Organic reactions

Author(s)

• Adams, Roger
• Kende, Andrew S.
• Dauben, William G.
• Paquette, Leo A.
• Overman, Larry E.
• Denmark, Scott E.

Bibliographic Information

Organic reactions

Roger Adams, editor-in-chief

Wiley, c1942-

• v. 1
• v. 2
• v. 3
• v. 4
• v. 5
• v. 6
• v. 7
• v. 8
• v. 9
• v. 10
• v. 11
• v. 12
• v. 13
• v. 14
• v. 15
• v. 16
• v. 17
• v. 18
• v. 19
• v. 20
• v. 21
• v. 22
• v. 23
• v. 24
• v. 25
• v. 26
• v. 27
• v. 28
• v. 29
• v. 30
• v. 31
• v. 32
• v. 33
• v. 34
• v. 35
• v. 36
• v. 37
• v. 38
• v. 39
• v. 40
• v. 41
• v. 42
• v. 43
• v. 44
• v. 45
• v. 46
• v. 47
• v. 48
• v. 49
• v. 50
• v. 51
• v. 52
• v. 53
• v. 54
• v. 55
• v. 56
• v. 57
• v. 58
• v. 59
• v. 60
• v. 61
• v. 62
• v. 63
• v. 64
• v. 65
• v. 66
• v. 67
• v. 68
• v. 69
• v. 70
• v. 71
• v. 72
• v. 73
• v. 74
• v. 75
• v. 76
• v. 77
• v. 78
• v. 79
• v. 80
• v. 81
• v. 82
• v. 83
• v. 84
• v. 85
• v. 86
• v. 87
• v. 88
• v. 89
• v. 90
• v. 91
• v. 92
• v. 93
• v. 94
• v. 95
• v. 96
• v. 97
• v. 98
• v. 99
• v. 100

Note

Vol. 1-10 / Roger Adams, editor-in-chief

Vol. 11-16 / Arthur C. Cope, editor-in-chief

Vol. 17-32 / William G. Dauben, editor-in-chief

Vol. 33-37 / Andrew S. Kende, editor-in-chief

Vol. 38-55 / Leo A. Paquette, editor-in-chief

Vol. 56-70 / Larry E. Overman, editor-in-chief

Vol. 71- / Scott E. Denmark, editor-in-chief

Description and Table of Contents

Volume

v. 67 ISBN 9780470041451

Description

Organic Reactions is a comprehensive series of volumes composed of chapters devoted to important synthetic reactions. For each volume, the chapter authors are world-renowned experts with extensive hands-on experience in the field. The chemistry is presented from a preparative point of view and particular attention is given to reaction limitations, interfering influences, effects of chemical structure, and the selection of experimental conditions.

Table of Contents

1. CATALYTIC ENANTIOSELECTIVE ALDOL ADDITION REACTIONS (Erick M. Carreira, Alec Fettes, and Christiane Marti). 2. BENZYLIC ACTIVATION AND STEREOCHEMICAL CONTROL IN REACTIONS OF TRICARBONYL(ARENE)CHROMIUM COMPLEXES (Motokazu Uemura). CUMULATIVE CHAPTER TITLES BY VOLUME. AUTHOR INDEX, VOLUMES 1-67. CHAPTER AND TOPIC INDEX, VOLUMES 1-67.

Volume

v. 68 ISBN 9780470098981

Description

Organic Reactions is a collection of chapters, each devoted to a single reaction or a definitive phase of a reaction of wide applicability, with particular attention given to limitations, interfering influences, effects of structure, and the selection of experimental techniques. Volume 68 includes two chapters on important reactions: Chapter 1 on Contrimerizations of Acetylenic Compounds by Max Malacria, and Chapter 2 on Glycosylation on Polymer Supports by Peter Seeberger Includes tables that contain all possible examples of the reactions under consideration Each reaction is fully referenced to the primary literature

Table of Contents

1. COTRIMERIZATIONS OF ACETYLENIC COMPOUNDS (Nicolas Agenet, Olivier Buisine, Franck Slowinski, Vincent Gandon, Corinne Aubert, and Max Malacria) 2. GLYCOSYLATION ON POLYMER SUPPORTS (Simone Bufali and Peter H. Seeberger). CUMULATIVE CHAPTER TITLES BY VOLUME . AUTHOR INDEX, VOLUMES 1-68 . CHAPTER AND TOPIC INDEX, VOLUMES 1-68 .

Volume

v. 71 ISBN 9780470098998

Description

Organic Reactions is a collection of chapters, each devoted to a single reaction or a definitive phase of a reaction of wide applicability, with particular attention given to limitations, interfering influences, effects of structure, and the selection of experimental techniques. Volume 71 includes a chapter on Ionic and Organometallic-Catalyzed Organosilane Reductions. Includes tables that contain all possible examples of the reactions under consideration Each reaction is fully referenced to the primary literature

Table of Contents

Chapter 1. Ionic and Organometallic-Catalyzed Organosilane Reductions (Gerald L. Larson and James L. Fry). Cumulative Chapter titles by Volume. Author Index, Volumes 1-71. Chapter and Topic Index, Volumes 1-71.

Volume

v. 69 ISBN 9780470223970

Description

Dental Implants for Hygienists and Therapists An essential handbook for dental hygienists and therapists seeking a comprehensive resource covering dental implants Dental Implants for Hygienists and Therapists delivers an accessible and informative exploration of the fundamental principles of tooth replacement with dental implants, as well as the science and theory that underlies modern implants, and the factors impacting their success and survival. The book offers robust guidance on the assessment of peri-implant tissues in health and in disease, an evidence-based approach to their management, and instruction on when a referral should be made. It also covers function and anatomy in health and disease around dental implants and the supporting tissues as well as the factors that influence predictability and patient management. This book includes: Thorough introductions to the history of dental implants and osseointegration, including the difference between success and survival Comprehensive exploration of one-piece and two-piece implant systems, patient selection and indications for implant treatment Practical discussions of surgical (including augmentation) and prosthodontic protocols and peri-implant tissues In-depth examinations of maintenance care, including the management of peri-implant disease with non-surgical and surgical treatment, and the role of the hygienist Dental Implants for Hygienists and Therapists is invaluable to dental hygienists and therapists seeking a one-stop resource on dental implantology

Table of Contents

1. Dioxirane Oxidations of Compounds Other Than Alkenes 1 Waldemar Adam, Cong-Gui Zhao, and Kavitha Jakka 2. Electrophilic Fluorination With N-F Reagents 347 Jerome Baudoux and Dominique Cahard Cumulative Chapter Titles By Volume 673 Author Index, Volumes 1-69 687 Chapter And Topic Index, Volumes 1-69 693

Volume

v. 70 ISBN 9780470254530

Description

Organic Reactions is a collection of chapters, each devoted to a single reaction or a definitive phase of a reaction of wide applicability, with particular attention given to limitations, interfering influences, effects of structure, and the selection of experimental techniques. Volume 70 includes two chapters, the first takes a look at the Catalytic Asymmetric Strecker Reaction, the second at the Synthesis of Phenols and Quinones via Fischer Carbene Complexes. Includes tables that contain all possible examples of the reactions under consideration Each reaction is fully referenced to the primary literature

Table of Contents

1. THE CATALYTIC ASYMMETRIC STRECKER REACTION (Masakatsu Shibasaki, Motomu Kanai, and Tsuyoshi Mita). 2. THE SYNTHESIS OF PHENOLS AND QUINONES VIA FISCHER CARBENE COMPLEXES (Marcey L. Waters and William D. Wulff ). CUMULATIVE CHAPTER TITLES BY VOLUME. AUTHOR INDEX, VOLUMES 1-70. CHAPTER AND TOPIC INDEX, VOLUMES 1-70.

Volume

v. 72 ISBN 9780470423745

Description

For all volumes: the volumes of Organic Reactions are collections of chapters each devoted to a single reaction or a definitive phase of a reaction, of wide applicability. The authors have had experience with the processes surveyed. The subjects are presented from the preparative viewpoint and particular attention is given to limitations, interfering influences, effects of structure and the selection of experimental techniques. Each chapter includes several detailed procedures illustrating the significant modifications of the method. Each chapter contains tablets that include all the examples of the reaction under consideration that the author has been able to find.

Table of Contents

CHAPTER PAGE. 1. ELECTROPHILIC AMINATION OF CARBANIONS, ENOLATES, AND THEIR SURROGATES (Engelbert Ciganek). 2. DESULFONYLATION REACTIONS (Diego A. Alonso and Carmen Najera). CUMULATIVE CHAPTER TITLES BY VOLUME. AUTHOR INDEX, VOLUMES 1-72. CHAPTER AND TOPIC INDEX, VOLUMES 1-72.

Volume

v. 73 ISBN 9780470436905

Description

Allylic boron compounds have gained a prominent position as a truly practical class of synthetic reagents in the past twenty-five years. Their main application as a method for the stereoselective synthesis of homoallylic alcohols by allyl-transfer to carbonyl compounds is essentially unmatched. In this process, a new carbon-carbon bond is formed, and up to two new stereogenic centers are created in a predictably controlled manner. Highly effective and general enantioselective variants are available, with countless applications in the total syntheses of polyacetate and polypropionate natural products. Furthermore, the residual allylic unit can be manipulated through a number of different transformations such as oxidative cleavage, olefin metathesis, hydrometalations, and many others. The discovery of Lewis and Bronsted acid catalyzed manifolds recently, has opened new doors for further development of this important reaction. This book provides an up-to-date, comprehensive survey of the literature of this rich chemistry as it pertains to organic synthesis. Consistent with the goal of Organic Reactions, the content and presentation emphasize the preparative aspects of the reactions, giving considerable attention to the scope and limitations of the individual transformations along with detailed experimental procedures. A tabular survey of all examples of carbonyl allylboration used in organic synthesis is presented in nine tables organized by type of allylic boron reagent with listings within each table according to increasing carbon number of the carbonyl substrates. The literature is covered through December 2010, including a new listing of nearly 200 literature citations that supplement the original coverage of 834 references used in the earlier hard cover version of the chapter. Allylboration of Carbonyl Compounds is intended to be a useful, easily read reference book for all practitioners of synthetic organic chemistry working in academic and industrial laboratories.

Table of Contents

1. Allylboration of Carbonyl Compounds 1 Hugo Lachance and Dennis G. Hall Cumulative Chapter Titles by Volume 575 Author Index, Volumes 1-73 589 Chapter and Topic Index, Volumes 1-73 595

Volume

v. 74 ISBN 9780470530481

Description

This series provides the most comprehensive and highly focused treatment of important organic reactions currently available. This volume in the prestigious series includes chapters covering two of the most fundamental processes in organic chemistry: oxidation and reduction. The coverage also includes tables containing all possible examples of the reactions under consideration, as well as references to the primary literature, reaction conditions, products, and yields where available for each reaction. Written by world-reowned experts with extensive hands-on experience in the field, Organic Reactions, Volume 74 is a key working resource.

Table of Contents

1. CATALYTIC ASYMMETRIC HYDROGENATION OF C=N FUNCTIONS (Hans-Ulrich Blaser and Felix Spindler). 2. OXOAMMONIUM- AND NITROXIDE-CATALYZED OXIDATIONS OF ALCOHOLS (James M. Bobbitt, Christian Bruckner, and Nabyl Merbouch). 3. ASYMMETRIC EPOXIDATION OF ELECTRON-DEFICIENT ALKENES (Michael J. Porter and John Skidmore). CUMMULATIVE CHAPTER TITLES BY VOLUME. AUTHRO INDEX, VOLUMES 1-74. CHAPTER AND TOPIC INDEX, VOLUMES 1-74.

Volume

v. 76 ISBN 9780470638439

Description

Volume 76 in the venerable Organic Reactions series comprises three chapters that cover the ever-increasing emphasis of transition metal catalysis in organic synthesis. These three chapters represent some of the most important transformations that enable the construction of carbon-carbon bonds, heterocycles and carbon-heteratom bonds. This volume features a comprehensive treatment of transition metal (palladium, nickel, copper) catalyzed a-arylation of enolates derived from many common functional groups such as ketones, aldehydes, esters and nitriles (Prim, Marque, Gaucher, Campagne) including enantioselective variants; palladium catalyzed cyclization to form indoles (Cacchi, Fabrizi, Goggiamani) one of the most prevalent and important classes of heterocycles in natural products and pharmaceutical agents; and an overview of a newly developed dihydroxylation reaction of alkenes (Donohoe, Bataille, Innocenti) that uses hydrogen bonding interactions to direct the delivery of an osmium catalyst with high selectivity. As with all Organic Reactions chapters, these reviews emphasize the preparative aspects of the featured transformation and contain comprehensive compilations of all known examples in the tables.

Table of Contents

1. HYDROGEN-BONDING-MEDIATED DIRECTED OSMIUM DIHYDROXYLATION Timothy J. Donohoe, Carole J. R. Bataille, and Paolo Innocenti1 2. TRANSITION-METAL-CATALYZED -ARYLATION OF ENOLATES Damien Prim, Sylvain Marque, Anne Gaucher, and Jean-Marc Campagne 49 3. INDOLES VIA PALLADIUM-CATALYZED CYCLIZATION Sandro Cacchi, Giancarlo Fabrizi, and Antonella Goggiamani 281 CUMULATIVE CHAPTER TITLES BY VOLUME535 AUTHOR INDEX, VOLUMES 1-76 551 CHAPTER AND TOPIC INDEX, VOLUMES 1-76 557

Volume

v. 75 ISBN 9780470889077

Description

This series provides the most comprehensive and highly focused treatment of important organic reactions currently available. All volumes of Organic Reactions (including this one) are collections of chapters each devoted to a single reaction or a definitive phase of a reaction, of wide applicability. The authors have had experience with the processes surveyed. The subjects are presented from the preparative viewpoint and particular attention is given to limitations, interfering influences, effects of structure, and the selection of experimental techniques. Each chapter includes several detailed procedures illustrating the significant modifications of the method.

Table of Contents

CHAPTER PAGE 1. HYDROCYANATION OF ALKENES AND ALKYNES T. V. RajanBabu1 2. INTERMOLECULAR C-H INSERTIONS OF CARBENOIDS Huw M. L. Davies and Phillip M. Pelphrey 75 3. CROSS-COUPLING WITH ORGANOSILICON COMPOUNDS Wen-Tau T. Chang, Russell C. Smith, Christopher S. Regens, Aaron D. Bailey, Nathan S. Werner, and Scott E. Denmark 213 4. THE AZA-COPE/MANNICH REACTION Larry E. Overman, Philip G. Humphreys, and Gregory S. Welmaker 747 CUMULATIVE CHAPTER TITLES BY VOLUME 821 AUTHOR INDEX, VOLUMES 1-75 835 CHAPTER AND TOPIC INDEX, VOLUMES 1-75 841

Volume

v. 25 ISBN 9780471017417

Description

The volumes of Organic Reactions are collections of chapters each devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure, and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.

Table of Contents

THE RAMBERG-BLACKLUND REARRANGEMENT (Leo A. Paquette). Synthetic Application of Phosphoryl-Stabilized Anons (William S.Wadsworth Jr.). Hydrocyanation of Conjugated Carbonyl Compounds (Wataru Nagata& Mitsuru Yoshioka). Author Index, Volumes 1-25. Chapter and Topic Index, Volumes 1-25. Subject Index. Volume 25.

Volume

v. 45 ISBN 9780471031611

Description

The volumes in this series are collections of chapters each devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The subjects are presented from a preparative viewpoint, and particular attention is given to limitations, interfering influences, effects of structure, and the selection of experimental techniques.

Table of Contents

Photocyclization of Stilbenes and Related Molecules (F. Mallory & C. Mallory). Olefin Synthesis by Deoxygenation of Vicinal Dials (E. Block). Author Index. Chapter and Topic Index. Subject Index.

Volume

v. 26 ISBN 9780471052098

Description

The volumes of Organic Reactions are collections of chapters each devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.

Table of Contents

Heteroatom-Facilitated Lithiations (H. Gschwend and R. Rodriguez). Intramolecular Reactions of Diazocarbonyl Compounds (S. Burke and P. Grieco). Author Index, Volumes 1-26. Chapter and Topic Index, Volumes 1-26. Subject Index, Volume 26.

Volume

v. 46 ISBN 9780471086192

Description

The volumes in this series are collections of chapters each devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The subjects are presented from a preparative viewpoint, and particular attention is given to limitations, interfering influences, effects of structure, and the selection of experimental techniques.

Table of Contents

Tin (II) Enolates in the Aldol, Michael, and Related Reactions (T.Mukaiyama & S. Kobayashi). The [2,3]-Wittig Reaction (T. Nakai & K. Mikami). Reductions with Samarium (II) Iodide (G. Molander). Cumulative Chapter Titles by Volume. Indexes.

Volume

v. 27 ISBN 9780471096573

Description

The volumes of Organic Reactions are collections of chapters each devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.

Table of Contents

Allylic and Benzylic Carbanions Substituted by Heteroatoms. (Jean Francois Biellmann and Jean Bernard Ducep). Palladium-Catalyzed Vinylation of Organic Halides (Richard F. Heck). Author Index, Volumes 1-27. Chapter and Topic Index, Volumes 1-27. Subject Index, Volume 27.

Volume

v. 58 ISBN 9780471105909

Description

Organic Reactions is a comprehensive series of volumes composed of chapters devoted to important synthetic reactions. Each chapter includes detailed procedures illustrating the significant modifications of the chemical reaction as well as tables including all the pertinent examples.

Table of Contents

Simmons-Smith Cyclopropanation Reaction (A. Charette & A. Beauchemin). Preparation and Applications of Functionalized Organozinc Compounds (P. Knochel, et al.). Cumulative Chapter Titles by Volume. Author Index, Volumes 1-58. Chapter and Topic Index, Volumes 1-58.

Volume

v. 47 ISBN 9780471117377

Description

The latest volume in this series for organic chemists in industry presents critical discussions of widely used organic reactions or particular phases of a reaction. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. The work includes tables that contain all possible examples of the reaction under consideration. Detailed procedures illustrate the significant modifications of each method.

Table of Contents

Lateral Lithiation Reactions Promoted by Heteroatomic Substituents(R. Clark & A. Jahangir). The Intramolecular Michael Reaction (R. Little, et al.). Cumulative Chapter Titles by Volume. Indexes.

Volume

v. 48 ISBN 9780471146995

Description

The latest volume in this series for organic chemists in industry presents critical discussions of widely used organic reactions or particular phases of a reaction. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.

Table of Contents

Asymmetric Epoxidation of Allylic Alcohols: The Katsuki-Sharpless Epoxidation Reaction (T. Katsuki & V. Martin). Radical Cyclization Reactions (B. Giese, et al.). Cumulative Chapter Titles by Volume. Indexes.

Volume

v. 49 ISBN 9780471156550

Description

The latest volume in this series for organic chemists in industry presents critical discussions of widely used organic reactions or particular phases of a reaction. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.

Table of Contents

The Vilsmeier Reaction of Fully Conjugated Carbocycles and Heterocycles (G. Jones & S. Stanforth). [6 + 4] Cycloaddition Reactions (J. Rigby). Carbon-Carbon Bond-Forming Reactions Promoted by Trivalent Manganese (G. Melikyan). Cumulative Chapter Titles by Volume. Indexes.

Volume

v. 50 ISBN 9780471156574

Description

The latest volume in this series for organic chemists in industry presents critical discussions of widely used organic reactions or particular phases of a reaction. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.

Table of Contents

The Stille Reaction (V. Farina, et al.). Cumulative Chapter Titles by Volume. Indexes.

Volume

v. 15 ISBN 9780471171683

Description

The volumes of Organic Reactions are collections of chapters each devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure, and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.

Table of Contents

1. The Dieckmann Condensation--John P. Schaefer and Jordan J.Bloomfield. 2. The Knoevenagel Condensation--G. Jones Author Index, Volumes 1-15 Chapter Index, Volumes 1-15 Subject Index, Volume 15

Volume

v. 16 ISBN 9780471171690

Description

The volumes of Organic Reactions are collections of chapters each devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure, and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.

Table of Contents

The Aldol Condensation Author Index, Volumes 1-16 Chapter Index, Volumes 1-16 Subject Index, Volume 16

Volume

v. 59 ISBN 9780471176558

Description

Organic Reactions is a comprehensive series of volumes composed of chapters devoted to important synthetic reactions. The subjects are presented from the preparative viewpoint and particular attention is given to limitation, interfering influences, effects of structure, and the selection of experimental techniques.

Table of Contents

Reductive Aminations of Carbonyl Compounds with Borohydride and Borane Reducing Agents (Ellen W. Baxter & Allen B. Reitz). Cumulative Chapter Titles by Volume. Author Index, Volumes 1-59. Chapter and Topic Index, Volumes 1-59.

Volume

v. 51 ISBN 9780471183945

Description

The latest volume in this series presents critical discussions of widely used organic reactions or particular phases of a reaction. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. The volume includes tables that contain all possible examples of the reaction under consideration.

Table of Contents

Asymmetric Aldol Reactions Using Boron Enolates (C. Cowden & I.Paterson). The Catalyzed proportional to -Hydroxyalkylation and proportionalto -Aminoalkylation of Activated Olefins (The Morita-Baylis-HillmanReaction) (E. Ciganek). (4 + 3) Cycloaddition Reactions (J. Rigby & F. Pigge). Cumulative Chapter Titles by Volume. Indexes.

Volume

v. 52 ISBN 9780471183952

Description

The volumes of Organic Reactions are collections of chapters, eachdedicated to a singled reaction or definitive phase of a reactionof wide applicability. The subject is presented from thepreparative viewpoint & particular attention is given tolimitations, interfering influences, effects of structure & theselection of experimental techniques.

Table of Contents

The Retro-Diels-Alder Reaction, Part I: C-C Dienophiles (B.Rickborn). Enantioselective Reduction of Ketones (S. Itsuno). Cumulative Chapter Titles by Volume. Indexes.

Volume

v. 17 ISBN 9780471196150

Description

The volumes of Organic Reactions are collections of chapters each devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure, and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.

Table of Contents

1. The Synthesis of Substituted Ferrocenes and Other phi-Cyclopentadienyl-Transition Metal Compounds--Donald E. Bublitz and Kenneth L. Rinehart, Jr 2. The gamma-Alkylation and gamma-Arylation of Dianions of beta-Dicarbonyl Compounds--Thomas M. Harris and Constance M. Harris 3. The Ritter Reaction--L. I. Krimen and Donald J. Cota Author Index, Volumes 1-17 Chapter and Topic Index, Volumes 1-17 Subject Index, Volume 17

Volume

v. 18 ISBN 9780471196181

Description

The volumes of Organic Reactions are collections of chapters each devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure, and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.

Table of Contents

1. Preparation of Ketones from the Reaction of Organolithium Reagents with Carboxylic Acids Margaret J. Jorgenson 2. The Smiles and Related Rearrangements of Aromatic Systems William E. Truce, Eunice M. Kreider, and William W. Brand 3. The Reactions of Diazoacetic Esters with Alkenes, Alkynes, Heterocylic and Aromatic Compounds Vinod Dave and E. W. Warnhoff 4. The Base Promoted Rearrangements of Quaternary Ammonium Salts Stanley H. Pine Author Index, Volumes 1-18 Chapter Index, Volumes 1-18 Subject Index, Volume 18

Volume

v. 19 ISBN 9780471196198

Description

The volumes of Organic Reactions are collections of chapters each devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.

Table of Contents

1. Conjugate Addition Reactions of Organocopper Reagents Gary H. Posner 2. Formation of Carbon-Carbon Bonds Via phi-Allylnickel Compounds Martin F. Semmelhack 3. The Thiele-Winter Acetoxylation of Quinones J. F. W. McOmie and J. M. Blatchly 4. Oxidative Decarboxylation of Acids by Lead Tetra-Acetate Roger A. Sheldon and Jay K. Kochi Author Index, Volumes 1-19 Chapter and Topic Index, Volumes 1-19 Subject Index, Volume 19

Volume

v. 20 ISBN 9780471196211

Description

The volumes of Organic Reactions are collections of chapters each devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure, and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.

Table of Contents

1. Cyclopropanes from Unsaturated Compounds, Methylene Iodide, andZinc-Copper Couple Howard E. Simmons, Theodore L. Cairns, Susan A.Vladuchick, and Connie M. Hoiness 2. Sensitized Photooxygenation of Olefins R. W. Denny and A.Nickon 3. The Synthesis of 5-Hydroxyindoles by the Nenitzecu ReactionGeorge R. Allen, Jr. 4. The Zinin Reduction of Nitroarenes H. K. Porter Author Index, Volumes 1-20 Chapter and Topic Index, Volumes 1-20 Subject Index, Volume 20

Volume

v. 21 ISBN 9780471196228

Description

The volumes of Organic Reactions are collections of chapters each devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure, and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.

Table of Contents

Fluorination by Sulfur Tetrafluorid (E G. A. Boswell, Jr., W. C.Ripka, R. M. Scribner, and C. W. Tullock. Modern Methods to Prepare Monofluoroaliphatic Compounds (Clay M.Sharts and William A. Sheppard). Author Index, Volumes 1 21 Chapter Index, Volumes 1 21 Subject Index, Volume 21

Volume

v. 22 ISBN 9780471196235

Description

The volumes of Organic Reactions are collections of chapters each devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure, and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.

Table of Contents

1. The Claisen and Cope Rearrangements Sara Jane Rhoads and N. Rebecca Raulins 2. Substitution Reactions Using Organocopper Reagents Gary H. Posner 3. Clemmensen Reduction of Ketones in Anhydrous OrganicSolvents E. Vedejs. 4. The Reformatsky Reaction Michael W. Rathke Author Index, Volumes 1-22 Chapter and Topic Index, Volumes 1-22 Subject Index, Volume 22

Volume

v. 23 ISBN 9780471196242

Description

The volumes of Organic Reactions are collections of chapters each devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure, and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.

Table of Contents

Reduction and Related Reactions of gamma,B-Unsaturated Compoundswith Metals in Liquid Ammonia (D. Caine). The Acyloin Condensation (J. J. Bloomfield, D. C. Owsley, and J. M. Nelke). Alkenes from Tosylhydrazones (R. H. Shapiro).

Volume

v. 24 ISBN 9780471196259

Description

The volumes of Organic Reactions are collections of chapters each devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure, and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.

Table of Contents

Homogeneous Hydrogenation Catalysts in Organic Synthesis (A. J.Birch and D. H. Williamson). Ester Cleavages via SN 2-Type Dealkylation (J. E. McMurry). Arylation of Unsaturated Compounds by Diazonium Salts (The MeerweinArylation Reaction (C. S. Rondestvedt, Jr.). Selenium Dioxide Oxidation (N. Rabjohn).

Volume

v. 60 ISBN 9780471235811

Description

Organic Reactions is a comprehensive series devoted to important synthetic reactions, each volume having wide applicability. Each chapter focuses on a single reaction or a definitive phase of a reaction, and each is written by world-renowned chemists with extensive hands-on experience in their specialties. The material is presented from a preparative point of view, and particular attention is given to reaction limitations, interfering influences, effects of chemical structure, and the selection of experimental conditions. Each reaction includes information about its conditions, products, and yields, where available, and is fully referenced to the primary literature. The authors also include detailed procedures illustrating the significant modifications of the chemical reaction, as well as tables featuring all pertinent data about the reaction. Volume 60 contains two chapters: "Epoxide Migration (Payne Rearrangement) and Related Reactions," by Robert M. Hanson, and "The Intramolecular Heck Reaction," by J.T. Link. The most comprehensive and highly focused treatment of important organic reactions currently available, this series represents an important addition to chemistry libraries in both academic and industrial settings, and is a valuable resource for both students and professionals in the field.

Table of Contents

1. Epoxide Migration (Payne Rearrangement) and Related Reactions (Robert M. Hanson). 2. The Intramolecular Heck Reaction (J. T. Link). Cumulative Chapter Titles by Volume. Author Index, Volumes 1-60. Chapter and Topic Index, Volumes 1-60.

Volume

v. 61 ISBN 9780471274483

Description

The most comprehensive and highly focused treatment of important organic reactions currently available, this series represents an important addition to chemistry libraries in both academic and industrial settings, and is a valuable resource for both students and professionals in the field. Volume 61 contains two chapters: "[3 + 2] Cycloaddition of Trimethylenemethane and its Synthetic Equivalents," by Shigeru Yamago and Eiichi Nakamura, and "Dioxirane Epoxidation of Alkenes," by Waldemar Adam, Chantu R. Saha-Moeller, and Cong-Gui Zhao.

Table of Contents

[3+2] Cycloaddition of Trimethylenemethane and its Synthetic Equivalents (Shigeru Yamago and Eiichi Nakamura). Dioxirane Epoxidation of Alkenes (Waldemar Adam, et al.). Cumulative Chapter Titles by Volume. Author Index, Volumes 1-61. Chapter and Topic Index, Volumes 1-61.

Volume

v. 44 ISBN 9780471303022

Description

The volumes of Organic Reactions are collections of chapters each devoted to a single reaction or a definitive phase of a reaction, of wide applicability. The authors have had experience with the processes surveyed. The subjects are presented from the preparative viewpoint and particular attention is given to limitations, interfering influences, effects of structure and the selection of experimental techniques. Each chapter includes several detailed procedures illustrating the significant modifications of the method. Each chapter contains tablets that include all the examples of the reaction under consideration that the author has been able to find.

Table of Contents

Preparation of ,beta-Unsaturated Carbonyl Compounds and Nitriles bySelenoxide Elimination (H. Reich & S. Wollowitz). Enone Olefin [2 + 2] Photochemical Cycloadditions (M. Crimmins& T. Reinhold). Cumulative Chapter Titles by Volume. Author Index, Volumes 1-44. Chapter and Topic Index, Volumes 1-44.

Volume

v. 53 ISBN 9780471326090

Description

Every volume in the Organic Reactions series contains chapters devoted to a single reaction-or a definitive phase of a reaction-of wide applicability. Volume 53 features coverage of the Retro-Diels-Alder Reaction and the enantioselective reduction of ketones. Both subjects are presented from the preparative viewpoint.

Table of Contents

The Oxidation of Alcohols by Modified Oxochromium (VI)-Amine Reagents (F. Luzzio). The Retro-Diels-Alder Reaction. Part II. Dienophiles with One or More Heteroatom (B. Rickborn). Cumulative Chapter Titles by Volume. Indexes.

Volume

v. 54 ISBN 9780471348887

Description

As with previous volumes in this acclaimed series, Volume 54 is devoted to a specific process with important applications in organic and medicinal chemistry. In two major parts, expert contributions address aromatic substitution by the S-RN1 reaction and the oxidation of carbonyl compounds with organohypervalent iodine reagents. The authors draw on their experience with the processes surveyed, presenting topics from the preparative viewpoint and discussing limitations, interfering influences, effects of structure, and how to select experimental techniques.

Table of Contents

Aromatic Substitution by the S-RN1 Reaction ( R. Rossi, et al.). Oxidation of Carbonyl Compounds with Organohypervalent Iodine Reagents (R. Moriarty & O. Prakash). Cumulative Chapter Titles by Volume. Indexes.

Volume

v. 55 ISBN 9780471376149

Description

This volume focuses on the synthesis of nucleotides, presented from the preparative viewpoint. Attention is given to limitations, interfering influences, effects of structure and the selection of experimental techniques. Each chapter includes several detailed procedures illustrating the significant modifications of the method and contains tablets that include all the examples of the reaction under consideration.

Table of Contents

Nucleoside Synthesis. Silyl-Hilbert-Johnson Reaction in the Presence of Friedel-Crafts Catalysts. Mechanism of Nucleoside Formation in the Presence of Friedel-Crafts Catalysts. Special Preparations. Miscellaneous Methods. Alternative Nucleoside-Forming Reactions. Experimental Conditions. Experimental Procedures. Tabular Survey. References.

Volume

v. 56 ISBN 9780471395683

Description

Organic Reactions is a comprehensive series of volumes devoted to important synthetic reactions. For each volume, the authors are world-renowned experts with extensive hands-on experience in the field. The subjects are presented from the preparative viewpoint, and particular attention is given to limitations, interfering influences, effects of structure, and the selection of experimental techniques. Each chapter includes detailed procedures illustrating the significant modifications of the chemical reaction, as well as tables listing all the pertinent examples of the reaction. The topics discussed in Volume 56 are the Hydroformylation reaction and the Vilsmeier reactions of non-aromatic compounds. Each reaction is presented with information about the reaction conditions, products, and yields where available, and is fully referenced to the primary literature.

Table of Contents

The Hydroformylation Reaction (I. Ojima, et al.). The Vilsmeier Reaction. 2. Reactions with Compounds Other Than Fully Conjugated Carbocycles and Heterocycles (G. Jones & S. Stanforth). Cumulative Chapter Titles by Volume. Indexes.

Volume

v. 57 ISBN 9780471435112

Description

Organic Reactions is a comprehensive series of volumes composed of chapters devoted to important synthetic reactions. Each chapter includes detailed procedures illustrating the significant modifications of the chemical reaction as well as tables including all the pertinent examples. Each reaction is presented with information about the conditions, products, and yields where available. * Particular attention is given to reaction limitations, interfering influences, effects of chemical structure, and the selection of experimental conditions

Table of Contents

Intermolecular Metal-Catalyzed Carbenoid Cyclopropanations (H. Davies & E. Antoulinakis). Oxidation of Phenolic Compounds with Organohypervalent Iodine Reagents (R. Moriarty & O. Prakash). Synthetic Uses of Tosylmethyl Isocyanide (TosMIC) (D. van Leusen & A. van Leusen). Cumulative Chapter Titles by Volume. Author Index, Volumes 1-57. Chapter and Topic Index, Volumes 1-57.

Volume

v. 63 ISBN 9780471445326

Description

Organic Reactions is a comprehensive series of volumes composed of chapters devoted to important synthetic reactions. For each volume, the chapter authors are world-renowned experts with extensive hands-on experience in the field. The chemistry is presented from a preparative point of view and particular attention is given to reaction limitations, interfering influences, effects of chemical structure, and the selection of experimental conditions.

Table of Contents

Chapter 1. The Biginelli Dihydropyrimidine Synthesis (C. Oliver Kappe and Alexander Stadler). Chapter 2. Microbial Arene Oxidations (Roy A. Johnson). Chapter 3. Cu, Ni, and Pd Mediated Homocoupling Reactions in Biaryl Synthesis: The Ullmann Reaction (Todd D. Nelson and R. David Crouch). Cumulative Chapter Titles by Volume. Author Index, Volumes 1-63. Chapter and Topic Index, Volumes 1-63.

Volume

v. 62 ISBN 9780471445333

Description

Organic Reactions is a comprehensive series of volumes composed of chapters devoted to important synthetic reactions. World-renowned experts, who have extensive hands-on experience in this field, have written the chapters that comprise this volume. The chemistry is presented from a preparative point of view, with particular attention given to reaction limitations, interfering influences, effects of chemical structure, and the selection of experimental conditions. Each chapter includes detailed procedures illustrating the significant modifications of the chemical reaction as well as tables including all the pertinent examples of the reaction. Each reaction is presented with information about the reaction conditions as well as products and yields where available. Organic Reactions, Volume 62 includes chapters such as "The Ramberg-Backlund Reaction," "a -Hydroxylation of Enolates and Silyl Enol Ethers," "The a -Hydroxyl Ketone (a -Ketol) and Related Rearrangements," and " Transformation of Glycals into 2,3-Unsaturated Glycosyl Derivatives." Filled with in-depth insights and expert advice, Organic Reactions, Volume 62 provides the most comprehensive and highly focused treatment of important organic reactions currently available.

Table of Contents

1. a-Hydroxylation of Enolates and Silyl Enol Ethers (Bang-Chi Chang, et al.). 2. The Ramberg-Backlund Reaction (Richard J.K. Taylor and Guy Casy). 3. The a-Hyroxyl Ketone (?-Ketol) and Related Rearangements (Leo A. Paquette and John E. Hofferberth). 4. Transformation of Glycals into 2,3-Unsaturated Glycosyl Derivatives (Robert J. Ferrier and Oleg A. Zubkov). Cumulative Chapter Titles by Volume. Author Index, Volumes 1-62. Chapter and Topic Index, Volumes 1-62.

Volume

v. 37 ISBN 9780471501695

Description

The volumes of Organic Reactions are collections of chapters each devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure, and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.

Table of Contents

Chiral Synthons by Ester Hydrolysis Calalyzed by Pig Liver Esterase (M. Ohno & M. Otsuka). The Electrophilic Substitution of Allylsilanes and Vinylsilanes (I. Fleming et al.). Author Index, Volumes 1-37. Chapter and Topic Index, Volumes 1-37.

Volume

v. 38 ISBN 9780471515944

Description

The volumes in this series are collections of essays devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The subjects are presented from the preparative viewpoint and particular attention is given to the limitations, interfering influences, effects of structure and the selection of experimental techniques. Each chapter includes several detailed procedures illustrating the significant modifications of the method.

Table of Contents

The Peterson Olefination Reaction (D. Ager). Tandem Vicinal Difunctionalization: B-Addition to ,B-Unsaturated Carbonyl Substrates Followed by -Functionalization (M. Chapdelaine & M. Hulce). The Nef Reaction (H. Pinnick). Author Index, Volumes 1-38. Chapter and Topic Index, Volumes 1-38.

Volume

v. 39 ISBN 9780471526322

Description

Part of a series of volumes for organic chemists in industry, this work presents critical discussions of widely used organic reactions or particular phases of a reaction. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. The volume includes tables that contain all possible examples of the reaction under consideration.

Table of Contents

Lithioalkenes from Arenesulfonylhydrazones (A. Chamberlin & S. Bloom). The Polonovski Reaction (D. Grierson). Oxidation of Alcohols to Carbonyl Compounds via Alkoxysulfonium Ylides: The Moffatt, Swern, and Related Oxidations (T. Tidwell). Author Index, Volumes 1-39. Chapter and Topic Index, Volumes 1-39.

Volume

v. 40 ISBN 9780471538417

Description

The volumes of Organic Reactions are collections of chapters each devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure, and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.

Table of Contents

The Pauson-Khand Cycloaddition Reaction for Synthesis ofCyclopentenones (N. Schore). Reduction with Diimide (D. Pasto & R. Taylor). The Pummerer Reaction of Sulfinyl Compounds (O. De Lucchi, etal.). The Catalyzed Nucleophilic Addition of Aldehydes to ElectrophilicDouble Bonds (H. Stetter & H. Kuhlmann). Author Index, Volumes 1-40. Chapters and Topic Index, Volumes 1-40.

Volume

v. 41 ISBN 9780471544098

Description

The latest volume in this series for organic chemists in industry presents critical discussions of widely used organic reactions or particular phases of a reaction. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.

Table of Contents

Divinylcylopropane--Cycloheptadiene Rearrangement (T. Hudlicky, etal.). Formation of Carbon-Carbon Bonds via Organocopper Reagents (BLipshutz & S. Sengupta). Indexes.

Volume

v. 42 ISBN 9780471544104

Description

The latest volume in this series for organic chemists in industry presents critical discussions of widely used organic reactions or particular phases of a reaction. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.

Table of Contents

The Birch Reduction of Aromatic Compounds (P. Rabideau & Z.Marcinow). The Mitsunobu Reaction (D. Hughes). Indexes.

Volume

v. 43 ISBN 9780471584797

Description

Each volume in this series contains sections devoted to a single reaction, or a definitive phase of a reaction. Particular attention is given to limitations, interfering influences, the effects of structure and the selection of experimental techniques.

Table of Contents

Carbonyl Methylenation and Alkylidenation Using Titanium-BasedReagents (S. Pine). Anion-Assisted Sigmatropic Rearrangements (S. Wilson). The Baeyer-Villiger Oxidation of Ketones and Aldehydes (G.Krow). Cumulative Chapter Titles by Volume. Indexes.

Volume

v. 66 ISBN 9780471682585

Description

Organic Reactions is a comprehensive series of volumes composed of chapters devoted to important synthetic reactions. For each volume, the chapter authors are world-renowned experts with extensive hands-on experience in the field. The chemistry is presented from a preparative point of view and particular attention is given to reaction limitations, interfering influences, effects of chemical structure, and the selection of experimental conditions. * Each reaction is fully referenced to the primary literature * Numerous detailed procedures illustrate the significant modifications of each method * Includes tables that contain all possible examples of the reaction under consideration

Table of Contents

1. THE ALLYLIC TRIHALOACETIMIDATE REARRANGEMENT (Larry E. Overman and Nancy E. Carpenter). 2. ASYMMETRIC DIHYDROXYLATION OF ALKENES (Mark C. Noe, Michael A. Letavic, Sheri L. Snow, and Stuart W. McCombie). CUMULATIVE CHAPTER TITLES BY VOLUME. AUTHOR INDEX, VOLUMES 1-66. CHAPTER AND TOPIC INDEX, VOLUMES 1-66.

Volume

v. 65 ISBN 9780471682608

Description

"Organic Reactions" is a comprehensive series of volumes composed of chapters devoted to important synthetic reactions. For each volume, the chapter authors are world renowned experts with extensive hands on experience in the field. The chemistry is presented from a preparative point of view and particular attention is given to reaction limitations, interfering influences, effects of chemical structure, and the selection of experimental conditions. Each reaction is fully referenced to the primary literature. Numerous detailed procedures illustrate the significant modifications of each method. This book includes tables that contain all possible examples of the reaction under consideration

Table of Contents

Chapter 1. The Passerini Reaction. (Luca Banfi and Renata Riva).Chapter 2. Diels-Alder Reactions of Imino Dienophiles. (Geoffrey R. Heintzelman, Ivona R. Meigh, Yogesh R. Mahajan, and Steven M. Weinreb).Cumulative Chapter Titles By Volume.Author Index, Volumes 1-65.Chapter and Topic Index, Volumes 1-65.

Volume

v. 64 ISBN 9780471682622

Description

Organic Reactions is a comprehensive series of volumes composed of chapters devoted to a single reaction, or a definite phase of a reaction. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure, and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reactions under consideration. Authors are world-renowned experts with extensive hands-on experience in the field Volume 64 includes the following chapters: 1. ADDITIONS OF ALLYL, ALLENYL, AND PROPARGYLSTANNANES TO ALDEHYDES AND IMINES By Benjamin W. Gung 2. GLYCOSYLATION WITH SULFOXIDES AND SULFINATES AS DONORS AND PROMOTERS By David Crich and Linda B. L. Lim 3. ADDITION OF ORGANOCHROMIUM REAGENTS TO CARBONYL COMPOUNDS By Kazuhiko Takai

Table of Contents

1. ADDITIONS OF ALLYL, ALLENYL, AND PROPARAGYLSTANNANES TO ALDEHYDES AND IMINES (Benjamin W. Gung). 2. GYLCOSYLATION WITH SULFOXIDES AND SULFINATES AS DONORS OR PROMOTERS (David Crich and Linda B. L. Lim). 3. ADDITION OF ORGANOCHROMIUM REAGENTS TO CARBONYL COMPOUNDS (Kazuhiko Takai). CUMULATIVE CHAPTER TITLES BY VOLUME. AUTHOR INDEX, VOLUMES 1-64. CHAPTER AND TOPIC INDEX, VOLUMES 1-64.

Volume

v. 33 ISBN 9780471802297

Description

The volumes of Organic Reactions are collections of chapters each devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.

Table of Contents

Formation of Carbon-Carbon and Carbon-Heteroatom Bonds viaOrganoboranes and Organoborates (E. Negishi and M.Idacavage). The Vinylcyclopropane-Cyclopentene Rearrangement (T. Hudlicky etal.). Author Index. Chapter and Topic Index. Subject Index.

Volume

v. 34 ISBN 9780471806738

Description

The volumes of Organic Reactions are collections of chapters each devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure, and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.

Table of Contents

Reductions by Metal Alkoxyaluminum Hydrides (J. Malek). Fluorination by Sulfur Tetrafluoride (C. Wang). Author Index. Chapter and Topic Index.

Volume

v. 35 ISBN 9780471832539

Description

Each subject of organic chemistry reviewed in this series is presented from a preparative viewpoint. Emphasis is placed on limitations, interfering influences, effects of structure and the selection of experimental techniques.

Table of Contents

The Beckmann Reactions: Rearrangements, Elimination-Additions, Fragmentations, and Rearrangement-Cyclizations Robert E. Gawley 2. The Persulfate Oxidation of Phenols and Arylamines (The Elbs and the Boyland-Sims Oxidations) E. J. Behrman 3. Fluorination with Diethylaminosulfur Trifluoride and Related Aminofluorosulfuranes Milos Hudlicky Author Index, Volumes 1-35 Chapter and Topic Index, Volumes 1-35

Volume

v. 36 ISBN 9780471857488

Description

The volumes of Organic Reactions are collections of chapters each devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure, and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.

Table of Contents

The Nitrone-Olegin Cycloaddition Reaction (P. N. Confalone & E. M. Huie). Phosphorus Addition at sp 2 Carbon (R. Engel). Reduction by Metal Alkoxyaluminum Hydrides (J. Malek). Author Index, Vols. 1-36. Chapter and Topic Index, Vols. 1-36.

Volume

v. 28 ISBN 9780471861416

Description

The volumes of Organic Reactions are collections of chapters each devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.

Table of Contents

The Reimer-Tiemann Reaction (Hans Wynberg and Egbert W. Meijer). The Friedlander Synthesis of Quinolines (Chia-Chung Cheng and Shou-Jen Yan). The Directed Aldol Reaction (Tenuaki Mukaiyama).

Volume

v. 29 ISBN 9780471874904

Description

The volumes of Organic Reactions are collections of chapters each devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.

Table of Contents

Replacement of Alcoholic Hydroxyl Groups by Halogens and Other Nucleophiles Via Oxyphosphonium Intermediates (B. Castro). Reductive Dehalogenation of Polyhalo Ketones with Low-Valent Metals and Related Reducing Agents (R. Nayori & Y. Hayakawa). Base Isomerizations of Epoxides (J. Crandall & M. Apparu). Author Index, Volumes 1-29. Chapter and Topic Index, Volumes 1-29. Subject Index, Volume 29.

Volume

v. 32 ISBN 9780471881018

Description

Leading experts present papers devoted to a single reaction, or a definite phase of a reaction, of wide applicability. Emphasizes limitations, interfering influences, effects of structure, and the selection of experimental techniques. Chapters include detailed procedures illustrating the significant modifications of the method. Includes tables with examples of the reaction under consideration.

Table of Contents

The Intramolecular Diels-Alder Reaction (E. Ciganek). Syntheses Using Alkyne-Derived Alkenyl--And Alkynylaluminum Compounds (G. Zweifel & J. Miller). Author Index, Volumes 1-32. Chapter and Topic Index, Volumes 1-32. Subject Index, Volume 32.

Volume

v. 31 ISBN 9780471886716

Description

The volumes of Organic Reactions are collections of chapters each devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.

Table of Contents

Addition and Substitution Reactions of Nitrile-Stabilized Carbanions (S. Areniyadis et al.). Author Index, Volumes 1-31. Chapter and Topic Index, Volumes 1-31. Subject Index, Volume 31.

Volume

v. 30 ISBN 9780471890133

Description

The volumes of Organic Reactions are collections of chapters each devoted to a single reaction, or a definite phase of a reaction, of wide applicability. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.

Table of Contents

Photocyclization of Stilbenes and Related Molecules (F. Mallory & C. Mallory). Olefin Synthesis by Deoxygenation of Vicinal Dials (E. Block). Author Index. Chapter and Topic Index. Subject Index.

Volume

v. 77 ISBN 9781118163801

Description

This new volume in the venerable Organic Reactions series comprises two chapters written in part by the inventors of the unique and important name reactions discussed in these chapters. The first chapter describes a truly remarkable transformation of carboxylic acid derivatives into heteroatom-substituted cyclopropanes, now known as Kulinkovich Cyclopropanation. The second chapter represents an homage to one of the giants of organic chemistry, Sir Derek H. R. Barton. This chapter covers the radical deoxygenation of secondary alcohols that has become known as the Barton-McCombie Reaction.

Table of Contents

1. The Kulinkovich Cyclopropanation of Carboxylic Acid Derivatives 1 Jin Kun Cha and Oleg G. Kulinkovich 2. The Barton-Mccombie Reaction 161 Stuart W. McCombie, William B. Motherwell, and Matthew J. Tozer Cumulative Chapter Titles By Volume 593 Author Index, Volumes 1-77 609 Chapter and Topic Index, Volumes 1-77 615

Volume

v. 78 ISBN 9781118356364

Description

This volume in the venerable Organic Reactions series contains three chapters focusing on the introduction or the removal of nitrogen from organic compounds. The first chapter features a classic chemical reaction for introducing nitrogen into organic compounds, namely the Schmidt Reaction. The second chapter highlights a less-well-known yet fascinating transformation that introduces nitrogen into organic compounds, The Neber Rearrangement. The third chapter describes an unusual class of reactions that involve the loss of small molecular fragments from a ring, where separate carbon atoms unite to form alkenes.

Table of Contents

CHAPTER PAGE 1. THE SCHMIDT REACTION Aaron Wrobleski, Thomas C. Coombs, Chan Woo Huh, Sze-Wan Li, and Jeffrey Aube 1 2. THE NEBER REARRANGEMENT William F. Berkowitz 321 3. TWOFOLD EXTRUSION REACTIONS Lynn James Guziec and Frank S. Guziec, Jr 411 CUMULATIVE CHAPTER TITLES BY VOLUME 551 AUTHOR INDEX, VOLUMES 1-78 567 CHAPTER AND TOPIC INDEX, VOLUMES 1-78 573

Volume

v. 79 ISBN 9781118509418

Description

Volume 79 in the venerable Organic Reactions series contains two chapters. The first addresses cross-coupling reactions of organotrifluoroborate salts, useful in the development of natural products, materials, and pharmacologically active substances. It is an excellent companion to two previous chapters on tin-based and silicon-based cross-couplings contained in Volumes 50 and 75, respectively. The second chapter addresses asymmetric transformations by deprotonation using chiral lithium amides, useful in target-oriented synthesis, and representing one of the most powerful workhorse reactions in organic synthesis.

Table of Contents

1. CROSS-COUPLING REACTIONS OF ORGANOTRIFLUOROBORATE SALTS Gary A. Molander and Ludivine Jean-Gerard 1 2. ASYMMETRIC TRANSFORMATIONS BY DEPROTONATION USING CHIRAL LITHIUM AMIDES Nigel S. Simpkins and Michael D. Weller 317 CUMULATIVE CHAPTER TITLES BY VOLUME 637 AUTHOR INDEX, VOLUMES 1-79 653 CHAPTER AND TOPIC INDEX, VOLUMES 1-79 659

Volume

v. 80 ISBN 9781118513088

Description

Volume 80 in the venerable Organic Reactions series contains two chapters. The first describes the use of chiral rhodium complexes to effect catalytic, asymmetric carbon-hydrogen insertion reactions intramolecularly. It details the structural scenarios in which diazocarbonyl compounds can be generated and activated to form, inter alia, lactones, lactams and cyclic ketones. The second chapter describes the use of (chiral) rhodium complexes in combination with diazocarbonyl compounds, but in this case to effect a remarkable transformation that dramatically increases the molecular complexity of the substrates.

Table of Contents

1. CATALYTIC, ASYMMETRIC, INTRAMOLECULAR CARBON-HYDROGEN INSERTION 1 Michael P. Doyle, Yu Liu, and Maxim Ratnikov 2. CYCLOADDITIONS OF CARBONYL YLIDES DERIVED FROM DIAZOCARBONYL COMPOUNDS 133 David M. Hodgson, Agn`es H. Labande, and Sengodagounder Muthusamy CUMULATIVE CHAPTER TITLES BY VOLUME 497 AUTHOR INDEX, VOLUMES 1-80 513 CHAPTER AND TOPIC INDEX, VOLUMES 1-80 519

Volume

v. 81 ISBN 9781118674253

Description

Volume 81 represents the confluence of two rare and important phenomena for chapters in the Organic Reactions series, namely, it is a single-chapter volume, and it contains a name reaction coauthored by the inventor. Of the 261 chapters published thus far, only seven have been of sufficient impact to appear as single-chapter volumes. The single chapter in this volume entitled "The Krapcho Dealkoxycarbonylation Reaction of Esters with a-Electron-Withdrawing Substituents" has been coauthored by A. Paul Krapcho together with Organic Reactions' long-time contributor Engelbert Ciganek. The "Krapcho Decarboxylation," as it is known in common parlance, is an extraordinarily useful alternative to the classical hydrolysis-decarboxylation of esters bearing a-electron-withdrawing substituents. This process replaces the strongly basic or acidic conditions normally required for ester saponification with the neutral cleavage of the ester group by a BAC2 mechanism through the combination of water and a dipolar aprotic solvent at high temperature. However, another popular variant involves the use of inorganic salts such as lithium chloride, sodium iodide, or sodium cyanide in a dipolar aprotic solvent which can open a second mechanistic pathway (dependent upon the ester) through BAL2 cleavage. Drs. Krapcho and Ciganek expertly outline the broad substrate scope of this reaction and identify the preferred conditions for various substrate classes. The 371 pages of tables containing all known examples of this simple but important transformation, together with the 1,908 references cited in this Chapter, are testimony to the synthetic usefulness of the Krapcho reaction.

Table of Contents

1 THE KRAPCHO DEALKOXYCARBONYLATION REACTION OF ESTERS WITH -ELECTRON-WITHDRAWING SUBSTITUENTS A Paul Krapcho and Engelbert Ciganek 1 CUMULATIVE CHAPTER TITLES BY VOLUME 537 AUTHOR INDEX, VOLUMES 1-81 553 CHAPTER AND TOPIC INDEX, VOLUMES 1-81 559

Volume

v. 82 ISBN 9781118674284

Description

Volume 82 describe reactions that involve one of the most common transformations in organic chemistry, namely, the pairwise combination of double bonded functional groups. The importance of this enormous family of reactions is a reflection of the spectacular diversity of precursors and products that can arise from appropriate modulation of reactivity of the partners and especially selection of reagents that dictate the outcome. The first chapter authored by Takeshi Takeda and Akira Tsubouchi describes the combination of carbonyl compounds in the presence of highly reactive, low valent titanium reagents in the classic McMurry reaction. The second chapter concerns the chemistry of highly-reactive, double-bonded functional groups, namely ketenes.

Table of Contents

1. THE McMURRY COUPLING AND RELATED REACTIONS Takeshi Takeda and Akira Tsubouchi 1 2. CATALYTIC ASYMMETRIC KETENE [2+ 2] AND [4+ 2] CYCLOADDITIONS Scott G. Nelson, Robert D. Dura, and Timothy J. Peelen 471 CUMULATIVE CHAPTER TITLES BY VOLUME 623 AUTHOR INDEX, VOLUMES 1-82 639 CHAPTER AND TOPIC INDEX, VOLUMES 1-82 645

Volume

v. 83 ISBN 9781118835227

Description

The two chapters in Volume 83 describe reactions that represent two major (and growing) franchises in the Organic Reactions series, namely, transition metal catalyzed cross-coupling reactions and multicomponent reactions. These two processes not only have a rich history in synthetic organic chemistry, but also represent some of the most commonly employed transformations in the modern practice of molecule construction. The first chapter authored by Eiichi Nakamura, Takuji Hatakeyama, Shingo Ito, Kentaro Ishizuka, Laurean Ilies, and Masaharu Nakamura describes one of the most exiting advances in the field of transition metal catalyzed cross-coupling reactions: the use of iron catalysts. The second chapter authored by Stephen G. Pyne and Minyan Tang describes the latest in a long line of multicomponent reactions published in this series: the boronic acid Mannich reaction, sometimes called the Petasis reaction.

Table of Contents

CHAPTER PAGE 1. IRON-CATALYZED CROSS-COUPLING REACTIONS Eiichi Nakamura, Takuji Hatakeyama, Shingo Ito, Kentaro Ishizuka, Lauren Ilies, and Masaharu Nakamura 1 2. THE BORONIC ACID MANNICH REACTION Stephen G. Pyne and Minyan Tang 211 CUMULATIVE CHAPTER TITLES BY VOLUME 499 AUTHOR INDEX, VOLUMES 1-83 515 CHAPTER AND TOPIC INDEX, VOLUMES 1-83 521

Volume

v. 84 ISBN 9781118841907

Description

The two chapters in Volume 84 describe transition metal catalyzed processes that form carbon-carbon bonds and carbon-oxygen bonds in very interesting and practical ways. The first chapter authored by Christina Moberg describes an important subset of one of the earliest and most important enantioselective carbon-carbon bond forming reactions that employ transition metal complexes, namely molybdenum-catalyzed, asymmetric allylic alkylations. The second chapter authored by Brian W. Michel, Laura D. Steffens, and Matthew S. Sigman deals with one of the oldest examples of transition metal catalyzed oxidation, known as the Wacker process.

Table of Contents

1. Molybdenum-Catalyzed Asymmetric Allylic Alkylations Christina Moberg 1 2. The Wacker Oxidation Brian W. Michel, Laura D. Steffens, and Matthew S. Sigman 75 Cumulative Chapter Titles by Volume 415 Author Index, Volumes 1-84 431 Chapter and Topic Index, Volumes 1-84 437

Volume

v. 85 ISBN 9781118976517

Description

Volume 85 represents the ninth single chapter volume to be produced in Organic Reactions' 72-year history. The original authors, Drs. Shaughnessy and DeVasher, have compiled an enormous (and growing) literature and distilled it into an extraordinarily useful treatise on all aspects of the copper-catalyzed amination process. Given the myriad types of nitrogen-based nucleophiles and various ligand sets and reaction conditions, the authors have done an outstanding job of identifying the best options for various permutations of donor and acceptor. This comprehensive treatment of so many different options constitutes a dream "field guide" for the perplexed chemist who wants to know how best to approach the formation of a C-N bond in a target structure and whether copper or palladium catalysis is recommended.

Table of Contents

1. Copper-Catalyzed Amination of Aryl and Alkenyl Electrophiles 1 Kevin H. Shaughnessy, Engelbert Ciganek, and Rebecca B. DeVasher Cumulative Chapter Titles by Volume 669 Author Index, Volumes 1-85 685 Chapter and Topic Index, Volumes 1-85 691

Volume

v. 86 ISBN 9781119013990

Description

The latest volume in this series for organic chemists in industry presents critical discussions of widely used organic reactions or particular phases of a reaction. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. Numerous detailed procedures illustrate the significant modifications of each method. Includes tables that contain all possible examples of the reaction under consideration.

Table of Contents

1. Ring-Expanding Carbonylation of Epoxides 1 John W. Kramer, John M. Rowley, and Geoffrey W. Coates 2. The Tishchenko Reaction 105 Ari M. P. Koskinen and Antti O. Kataja Cumulative Chapter Titles by Volume 411 Author Index, Volumes 1-86 427 Chapter and Topic Index, Volumes 1-86 433

Volume

v. 87 ISBN 9781119014003

Description

The first chapter describes the manifold ways in which the latent functionality embedded in the humble heterocycle furan can be revealed by various oxidative processes.The second chapter details the fascinating cycloaddition and electrocyclization chemistry of unsaturated ketenes. The third chapter chronicles the development of a remarkable organometallic reaction of unactivated alkenes and alkynes, namely carbozincation.

Table of Contents

1. Oxidative Cleavage of Furans Pedro Merino 1 2. Cycloaddition and Electrocyclic Reactions of Vinylketenes, Allenylketenes, and Alkynylketenes Nanyan Fu and Thomas T. Tidwell 257 3. Carbozincation Reactions of Carbon-Carbon Multiple Bonds Genia Sklute, Hannah Cavender, and Ilan Marek 507 Cumulative Chapter Titles by Volume 765 Author Index, Volumes 1-87 781 Chapter and Topic Index, Volumes 1-87 787

Volume

v. 88 ISBN 9781119103851

Description

Volume 88 represents the tenth single-chapter-volume produced in our 73-year history. Such single-chapter volumes represent definitive treatises on extremely important chemical transformations. The success of the research efforts over the past 20 years forms the basis for the single chapter in this volume namely, Hydroamination of Alkenes by Alexander L. Reznichenko and Kai C. Hultzsch. The authors have compiled an enormous (and growing) literature and distilled it into an extraordinarily useful treatise on all aspects of the hydroamination process.

Table of Contents

1. Hydroamination of Alkenes Alexander L. Reznichenko and Kai C. Hultzsch 1 Cumulative Chapter Titles by Volume 555 Author Index, Volumes 1-88 571 Chapter and Topic Index, Volumes 1-88 577

Volume

v. 89 ISBN 9781119211211

Description

The latest volume in this series for organic chemists in industry presents critical discussions of widely used organic reactions or particular phases of a reaction. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. The work includes tables that contain all possible examples of the reaction under consideration. Detailed procedures illustrate the significant modifications of each method.

Table of Contents

1. Olefin Ring-Closing Metathesis Larry Yet 1 Abbreviations 92 Chart 1. Catalysts Used in Tables 95 Chart 2. Ligands Used in Tables 107 Table 1. Synthesis of Carbocycles 108 Table 2A. Synthesis of Cyclic Amides 374 Table 2B. Synthesis of Cyclic Ethers 569 Table 2C. Synthesis of Phosphorous-Containing Heterocycles 764 Table 2D. Synthesis of Silicon-Containing Heterocycles 788 Table 2E. Synthesis of Sulfur-Containing Heterocycles 818 Table 2F. Synthesis of Sulfonamide-Containing Heterocycles 828 Table 2G. Synthesis of Boron-Containing Derivatives 837 Table 2H. Synthesis of Unsaturated Lactams 838 Table 2I. Synthesis of Cyclic Peptides 916 Table 2J. Synthesis of Unsaturated Lactones 953 Table 2K. Synthesis of Heterocycles Containing Multiple Heteroatoms 1118 Table 3. Synthesis of Supramolecular Compounds 1180 Table 4. Tandem Metathesis Reactions 1204 References 1248 Cumulative Chapter Titles by Volume 1305 Author Index, Volumes 1-89 1321 Chapter and Topic Index, Volumes 1-89 1327

Volume

v. 93 ISBN 9781119281412

Description

The latest volume in this series for organic chemists in industry presents critical discussions of widely used organic reactions or particular phases of a reaction. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. The work includes tables that contain all possible examples of the reaction under consideration. Detailed procedures illustrate the significant modifications of each method.

Table of Contents

1. Enantioselective, Rhodium-Catalyzed 1,4-Addition of Organoboron Reagents to Electron-Deficient Alkenes 1 Alan R. Burns, Hon Wai Lam, and Iain D. Roy Cumulative Chapter Titles by Volume 687 Author Index, Volumes 1-93 705 Chapter and Topic Index, Volumes 1-93 711

Volume

v. 92 ISBN 9781119281429

Description

The latest volume in this series for organic chemists in industry presents critical discussions of widely used organic reactions or particular phases of a reaction. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. The work includes tables that contain all possible examples of the reaction under consideration. Detailed procedures illustrate the significant modifications of each method.

Table of Contents

1. Gold-Catalyzed Cyclizations ofAlkynes with Alkenes and Arenes 1 Antonio M. Echavarren, Michael E. Muratore, Veronica Lopez-Carrillo, Ana Escribano-Cuesta, Nuria Huguet, and Carla Obradors 2. Cyclization of Vinyl and Aryl Azides into Pyrroles, Indoles, Carbazoles, and Related Fused Pyrroles 413 William F. Berkowitz and Stuart W. McCombie Cumulative Chapter Titles by Volume 659 Author Index, Volumes 1-92 677 Chapter and Topic Index, Volumes 1-92 683

Volume

v. 91 ISBN 9781119281436

Description

The latest volume in this series for organic chemists in industry presents critical discussions of widely used organic reactions or particular phases of a reaction. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. The work includes tables that contain all possible examples of the reaction under consideration. Detailed procedures illustrate the significant modifications of each method.

Table of Contents

1. Nucleophilic Additions of Perfluoroalkyl Groups Petr Beier, Mikhail Zibinsky, and G. G. Surya Prakash 1 Cumulative Chapter Titles by Volume 743 Author Index, Volumes 1 91 761 Chapter and Topic Index, Volumes 1 91 767

Volume

v. 90 ISBN 9781119281443

Description

The latest volume in this series for organic chemists in industry presents critical discussions of widely used organic reactions or particular phases of a reaction. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. The work includes tables that contain all possible examples of the reaction under consideration. Detailed procedures illustrate the significant modifications of each method.

Table of Contents

1. The Catalytic, Enantioselective Michael Reaction Efraim Reyes, Uxue Uria, Jose L. Vicario, and Luisa Carrillo 1 Cumulative Chapter Titles by Volume 899 Author Index, Volumes 1-90 915 Chapter and Topic Index, Volumes 1-90 921

Volume

v. 95 ISBN 9781119308928

Description

The 95th volume in this series for organic chemists in industry presents critical discussions of widely used organic reactions or particular phases of a reaction. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. The work includes tables that contain all possible examples of the reaction under consideration. Detailed procedures illustrate the significant modifications of each method.

Table of Contents

1. The Julia-Kocienski Olefination 1 Paul R. Blakemore, Selena Milicevic Sephton, and Engelbert Ciganek 2. Asymmetric Synthesis of -Lactams by the Staudinger Reaction 423 Aitor Landa, Antonia Mielgo, Mikel Oiarbide, and Claudio Palomo Cumulative Chapter Titles by Volume 595 Author Index, Volumes 1-95 613 Chapter and Topic Index, Volumes 1-95 619

Volume

v. 94 ISBN 9781119308935

Description

The 94th volume in this series for organic chemists in industry presents critical discussions of widely used organic reactions or particular phases of a reaction. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. The work includes tables that contain all possible examples of the reaction under consideration. Detailed procedures illustrate the significant modifications of each method.

Table of Contents

1. [3 + 2] Dipolar Cycloadditions of Cyclic Nitrones with Alkenes 1 Alberto Brandi, Francesca Cardona, Stefano Cicchi, Franca M. Cordero, and Andrea Goti Cumulative Chapter Titles by Volume 531 Author Index, Volumes 1-94 549 Chapter and Topic Index, Volumes 1-94 555

Volume

v. 96 ISBN 9781119374534

Description

The 96th volume in this series for organic chemists in industry presents critical discussions of widely used organic reactions or particular phases of a reaction. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. The work includes tables that contain all possible examples of the reaction under consideration. Detailed procedures illustrate the significant modifications of each method.

Table of Contents

1. CATALYTIC, ENANTIOSELECTIVE HYDROGENATION OF HETEROAROMATIC COMPOUNDS Lei Shi and Yong-Gui Zhou 1 2. TRANSITION-METAL-CATALYZED HYDROACYLATION Vy M. Dong, Kevin G. M. Kou, and Diane N. Le 229 CUMULATIVE CHAPTER TITLES BY VOLUME 593 AUTHOR INDEX, VOLUMES 1-96 611 CHAPTER AND TOPIC INDEX, VOLUMES 1-96 617

Volume

v. 97 ISBN 9781119374541

Description

The 97th volume in this series for organic chemists in industry presents critical discussions of widely used organic reactions or particular phases of a reaction. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. The work includes tables that contain all possible examples of the reaction under consideration. Detailed procedures illustrate the significant modifications of each method.

Table of Contents

1. [2 + 2 + 2] Cycloadditions of Alkynes with Heterocumulenes and Nitriles Nicholas D. Staudaher, Ryan M. Stolley, and Janis Louie 1 2. Amide-Forming Ligation Reactions 203 Vijaya R. Pattabiraman, Ayodele O. Ogunkoya,and Jeffrey W. Bode Cumulative Chapter Titles by Volume 691 Author Index, Volumes 1-97 709 Chapter and Topic Index, Volumes 1-97 715

Volume

v. 98 ISBN 9781119456582

Description

The 98th volume in this series for organic chemists in academia and industry presents critical discussions of widely used organic reactions or particular phases of a reaction. The material is treated from a preparative viewpoint, with emphasis on limitations, interfering influences, effects of structure and the selection of experimental techniques. The work includes tables that contain all possible examples of the reaction under consideration. Detailed procedures illustrate the significant modifications of each method.

Table of Contents

1. The Saegusa Oxidation and Related Procedures 1 Jean Le Bras and Jacques Muzart 2. The Asymmetric Vinylogous Mukaiyama Aldol Reaction 173 Martin H. C. Cordes and Markus Kalesse Cumulative Chapter Titles by Volume 775 Author Index, Volumes 1-98 793 Chapter and Topic Index, Volumes 1-98 799

Volume

v. 99 ISBN 9781119456629

Description

ORGANIC REACTION

Table of Contents

1. Addition of Non-Stabilized Carbon-Based Nucleophilic Reagents to Chiral N-Sulfinyl Imines 1 Melissa A. Herbage, Jolaine Savoie, Joshua D. Sieber, Jean-Nicolas Desrosiers, Yongda Zhang, Maurice A. Marsini, Keith R. Fandrick, Daniel Rivalti, and Chris H. Senanayake 2. Iridium-Catalyzed, Enantioselective, Allylic Alkylations with Carbon Nucleophiles 423 Jian-Ping Qu, Gunter Helmchen, Ze-Peng Yang, Wei Zhang, and Shu-Li You Cumulative Chapter Titles by Volume 633 Author Index, Volumes 1-99 651 Chapter and Topic Index, Volumes 1-99 657

Volume

v. 100 ISBN 9781119456667

Description

Written by a "who is who" of leading organic chemists, this anniversary volume represent the Organic Reactions editors' choice of the most important, ground-breaking and versatile reactions in current organic synthesis. The 15 reaction types selected for this volume include reactions for carbon-carbon bond formation, cross-coupling reactions, hydro- and halofunctionalizations, among many others. In line with the successful recipe of the series, each chapter is focused on a single reaction, discussing its mechanism and stereochemistry, scope and limitations, applications to synthesis, comparison with other methods, and experimental procedures. Each chapter concludes with a tabular survey of selected key application examples, complete with reported reaction conditions and yields, to serve as a quick reference guide for synthesis planning.

Table of Contents

1. The Negishi Cross-Coupling Reaction 1 Colin Diner and Michael G. Organ 2. Generation and Trapping of Functionalized Aryl- and Heteroarylmagnesium and -Zinc Compounds 63 Ferdinand H. Lutter, Maximilian S. Hofmayer, Jeffrey M. Hammann, Vladimir Malakhov, and Paul Knochel 3. Copper-Catalyzed, Enantioselective Hydrofunctionalization of Alkenes 121 Haoxuan Wang and Stephen L. Buchwald 4. The Catalytic, Enantioselective Favorskii Reaction: in Situ Formation of Metal Alkynylides and Their Additions to Aldehydes 207 Yeshua Sempere and Erick M. Carreira 5. Enantioselective Lithiation-Substitution of Nitrogen-Containing Heterocycles 255 Kevin Kasten, Nico Seling, and Peter O'Brien 6. Catalytic, Enantioselective, Transfer Hydrogenation 329 Masahiro Yoshimura and Masato Kitamura 7. Hydrofunctionalization of Alkenes by Hydrogen-Atom Transfer 383 Ryan A. Shenvi, Jeishla L. M. Matos, and Samantha A. Green 8. Carbon-Carbon Bond Formation by Metallaphotoredox Catalysis 471 Eric D. Nacsa and David W. C. MacMillan 9. Suzuki-Miyaura Cross-Coupling 547 Alexander B. Pagett and Guy C. Lloyd-Jones 10. ortho-Directed C-H Alkylation of Substituted Benzenes 621 Yusuke Ano and Naoto Chatani 11. Catalytic, Enantioselective, C-H Functionalization to Form Carbon-Carbon Bonds 671 Qing-Feng Wu, Gang Chen, Jian He, and Jin-Quan Yu 12. Catalytic, Enantioselective Fluorination Reactions 749 Richard T. Thornbury and F. Dean Toste 13. Catalyst-Controlled Glycosylation 801 Samuel M. Levi and Eric N. Jacobsen 14. Palladium-Catalyzed Amination of Aryl Halides 853 John F. Hartwig, Kevin H. Shaughnessy, Shashank Shekhar, and Rebecca A. Green 15. Catalytic, Enantioselective, Copper-Boryl Additions to Alkenes 959 Amir H. Hoveyda, Ming Joo Koh, Kyunga Lee, and Jaehee Lee Cumulative Chapter Titles by Volume 1057 Author Index, Volumes 1-100 1075 Chapter and Topic Index, Volumes 1-100 1083

by "Nielsen BookData"

Details

• NCID: BA02878406
• ISBN:
  • 0471171689
  • 0471171697
  • 0471196150
  • 0471196185
  • 0471196193
  • 0471196215
  • 0471196223
  • 0471196231
  • 047119624X
  • 0471196258
  • 0471017418
  • 0471052094
  • 0471096571
  • 0471861413
  • 0471874906
  • 0471890138
  • 0471886718
  • 0471881015
  • 0471802298
  • 0471806730
  • 0471832537
  • 0471857483
  • 0471501697
  • 0471515949
  • 0471526320
  • 0471538418
  • 0471544094
  • 0471544108
  • 0471584797
  • 047130302X
  • 0471031615
  • 0471086193
  • 0471117374
  • 0471146994
  • 0471156558
  • 0471156574
  • 0471183946
  • 0471183954
  • 0471326097
  • 0471348880
  • 0471376140
  • 0471395684
  • 0471435112
  • 0471105902
  • 0471176559
  • 0471235814
  • 0471274488
  • 0471445339
  • 0471445320
  • 0471682624
  • 0471682608
  • 0471682586
  • 0470041455
  • 9780470098981
  • 9780470223970
  • 9780470254530
  • 9780470098998
  • 9780470423745
  • 9780470436905
  • 9780470530481
  • 9780470889077
  • 9780470638439
  • 9781118163801
  • 9781118356364
  • 9781118509418
  • 9781118513088
  • 9781118674253
  • 9781118674284
  • 9781118835227
  • 9781118841907
  • 9781118976517
  • 9781119013990
  • 9781119014003
  • 9781119103851
  • 9781119211211
  • 9781119281443
  • 9781119281436
  • 9781119281429
  • 9781119281412
  • 9781119308935
  • 9781119308928
  • 9781119374534
  • 9781119374541
  • 9781119456582
  • 9781119456629
  • 9781119456667
• LCCN: 42020265
• Country Code: us
• Title Language Code: eng
• Text Language Code: eng
• Place of Publication: New York
• Pages/Volumes: v.
• Size: 24 cm
• Classification:
  • NDC8 : 437.01
  • NLM : W1