends, and to characteristic experimental techniques such as absorption and fluorescence spectroscopy.The final chapter is a review of the lanthanide composition of the oceans and the processes that control the lanthanide distribution. Particular attention is given to research on the lanthanide geochemistry of marine hydrothermal vent systems.

目次

Preface. Contents. Contents of volumes 1-22. NMR studies of paramagnetic lanthanide complexes and shift reagents (J.H. Forsberg). Antenna effect in encapsulation complexes of lanthanide ions (N. Sabbatini, M. Guardigli, I. Manet). Rationalization of crystal-field parametrization (C. Goerller-Walrand, K. Binnemans). Phosphides (Y. Kuz'ma, S. Chykhrij). Halide vapors and vapor complexes (S. Boghosian, G.N. Papatheodorou). Marine chemistry and geochemistry of the lanthanides (R.H. Byrne, E.R. Sholkovitz). Author index. Subject index.

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v. 24 ISBN 9780444826077

内容説明

This volume contains a collection of articles dealing with the physics and materials science of mostly metallic rare earth materials. Chapters deal with the formation of amorphous, microcrystalline and quasicrystalline phases by mechanical alloying, rapid solidification and even normal casting operations. As is often the case with these 4f elements, magnetism is a dominant topic and this is reflected in the chapters covering surface magnetism, electron-spin resonance, exchange coupling in lanthanide-transition metal phases and the magnetic behavior of ternary rare-earth stannides, including their crystal structures.

目次

Preface. 159. Surface magnetism of the lanthanides (P. Dowben, D. McIlroy). 160. Mechanical alloying and mechanically induced chemical reactions (P. McCormick). 161. Amorphous, quasicrystalline and nanocrystalline alloys in A1- and Mg-based systems (A. Inoue). 162. Electron spin resonance on localized magnetic moments (B. Elschner, A. Loidl). 163. Intersublattice exchange coupling in the lanthanide-transition-metal intermetallics (N.H. Duc). 164. Stannides of rare earth and transition metals (R.V.Skolozdra).

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v. 25 ISBN 9780444828712

内容説明

Twenty years on and 164 reviews later since the appearance of volume 1 of this prestigious series, the rare earths continue to perplex, if not mystify us. There is no doubt that in the next breakthrough to a higher level of human understanding of nature, the rare earth elements and their compounds will play an important part in its elaboration. The reviews contained in this 25th volume continue this quest.The first chapter reveals the effects of the addition of the rare earths on steel. These elements were introduced to the steel-making industry in the 1920's to affect deoxidization and desulfurization. Today it is possible to extend their usefulness to provide steels with desired characteristics. The description of why and how additions of the rare earths affect micro- and nano-structures in steels which provide these beneficial modifications is explored.Chapter two reviews ternary and higher-order nitride materials. The synthesis of ternary compounds is examined and the products are categorized by their composition and the nature of the chemical bonding they exhibit. The structures of the compounds are discussed where possible.The spectral intensities of f-f transitions in lanthanide compounds are discussed at length in the following chapter. The authors present an exhaustive consideration of the unique appearance of intraconfigurational electronic transitions in f-type materials, particularly the lanthanides.The final chapter reviews the prodigious literature on the organometallic complexes of the f-elements. The authors consider the main classes of complexes of both the lanthanide and actinide organometallics, and synthesis and structure are dealt with in particular.

目次

Preface. Contents of volumes 1-24. 165. Rare earths in steels (H. Nagai). 166. Ternary and higher order nitride materials (R. Marchand). 167. Spectral intensities of f-f transitions (C. Goerller-Walrand, K. Binnemans). 168. Organometallic complexes of the f-elements (G. Bombieri, G. Paolucci). Author index. Subject index.

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v. 5 ISBN 9780444863751

内容説明

The rare earths play a unique role in science. These seventeen related elements afford a panoply of subtle variations deriving from the systematic development of their electronic configurations, allowing a test of theory with excellent resolution. In contrast they find widespread use in even the most mundane processes such as steel making, for polishing materials and gasoline cracking catalysts. In between are exotic uses such as TV screen phosphors, lasers, high strength permanent magnets and chemical probes. This multi-volume handbook covers the entire rare earth field in an integrated manner. Each chapter is a comprehensive up-to-date, critical review of a particular segment of the field. The work offers the researcher and graduate student alike, a complete and thorough coverage of this fascinating field.

目次

Preface. 41. Rare earth alloys and compounds as thin films (M. Gasgnier). 42. Transport properties (electrical resistivity, thermoelectric power and thermal conductivity) of rare earth intermetallic compounds (E. Gratz and M.J. Zuckermann). 43. Adsorption and catalysis on rare earth surfaces (F.P. Netzer and E. Bertel). 44. Defects and phase transformation near room temperature in rare earth sesquioxides (C. Boulesteix). 45. Rare earth fluorides (O. Greis and J.M. Haschke). 46. Spectroscopic properties of triply ionized lanthanides in transparent host crystals (C.A. Morrison and R.P. Leavitt). Subject Index.

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v. 6 ISBN 9780444865922

内容説明

The rare earths play a unique role in science. These seventeen related elements afford a panoply of subtle variations deriving from the systematic development of their electronic configurations, allowing a test of theory with excellent resolution. In contrast they find widespread use in even the most mundane processes such as steel making, for polishing materials and gasoline cracking catalysts. In between are exotic uses such as TV screen phosphors, lasers, high strength permanent magnets and chemical probes. This multi-volume handbook covers the entire rare earth field in an integrated manner. Each chapter is a comprehensive up-to-date, critical review of a particular segment of the field. The work offers the researcher and graduate student alike, a complete and thorough coverage of this fascinating field.

目次

Preface. 47. Hydrogen absorption in intermetallic compounds (K.H.J. Buschow). 48. Crystal structures and crystal chemistry of ternary rare earth-transition metal borides, silicides and homologues (E. Parthe and B. Chabot). 49. Phase equilibria in ternary and higher order systems with rare earth elements and boron (P. Rogl). 50. Preparation of divalent ytterbium and samarium derivatives and their use in organic chemistry (H.B. Kagan and J.L. Namy). Subject Index.

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v. 7 ISBN 9780444868510

内容説明

The rare earths play a unique role in science. These seventeen related elements afford a panoply of subtle variations deriving from the systematic development of their electronic configurations, allowing a test of theory with excellent resolution. In contrast they find widespread use in even the most mundane processes such as steel making, for polishing materials and gasoline cracking catalysts. In between are exotic uses such as TV screen phosphors, lasers, high strength permanent magnets and chemical probes. This multi-volume handbook covers the entire rare earth field in an integrated manner. Each chapter is a comprehensive up-to-date, critical review of a particular segment of the field. The work offers the researcher and graduate student alike, a complete and thorough coverage of this fascinating field.

目次

Preface. 51. Phase equilibria in ternary and higher order systems with rare earth elements and silicon (P. Rogl). 52. Amorphous alloys (K.H.J. Buschow). 53. Organometallic compounds of the rare earths (H. Schumann and W. Genthe). Subject Index.

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v. 8 ISBN 9780444869715

内容説明

The rare earths play a unique role in science. These seventeen related elements afford a panoply of subtle variations deriving from the systematic development of their electronic configurations, allowing a test of theory with excellent resolution. In contrast they find widespread use in even the most mundane processes such as steel making, for polishing materials and gasoline cracking catalysts. In between are exotic uses such as TV screen phosphors, lasers, high strength permanent magnets and chemical probes. This multi-volume handbook covers the entire rare earth field in an integrated manner. Each chapter is a comprehensive up-to-date, critical review of a particular segment of the field. The work offers the researcher and graduate student alike, a complete and thorough coverage of this fascinating field.

目次

Preface. 54. Intra rare earth binary alloys: phase relationships, lattice parameters and systematics (K.A. Gschneidner, Jr. and F.W. Calderwood). 55. Polarographic analysis of the rare earths (X. Gao). 56. Inorganic complex compounds I (M. Leskela and L. Niinisto). 57. Implications in organic synthesis (J.R. Long). Errata. Subject index.

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v. 9 ISBN 9780444870452

内容説明

The rare earths play a unique role in science. These seventeen related elements afford a panoply of subtle variations deriving from the systematic development of their electronic configurations, allowing a test of theory with excellent resolution. In contrast they find widespread use in even the most mundane processes such as steel making, for polishing materials and gasoline cracking catalysts. In between are exotic uses such as TV screen phosphors, lasers, high strength permanent magnets and chemical probes. This multi-volume handbook covers the entire rare earth field in an integrated manner. Each chapter is a comprehensive up-to-date, critical review of a particular segment of the field. The work offers the researcher and graduate student alike, a complete and thorough coverage of this fascinating field.

目次

Preface. Contents of volumes 1-8. 58. Excited state phenomena in vitreous materials (R. Reisfeld and C.K. Jorgensen). 59. Inorganic complex compounds II (L. Niinistoe and M. Leskela). 60. Complexes with synthetic ionophores (J.-C.G. Bunzli). 61. Rare earth coordination catalysis in stereospecific polymerization (Zhiquan Shen and Jun Ouyang). Errata. Subject Index.

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v. 12 ISBN 9780444871053

内容説明

The rare earths play a unique role in science. These seventeen related elements afford a panoply of subtle variations deriving from the systematic development of their electronic configurations, allowing a test of theory with excellent resolution. In contrast they find widespread use in even the most mundane processes such as steel making, for polishing materials and gasoline cracking catalysts. In between are exotic uses such as TV screen phosphors, lasers, high strength permanent magnets and chemical probes. This multi-volume handbook covers the entire rare earth field in an integrated manner. Each chapter is a comprehensive up-to-date, critical review of a particular segment of the field. The work offers the researcher and graduate student alike, a complete and thorough coverage of this fascinating field.

目次

Preface. Contents of volumes 1 - 11. 80. Preparation and crystal growth of rare earth elements and intermetallic compounds (J.S. Abell). 81. Growth of single crystals from molten metal fluxes (Z. Fisk and J.P. Remeika). 82. Physical properties of R 2 Fe 14 B-based alloys (E. Burzo and H.R. Kirchmayr). 83. Magnetic properties of ternary intermetallic compounds of the RT 2 X 2 type (A. Szytula and J. Leciejewicz). 84. Spin glasses (H. Maletta and W. Zinn). 85. Liquid metals and alloys (J. van Zytveld). 86. Thermodynamic properties of gaseous species (M.S. Chandrasekharaiah and K.A. Gingerich). 87. Laser spectroscopy (W.M. Yen). Subject index.

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v. 13 ISBN 9780444885470

内容説明

The justification for combining reports of studies of the rare earths from the disciplines of physics and chemistry can be found in the historical reliance each has had upon the other in the apprehension of these mysterious substances. This was stated in the preface to the first four volumes of the series and is even more true today. For a time, specializations thrived more or less independently but as theory has become more comprehensive it has become possible to progress towards unification of these specializations. Nowhere has this need for a unified approach been more evident than in the study of the rare earths where the insights won in one area become a vision to another resulting in the illumination of the whole. The lanthanides are particularly suited to multidisciplinary study because of the unity derived from the progressive filling of the 4f orbitals by electrons. This introduces many profound physical phenomena such as magnetism as well as the frequently subtle chemical variation that affords fine-tuning of our understanding of nature. Volume 13 of the Handbook continues to promote this interactive approach to the science of the rare earths.

目次

Preface. Contents of volumes 1-12. 88. Phase equilibria and crystal chemistry in ternary rare earth systems with metallic elements (E.I. Gladyshevsky, O.I. Bodak and V.K. Pecharsky). 89. Phase equilibrium and crystal chemistry in rare earth ternary systems with the chalcogenide elements (A.A. Eliseev and G.M. Kuzmichyeva). 90. The systems 2 O 3 -M 2 O 3 M'O (N. Kimizuka, E. Takayama-Muromachi and K. Siratori). 91. Elemental analysis by atomic emission and mass spectrometry with inductively coupled plasmas (R.S. Houk). 92. Rare earth elements in biological systems (P.H. Brown, A.H. Rathjen, R.D. Graham and D.E. Tribe). Errata. Subject index.

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v. 14 ISBN 9780444887436

内容説明

This volume differs somewhat from the previous volumes in the series in that there is a strong emphasis on the physical aspects and not so much on the chemical aspects of intermetallic compounds. Two of the chapters are concerned with relatively new experimental methods of studying rare earth metallic phases - high energy neutron spectroscopy and light scattering. In these chapters the authors explain the new kinds of information one obtains from these techniques and how this complements the knowledge previously gleaned from the more common measurements - such as NMR, heat capacities, magnetic susceptibility, transport and elastic properties. One of the remaining three chapters deals with NMR studies of rare earth intermetallics and the final two chapters are concerned, not so much with a particular experimental technique, but with physical phenomena that occur in these compounds: the electron-phonon interaction and heavy fermion behavior.

目次

Preface. Contents of volumes 1-13. 93. Intermultiplet transitions using neutron spectroscopy (R. Osborn, S.W. Lovesey, A.D. Taylor and E. Balcar). 94. NMR in intermetallic compounds (E. Dormann). 95. Light scattering in intermetallic compounds (E. Zirngiebl and G. Guntherodt). 96. The electron-phonon interaction in intermetallic compounds (P. Thalmeier and B. Luthi). 97. Heavy fermions (N. Grewe and F. Steglich). Subject index.

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v. 15 ISBN 9780444889669

内容説明

Volume 15 in this series continues the voyage of discovery started almost a decade ago.Chapter 98 adds significantly to an evaluation of systematic, experimental low-temperature studies of the ambivalent behaviours of cerium (ferromagnetism, antiferromagnetism, spin glass, superconductivity etc.) which depend upon its environment in materials. The conclusions arrived at should provide new data against which the theory can be advanced.The next chapter provides a review of rare earth carbides, emphasizing the thermodynamics, phase diagrams, crystal structures and physical properties. The binary rare earth carbides present an exceptionally wide range of compositions and structures both as solids and gas-phase molecules. Complex carbides with additional metal and non-metal components also receive attention.Metal-rich halides (i.e. compounds with an X/R ratio <2) are the subject of the next chapter. The compounds are classified according to their structure and chemical bonding characteristics and their electrical and magnetic properties are also reviewed.Chapter 101 deals with the preparation, structure, chemical and physical properties of heavy-metal fluoride glasses. Large amounts of rare earths can be added into these, and they possess a great potential for optical applications in the mid-infrared range as fiber optic glasses for communication and transmission of information, optical wave guides, fiber lasers and sensors.The following chapter explores the chemical kinetics of solvent and ligand exchange in aqueous lanthanide solutions. A wealth of tabulated information on rate and equilibrium constants is provided in textual and tabular form. Chapter 103 considers the fundamentally important reactions of the lanthanide ions with water. These interactions are discussed for both solids and solutions. The hydrated species are considered in detail for the aqueous solution, revealing the consequences of the lanthanide series sequence.The concluding chapter reviews macrocyclic complexes formed by rare earth and dioxouranium ions as templates. Synthetic trends and reactivity are considered as well as potential uses of these intriguing wrap-around structures.

目次

Preface. Contents volumes 1-14. 98. Low temperature behaviors of cerium compounds. Heat capacity of binary and related intermetallics (J.G. Sereni). 99. Rare earth carbides (G.-Y. Adachi, N. Imanaka and Z. Fuzhong). 100. Metal-rich halides - Structure, bonding and properties (A. Simon et al.). 101. Fluoride glasses (R.M. Almeida). 102. Kinetics of complexation and Redox reactions of the lanthanides in aqueous solutions (K.L. Nash and J.C. Sullivan). 103. Hydration and hydrolysis of lanthanides (E.N. Rizkalla and G.R. Choppin). 104. Macrocyclic complexes of the lanthanide (III), yttrium (III), and dioxouranium (VI) ions from metal-templated syntheses (L.M. Vallarino). Subject index.

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v. 16 ISBN 9780444897824

内容説明

Hardbound. The first chapter focuses on one aspect of one of the most stimulating topics in the whole of lanthanide science: the dual valence state elements Ce, Pr and Tb (valences of 3 and 4) and Sm, Eu, Tm and Yb (valences of 2 and 3). The authors bring us up to date on the status of our knowledge of valence fluctuation and heavy fermion 4f systems as gleaned from neutron scattering experiments. The major topics include cerium-based valence fluctuation systems, cerium-based heavy fermion materials and ytterbium-based materials. The remaining quarter of the chapter deals with samarium-, europium- and thulium-based systems.The next chapter deals with the thermal conductivity of rare earth containing materials and is the first major review on this topic. A great deal of information can be obtained on the electrical and magnetic nature of these solids, because of the varied response of the thermal conductivity to long range magnetic order,

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cumulative index, vols. 1-15 ISBN 9780444899651

内容説明

The first volumes of the "Handbook on the Physics and Chemistry of Rare Earths" were published in 1978 and 1979. Since then, approximately one volume per year has been published, making a total of 15 volumes to date, containing 104 chapters with little duplication of topics covered. Some of the discoveries of marked technological importance of the 1980s include the excellent permanent magnetic properties of the Nd-Fe-B alloys, the magneto-optic behaviour of Co (or Fe)-Gd (or Tb) amorphous thin films, and the existence of superconductivity at temperatures well above liquid nitrogen (77 K) in YBa2Cu3O7-x; and these topics have been reviewed in some of the 104 chapters. To increase the usefulness of this serial publication, this volume contains comprehensive subject and author indexes for the whole series, up to and including volume 15. The value of the index volume has been enhanced by the inclusion of a comprehensive tabulation of most of the physical properties of the rare earth metals (14 tables). Also included is an errata listing all corrections of mistakes discovered while compiling this index, and those errors pointed out by authors, editors and users of the Handbook.

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詳細情報

• NII書誌ID(NCID): BA00144627
• ISBN:
  • 0444850228
  • 0444863753
  • 0444865926
  • 0444868518
  • 0444869719
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• LCCN: 78012371
• 出版国コード: ne
• タイトル言語コード: eng
• 本文言語コード: eng
• 出版地: Amsterdam ; Tokyo,New York, N.Y., U.S.A.
• ページ数/冊数: v.
• 大きさ: 24-25 cm
• 分類:
  • LCC : QD172.R2
  • DC19 : 546.4
  • NDC7 : 436.3
• 件名:
  • LCSH : Earths, Rare