Organic syntheses

著者

• Gilman, Henry
• Blatt, Albert Harold
• Horning, E. C. (Evan C.)
• Rabjohn, Norman
• Noland, Wayland E.
• Baumgarten, Henry E.
• Freeman, Jeremiah P.

書誌事項

Organic syntheses

John Wiley & Sons, 1932-

A rev. ed. of annual volumes

• collective v. 1
• collective v. 2
• collective v. 3
• collective v. 4
• collective v. 5
• collective v. 6
• collective v. 7
• collective v. 8
• collective v. 9
• collective v. 10
• collective v. 11
• collective v. 12

電子リソースにアクセスする 全7件

• Organic syntheses.

  v.1 1921 1921

  HathiTrust

  

• Organic syntheses.

  v.2 1922 1922

  HathiTrust

  

• Organic syntheses.

  v.3 1923 1923

  HathiTrust

  

• Organic syntheses.

  v.4 1924 1924

  HathiTrust

  

• Organic syntheses.

  v.5 1925 1925

  HathiTrust

  

• Organic syntheses.

  v.6 1926 1926

  HathiTrust

  

• Organic syntheses.

  v.7 1927 1927

  HathiTrust

  

すべて表示

注記

Vol. 1: Being a revised edition of annual volumes I-IX; Henry Gilman, editor-in-chief

Vol. 2: A revised edition of Annual volumes X-XIX; A.H. Blatt, editor-in-chief

Vol. 3: A revised edition of Annual volumes 20-29; E.C. Horning, editor-in-chief

Vol. 4: A revised edition of Annual volumes 30-39; Norman Rabjohn, editor-in-chief

Vol. 5: A revised edition of Annual volumes 40-49; Henry E. Baumgarten, editor-in-chief

Vol. 6: A revised edition of Annual volumes 50-59; Wayland E. Noland, editor-in-chief

Vol. 7: A revised edition of Annual volumes 60-64; Jeremiah P.Freeman, editor-in-chief

Vol. 8: A revised edition of Annual volumes 65-69; Jeremiah P. Freeman, editor-in-chief

Vol. 9: A revised edition of Annual volumes 70-74; Jeremiah P. Freeman, editor-in-chief

Vol. 10: A revised edition of Annual volumes 75-79; Jeremiah P. Freeman, editor-in-chief

Vol. 11: A revised edition of Annual volumes 80-84

Vol. 12: A revised edition of Annual volumes 85-89; Rick L. Danheiser, editor-in-chief

The place of publication of Vol.11: Hoboken, New Jersey

The place of publication of Vol.12: Hoboken, New Jersey

内容説明・目次

巻冊次

collective v. 11 ISBN 9780470395486

内容説明

Continuing the tradition of providing information on significant and interesting procedures with demonstrated utility in organic synthesis, this is a compilation of revised editions of Annual Volumes 80 through 84. Following precedent, there is no central theme, but the procedures can be organized into four categories: (1) asymmetric syntheses, chiral auxiliaries, and chiral ligands; (2) reactions that are promoted by metals or proceed via organometallic intermediates; (3) cycloaddition reactions; (4) valuable synthetic transformations and building blocks. This is a hands-on reference for professionals and students in organic and medicinal chemistry.

巻冊次

collective v. 5 ISBN 9780471057079

内容説明

Reflecting the increased pace of research and the many recent advances in organic chemistry, this series serves as a single-source compendium of the most up-to-date and significant procedures currently in use.

巻冊次

collective v. 2 ISBN 9780471079866

内容説明

Reflecting the increased pace of research and the many recent advances in organic chemistry, this series serves as a single-source compendium of the most up-to-date and significant procedures currently in use.

巻冊次

collective v. 9 ISBN 9780471242482

内容説明

Reflecting the increased pace of research and the many recent advances in organic chemistry, this series serves as a single-source compendium of the most up-to-date and significant procedures currently in use. Volume 9 consists of checked procedures previously published in annual volumes, revised and updated.

目次

Partial table of contents: Synthesis of 2-Substituted Naphthalenediol Derivatives UsingChromium Carbene Complexes:1-Acetoxy-2-Butyl-4-Methoxynaphthalene. Highly Reactive Calcium for the Preparation of OrganocalciumReagents: Preparation of 1-Adamantylcalcium Halides and TheirAddition to Ketones: 1-(1-Adamantyl) Cycohexanol. Bis(Trifluoroethyl)(Carboethoxymethyl)Phosphonate. N-tert--Butoxycarbonyl-2-Bromopyrrole. Allylic Alcohols by Alkene Transfer from Zirconium to Zinc:1-[(tert-Butyldiphenylsilyl)Oxy]-Dec-3-En-5-Ol. 1,3,5-Cyclooctatriene. Diethyl 1-Propyl-2-Oxoethylphosphonate. 3, 4-Diethylpyrrole. Dialkyl Mesoxalates by Ozonolysis of Dialkyl Benzalmalonates:Dimethyl Mesoxalate. Manganese-Copper-Catalyzed Conjugate Addition of OrganomagnesiumReagents to ,beta-Ethylenic Ketones:2-(1,1-Dimethylpentyl)-5-Methyl Cyclohexanone. 4-Dodecylbenzenesulfonyl Azides. Ethyl 2-Methyl-5-Phenyl-3-Furancarboxylate. Preparation and Reactions of Alkenylchromium Reagents:2-Hexyl-5-Phenyl-1-Penten-3-OL. Preparation and Use of (Methoxymethoxy)Methyllithium:1-(Hydroxymethyl) Cycloheptanol. Acetylenic Ethers from Alcohols and Their Reduction to Z- andE-Enol Ethers: 1-Menthoxy-1-Butyne. Methyl 5-Methoxyindole-2-Acetate. A General Method for the Preparation of -Branched Amino Acids:(S)-2-Methyl Proline. Synthesis of Epoxides Using Dimethyldioxirane: trans-StilbeneOxide. Tris(Trimethylsilyl)Silane. Indexes.

巻冊次

collective v. 3 ISBN 9780471409533

内容説明

Reflecting the increased pace of research and the many recent advances in organic chemistry, this series serves as a single-source compendium of the most up-to-date and significant procedures currently in use.

巻冊次

collective v. 10 ISBN 9780471445296

内容説明

Reflecting the increased pace of research and the many recent advances in organic chemistry, this series serves as a single-source compendium of the most up-to-date and significant procedures currently in use.

目次

• 7 -ACETOXY-(1H , 6H )-BICYCLO[4.4.1]UNDECA-2,4,8-TRIENE VIA CHROMIUMMEDIATED HIGHER ORDER CYCLOADDITION. STILLE COUPLINGS CATALYZED BY PALLADIUM-ON-CARBON WITH CUI AS A COCATALYST: SYNTHESIS OF 2-(4'-ACETYLPHENYL)THIOPHENE. ASYMMETRIC SYNTHESIS OF -AMINO ACIDS BY THE ALKYLATION OF PSEUDOEPHEDRINE GLYCINAMIDE: L-ALLYLGLYCINE AND N-Boc-L-ALLYLGLYCINE. 2-AMINO-3-FLUOROBENZOIC ACID. (1S,2R)-1-AMINOINDAN-2-OL. SYNTHESIS OF cis-4a(S),8a(R)-PERHYDRO-6(2H)-ISOQUINOLINONES FROM QUININE: 4a(S), 8a(R)-2-BENZOYLOCTAHYDRO-6(2H)-ISOQUINOLINONE. N-BENZYL-2,3-AZETIDINEDIONE. SULFINIMINES (THIOOXIMINE S-OXIDES): ASYMMETRIC SYNTHESIS OF METHYL (R)-(th)-b-PHENYLALANATE FROM (S)-(th)-N-(BENZYLIDENE)-p-TOLUENESULFINAMIDE. 2-(N-BENZYL-N-MESITYLENESULFONYL)AMINO-1-PHENYL-1-PROPYL PROPIONATE. REGIOSELECTIVE MONOALKYLATION OF KETONES VIA THEIR MANGANESE ENOLATES: 2-BENZYL-6-METHYLCYCLOHEXANONE FROM 2-METHYLCYCLOHEXANONE. SYNTHESIS OF (-)-(E.S)-3-(BENZYLOXY)-1-BUTENYL PHENYL SULFONE VIA A HORNER-WADSWORTH- EMMONS REACTION OF (-)-(S)-2-(BENZYL OXY)PROPANAL. 1-[N-BENZYLOXYCARBONYL-(1S)-1-AMINO-2-OXOETHYL]-4-METHYL-2,6,7-TRIOXABICYCLO[2.2.2]OCTANE. (3,4,5-TRIFLUOROPHENYL)BORONIC ACID-CATALYZED AMIDE FORMATION FROM CARBOXYLIC ACIDS AND AMINES: N-BENZYL-4-PHENYLBUTYRAMIDE. PHOTOCHEMICAL SYNTHESIS OF BICYCLO[1.1.1]PENTANE-1,3-DICARBOXYLIC ACID. BICYCLOPROPYLIDENE. RESOLUTION OF 1,1'-Bi-2-NAPHTHOL. (R,R)-N,N'-BIS(3,5-DI-tert-BUTYLSALICYLIDENE-1,2-CYCLOHEXANEDIAMINO MANGANESE(III) CHLORIDE, A HIGHLY ENANTIOSELECTIVE EPOXIDATION CATALYST. SYNTHESIS OF UNSYMMETRICAL BIARYLS USING A MODIFIED SUZUKI CROSSCOUPLING: 4-BIPHENYLCARBOXALDEHYDE. EFFICIENT SYNTHESIS OF HALOMETHYL-2,2'-BIPYRIDINES: 4,4'-BIS(CHLOROMETHYL)-2,2'-BIPYRIDINE. (R)-(+)- AND (S)-(-)-2,2'-BIS-(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL (BINAP). BIS(PINACOLATO)DIBORON. PREPARATION OF BIS(2,4,6-TRIMETHYLPYRIDINE)IODINE(I) HEXAFLUOROPHOSPHATE AND BIS(2,4,6-TRIMETHYLPYRIDINE)BROMINE(I) HEXAFLUOROPHOSPHATE. 3-(4-BROMOBENZOYL)PROPANOIC ACID. BROMOFLUORINATION OF ALKENES: 1-BROMO-2-FLUORO-2-PHENYLPROPANE. SYNTHESIS OF 4-(2-BROMO-2-PROPENYL)-4-METHYL- -BUTYROLACTONE BY THE REACTION OF ETHYL LEVULINATE WITH (2-BROMOALLYL) DIISOPROPOXYBORANE PREPARED BY HALOBORATION OF ALLENE. DIASTEREOSELECTIVE SYNTHESIS OF PROTECTED VICINAL AMINO ALCOHOLS: (S)-2-[(4S)-N-tert-BUTOXYCARBONYL-2,2-DIMETHYL-1,3-OXAZOLIDINYL]-2-tert-BUTYLDIMETHYLSILOXYETHANAL FROM A SERINE-DERIVED ALDEHYDE. BUTYL 4-CHLOROPHENYL SULFIDE. PHOTOINDUCED-ADDITION OF METHANOL TO (5S)-(5-O-tert-BUTYLDIMETHYLSILOXYMETHYL) FURAN-2(5H)-ONE: (4R,5S)-4-HYDROXYMETHYL-(5-O-tert-BUTYLDIMETHYLSILOXYMETHYL)FURAN-2(5H)-ONE. [3 + 4] ANNULATION USING A [ -(TRIMETHYLSILYL)ACRYLOYL]SILANE AND THE LITHIUM ENOLATE OF AN ?, ?-UNSATURATED METHYL KETONE: (1R*,6S*,7S*)-4-(tert-BUTYLDIMETHYLSILOXY)-6-(TRIMETHYLSILYL)BICYCLO[5.4.0]UNDEC-4-EN-2-ONE. (tert-BUTYLDIMETHYLSILYL)ALLENE. SYNTHESIS AND UTILIZATION OF INDIUM (I) IODIDE FOR IN SITU FORMATION OF ENANTIOENRICHED ALLENYLINDIUM REAGENTS AND THEIR ADDITION TO ALDEHYDES: (2R,3S,4S)-1-(tert-BUTYLDIPHENYLSILYLOXY)-2,4-DIMETHYL-5-HEXYN-3-OL. DIMETHYL SQUARATE AND ITS CONVERSION TO 3-ETHENYL-4-METHOXYCYCLOBUTENE-1,2-DIONE AND 2-BUTYL-6-ETHENYL-5-METHOXY-1,4-BENZOQUINONE. PREPARATION OF 1-BUTYL-3-METHYL IMIDAZOLIUM-BASED ROOM TEMPERATURE IONIC LIQUIDS. PREPARATION AND DIELS-ALDER REACTION OF A 2-AMIDO SUBSTITUTED FURAN: tert-BUTYL 3a-METHYL-5-OXO-2,3,3a,4,5,6-HEXAHYDROINDOLE-1-CARBOXYLATE. (S)-3-(tert-BUTYLOXYCARBONYLAMINO)-4-PHENYLBUTANOIC ACID. USE OF CERIUM(III) CHLORIDE IN THE REACTIONS OF CARBONYL COMPOUNDS WITH ORGANOLITHIUMS OR GRIGNARD REAGENTS FOR THE SUPPRESSION OF ABNORMAL REACTIONS: 1-BUTYL-1,2,3,4-TETRAHYDRO-1-NAPHTHOL. CAMPHORQUINONE AND CAMPHORQUINONE MONOXIME. PHOTO-INDUCED RING EXPANSION OF 1-TRIISOPROPYLSILYLOXY-1-AZIDOCYCLOHEXANE: PREPARATION OF e-CAPROLACTAM. 3-CHLORO-2-(CHLOROMETHYL)-1-PROPENE. 1-CHLORO-(2S,3S)-DIHYDROXYCYCLOHEXA-4,6-DIENE. 6-CHLORO-1-HEXENE AND 8-CHLORO-1-OCTENE. 2-CHLOROPHENYL PHOSPHORODICHLORIDOTHIOATE. 3-CYCLOPENTENE-1-CARBOXYLIC ACID. CYCLOPROPENE: A NEW SIMPLE SYNTHESIS AND ITS DIELS-ALDER REACTION WITH CYCLOPENTADIENE. CYCLOPROPYLACETYLENE. EFFICIENT SYNTHESIS OF BROMIDES FROM CARBOXYLIC ACIDS CONTAINING A SENSITIVE FUNCTIONAL GROUP: DEC-9-ENYL BROMIDE FROM 10-UNDECENOIC ACID. TRIBUTYLSTANNANE (Bu3SnH)-CATALYZED BARTON-McCOMBIE DEOXYGENATION OF ALCOHOLS: 3-DEOXY-1,2:5,6-BIS-O-(1-METHYLETHYLIDENE)-?-D-ribo-HEXOFURANOSE. -30,50-DI-O-BENZOYLTHYMIDINE. PREPARATION OF ENANTIOMERICALLY PURE -N,N-DIBENZYLAMINOALDEHYDES: S-2-(N,N-DIBENZYLAMINO)-3-PHENYLPROPANAL. SYNTHESIS OF SYMMETRICAL trans-STILBENES BY A DOUBLE HECK REACTION OF (ARYLAZO)-AMINES WITH VINYLTRIETHOXYSILANE: trans-4,4'-DIBROMOSTILBENE. PREPARATION AND USE OF N,N'-DI-Boc-N"-TRIFLYLGUANIDINE. SYNTHESIS OF 8,8-DICYANOHEPTAFULVENE FROM CYCLOHEPTATRIENYLIUM TETRAFLUOROBORATE AND BROMOMALONONITRILE. DICYCLOHEXYLBORON TRIFLUOROMETHANESULFONATE. (R,R)-1,2:4,5-DIEPOXYPENTANE. ASYMMETRIC SYNTHESIS OF DIETHYL (R)-(-)-(1-AMINO-3-METHYLBUTYL)PHOSPHONATE. DIETHYL [(PHENYLSULFONYL)METHYL]PHOSPHONATE. 6,7-DIHYDROCYCLOPENTA-1,3-DIOXIN-5(4H)-ONE. SYNTHESIS OF CHIRAL NON-RACEMIC DIOLS FROM (S,S)-1,2,3,4-DIEPOXYBUTANE: (2S,3S)-DIHYDROXY-1,4-DIPHENYLBUTANE. PREPARATION OF (E)-1-DIMETHYLAMINO-3-tert-BUTYLDIMETHYLSILOXY-1,3-BUTADIENE. (2S)-(-)-3-exo-(DIMETHYLAMINO)ISOBORNEOL [(2S)-(-)-DAIB]. 4-DIMETHYLAMINO-N-TRIPHENYLMETHYLPYRIDINIUM CHLORIDE. (R,R)- AND (S,S)-N,N0-DIMETHYL-1,2-DIPHENYLETHYLENE-1,2-DIAMINE. SYNTHESIS OF 1,1-DIMETHYLETHYL (S)-4-FORMYL-2,2-DIMETHYL-3-OXAZOLIDINECARBOXYLATE BY OXIDATION OF THE ALCOHOL. CONVERSION OF NITRILES INTO TERTIARY AMINES: N,N-DIMETHYLHOMOVERATRYLAMINE. NICKEL-CATALYZED COUPLING OF ARYL O-CARBAMATES WITH GRIGNARD REAGENTS: 2,7-DIMETHYLNAPHTHALENE. [4 + 3] CYCLOADDITION IN WATER: 2,4-endo,endo-DIMETHYL-8-OXABICYCLO[3.2.1]OCT-6-EN-3-ONE. SYNTHESIS OF -LACTONES BY ALDOLIZATION OF KETONES WITH PHENYL ESTER ENOLATES: 3,3-DIMETHYL-1-OXASPIRO[3.5]NONAN-2-ONE. ANTI-SELECTIVE BORON-MEDIATED ASYMMETRIC ALDOL REACTION OF CARBOXYLIC ESTERS: (2S, 3R)-2,4-DIMETHYL-1,3-PENTANEDIOL. (4R,5R)-2,2-DIMETHYL- , , ', '-TETRA(NAPHTH-2-YL)-1,3-DIOXOLANE-4,5-DIMETHANOL FROM DIMETHYL TARTRATE AND 2-NAPHTHYLMAGNESIUM BROMIDE. DIMETHYLTITANOCENE. 9,10-DIPHENYLPHENANTHRENE. (R)-2-DIPHENYLPHOSPHINO-20-METHOXY-1,1'-BINAPHTHYL. 5-PHENYLDIPYRROMETHANE AND 5,15-DIPHENYLPORPHYRIN. (4R,5S)-4,5-DIPHENYL-3-VINYL-2-OXAZOLIDINONE. 1S-(-)-1,3-DITHIANE 1-OXIDE. ETHYL (R)-2-AZIDOPROPIONATE. ETHYL 5-CHLORO-3-PHENYLINDOLE-2-CARBOXYLATE. ETHYL 3-(p-CYANOPHENYL)PROPIONATE FROM ETHYL 3-IODOPROPIONATE AND p-CYANOPHENYLZINC BROMIDE. 9-ETHYL-3,6-DIMETHYLCARBAZOLE (DMECZ)*. ETHYL GLYCIDATE FROM (S)-SERINE: ETHYL (R)-(+)-2,3-EPOXYPROPANOATE. (-)-2,4-O-ETHYLIDENE-D-ERYTHROSE AND ETHYL (E)-(-)-4,6-OETHYLIDENE-(4S,5R,1'R)-4,5,6-TRIHYDROXY-2-HEXENOATE. COPPER-CATALYZED CONJUGATE ADDITION OF FUNCTIONALIZED ORGANOZINC REAGENTS TO , ?-UNSATURATED KETONES: ETHYL 5-(3-OXOCYCLOHEXYL)PENTANOATE. ULLMAN METHOXYLATION IN THE PRESENCE OF A 2,5-DIMETHYLPYRROLE-BLOCKED ANILINE: 2-FLUORO-4-METHOXYANILINE. PALLADIUM-CATALYZED AMINATION OF ARYL HALIDES AND ARYL TRIFLATES: N-HEXYL-2-METHYL-4-METHOXYANILINE AND N-METHYL-N-(4-CHLOROPHENYL)ANILINE. 4-HYDROXY[1-13C]BENZOIC ACID. N-HYDROXY-4-(p-CHLOROPHENYL)THIAZOLE-2(3H)-THIONE. [4 + 2] CYCLOADDITION OF 1-DIMETHYLAMINO-3-tert-BUTYLDIMETHYLSILOXY-1,3-BUTADIENE WITH METHYL ACRYLATE: 4-HYDROXYMETHYL-2-CYCLOHEXEN-1-ONE. ASYMMETRIC SYNTHESIS OF (M)-2-HYDROXYMETHYL-1-(2-HYDROXY-4,6-DIMETHYLPHENYL)-NAPHTHALENE VIA A CONFIGURATIONALLY UNSTABLE BIARYL LACTONE. SYNTHESIS AND DIASTEREOSELECTIVE ALKYLATION OF PSEUDOEPHEDRINE AMIDES: (1S,2S)-PSEUDOEPHEDRINEPROPIONAMIDE AND [(1S,2S)-PSEUDOEPHEDRINE-(R)-2-METHYLHYDROCINNAMAMIDE. GENERATION AND USE OF LITHIUM PENTAFLUOROPROPEN-2-OLATE: 4-HYDROXY-1,1,1,3,3- PENTAFLUORO-2-HEXANONE HYDRATE. (R)-(+)-2-HYDROXY-1,2,2-TRIPHENYLETHYL ACETATE. 2-(4-METHOXYPHENYL)-2-CYCLOHEXEN-1-ONE: PREPARATION OF 2-IODO-2-CYCLOHEXEN-1-ONE AND SUZUKI COUPLING WITH 4-METHOXYPHENYLBORONIC ACID. O4,O5-ISOPROPYLIDENE-1,2:3,6-DIANHYDRO-D-GLUCITOL FROM ISOSORBIDE. -MERCAPTOPROPIONITRILE (2-CYANOETHANETHIOL). PREPARATION OF SECONDARY AMINES FROM PRIMARY AMINES VIA 2-NITROBENZENESULFONAMIDES: N-(4-METHOXYBENZYL)-3-PHENYLPROPYLAMINE. 4-METHOXYCARBONYL-2-METHYL-1,3-OXAZOLE. SELECTIVE PROTECTION OF 1,3-DIOLS AT THE MORE HINDERED HYDROXY GROUP: 3-(METHOXYMETHOXY)-1-BUTANOL. (S,E)-1-(METHOXYMETHOXY)-1-TRIBUTYLSTANNYL-2-BUTENE. ACCELERATED SUZUKI COUPLING VIA A LIGANDLESS PALLADIUM CATALYST: 4-METHOXY-20-METHYLBIPHENYL. NUCLEOPHILIC AROMATIC SUBSTITUTION OF ARYL FLUORIDES BY SECONDARY NITRILES: 2-(2-METHOXYPHENYL)-2-METHYLPROPIONITRILE. TRANSFORMATION OF PSEUDOEPHEDRINE AMIDES INTO HIGHLY ENANTIOMERICALLY ENRICHED ALDEHYDES, ALCOHOLS, AND KETONES: (R)- -METHYLBENZENEPROPANAL, (R)- -METHYLBENZENEPROPANOL, AND (R)-2-METHYL-1-PHENYL-3-HEPTANONE. SYNTHESIS OF 4-, 5-, AND 6-METHYL-2,2'-BIPYRIDINE BY A NEGISHI CROSS-COUPLING STRATEGY: 5-METHYL-2,2'-BIPYRIDINE. (1'S,2'S)-METHYL-3O,4O-(1',2'-DIMETHOXYCYCLOHEXANE-10,20 DIYL)- -DMANNOPYRANOSIDE. FORMATION OF -KETO ESTERS FROM -KETO ESTERS: METHYL 5,5-DIMETHYL-4-OXOHEXANOATE. SYNTHESIS OF CHIRAL (E)-CROTYLSILANES: [3R- AND 3S-]-(4E)-METHYL 3-(DIMETHYLPHENYLSILYL)-4-HEXENOATE. IN SITU CATALYTIC EPOXIDATION OF OLEFINS WITH TETRAHYDROTHIOPYRAN-4-ONE AND OXONE: trans-2-METHYL-2,3-DIPHENYLOXIRANE. ALLYLINDATION IN AQUEOUS MEDIA: METHYL 3-(HYDROXYMETHYL)-4-METHYL-2-METHYLENEPENTANOATE. SYNTHESIS OF AMINO ACID ESTER ISOCYANATES: METHYL (S)-2-ISOCYANATO-3-PHENYLPROPANOATE. REDUCTION OF SULFONYL HALIDES WITH ZINC POWDER: S-METHYL METHANETHIOSULFONATE. METHYL CARBAMATE FORMATION VIA MODIFIED HOFMANN REARRANGEMENT REACTIONS: METHYL N-(p-METHOXYPHENYL)CARBAMATE. METHYL 2,3-O-(6,6'-OCTAHYDRO-6,6'-BI-2H-PYRAN-2,2'-DIYL)- -D-GALACTOPYRANOSIDE. [R-(R*,S*)]- -METHYL- -PHENYL-1-PYRROLIDINEETHANOL. METHYL (S)-2-PHTHALIMIDO-4-OXOBUTANOATE. THE SYNTHESIS OF 2-ALKYL-4-PYRONES FROM MELDRUM'S ACID: 2-METHYL-4HPYRAN-4-ONE. CATALYTIC ASYMMETRIC SYNTHESIS OF NITROALDOLS USING A LANTHANUM-LITHIUM-BINOL COMPLEX: (2S,3S)-2-NITRO-5-PHENYL-1,3-PENTANEDIOL. 3-NITROPROPANAL, 3-NITROPROPANOL, AND 3-NITROPROPANAL DIMETHYL ACETAL. [4 + 3] CYCLOADDITION OF AMINOALLYL CATIONS WITH 1,3-DIENES: 11-OXATRICYCLO-[4.3.1.12,5]UNDEC-3-EN-10-ONE. 2-(3-OXOBUTYL)CYCLOPENTANONE-2-CARBOXYLIC ACID ETHYL ESTER. 1-OXO-2-CYCLOHEXENYL-2-CARBONITRILE. PENTA-1,2-DIEN-4-ONE (ACETYLALLENE). ISOMERIZATION OF -ALKYNYL ALLYLIC ALCOHOLS TO FURANS CATALYZED BY SILVER NITRATE ON SILICA GEL: 2-PENTYL-3-METHYL-5-HEPTYLFURAN. (+)-(1S,2R)- AND (-)-(1R,2S)-trans-2-PHENYLCYCLOHEXANOL VIA SHARPLESS ASYMMETRIC DIHYDROXYLATION (AD). (R)-3-PHENYLCYCLOHEXANONE. (2S,3S)-(+)-(3-PHENYLCYCLOPROPYL)METHANOL. MOLYBDENUM CARBONYL-CATALYZED ALKYNOL CYCLOISOMERIZATION: 2-PHENYL-2,3-DIHYDROFURAN. GENERATION OF 1-PROPYNYLLITHIUM FROM (Z/E)-1-BROMO-1-PROPENE: 6-PHENYLHEX-2-YN-5-EN-4-OL. CATALYTIC ASYMMETRIC ALLYLATION REACTIONS: (S)-1-PHENYLMETHOXY)-4-PENTEN-2-OL. CATALYTIC ENANTIOSELECTIVE ADDITION OF DIALKYLZINCS TO ALDEHYDES USING (2S)-(-)-3-exo-(DIMETHYLAMINO)ISOBORNEOL [(2S)-DAIB]: (S)-1-PHENYL-1-PROPANOL. MONO-C-METHYLATION OF ARYLACETONITRILES AND METHYL ARYLACETATES BY DIMETHYL CARBONATE: A GENERAL METHOD FOR THE SYNTHESIS OF PURE 2-ARYLPROPIONIC ACIDS. 2-PHENYLPROPIONIC ACID. PREPARATION OF CYANOALKYNES: 3-PHENYL-2-PROPYNENITRILE. N-VINYLPYRROLIDIN-2-ONE AS A 3-AMINOPROPYL CARBANION EQUIVALENT IN THE SYNTHESIS OF SUBSTITUTED 1-PYRROLINES: 2-PHENYL-1-PYRROLINE. (PHENYL)[2-(TRIMETHYLSILYL)PHENYL]IODONIUM TRIFLATE, AN EFFICIENT AND MILD BENZYNE PRECURSOR: PREPARATION OF 1,4-DIHYDRONAPHTHALENE 1,4-OXIDE. [1.1.1]PROPELLANE. 1,2-METALLATE REARRANGEMENT: (Z)-4-(2-PROPENYL)-3-OCTEN-1-OL. 1,4,7,10-TETRAAZACYCLODODECANE. (+)-(1R,2S,3R)-TETRACARBONYL[(1-3Z)-1-(PHENYLSULFONYL)-BUT-2-EN-1-YL]IRON(1+) TETRAFLUOROBORATE. USE OF 1,2,4,5-TETRABROMOBENZENE AS A 1,4-BENZADIYNE EQUIVALENT: anti- AND syn-1,4,5,8-TETRAHYDROANTHRACENE 1,4:5,8-DIEPOXIDES. INDOLE SYNTHESIS BY Pd-CATALYZED ANNULATION OF KETONES WITH o-IODOANILINE: 1,2,3,4-TETRAHYDROCARBAZOLE. 6A-O-p-TOLUENESULFONYL- -CYCLODEXTRIN. 6A-O-p-TOLUENESULFONYL- -CYCLODEXTRIN. -TOSYLBENZYL ISOCYANIDE. THE DESS-MARTIN PERIODINANE: 1,1,1-TRIACETOXY-1,1-DIHYDRO-1,2-BENZIODOXOL-3-(1H)-ONE. WITTIG OLEFINATION OF PERFLUOROALKYL CARBOXYLIC ESTERS
• SYNTHESIS OF 1,1,1-TRIFLUORO-2-ETHOXY-5-PHENYLPENT-2-ENE AND 1-PERFLUOROALKYL EPOXY ETHERS: 1,1,1-TRIFLUORO-2-ETHOXY-2,3-EPOXY-5-PHENYLPENTANE. 2-TRIMETHYLSILYLETHANESULFONYL CHLORIDE (SES-CI). TRIS(2-PERFLUOROHEXYLETHYL)TIN HYDRIDE: A HIGHLY FLUORINATED TIN HYDRIDE WITH ADVANTAGEOUS FEATURES OF EASY PURIFICATION. VITAMIN D2 FROM ERGOSTEROL. TYPE OF REACTION INDEX. TYPE OF COMPOUND INDEX. FORMULA INDEX. AUTHOR INDEX. GENERAL INDEX. HAZARD AND WASTE DISPOSAL INDEX. CONCORDANCE INDEX.

巻冊次

collective v. 7 ISBN 9780471515593

内容説明

A revised collective volume, this book incorporates standardized nomenclature, presentation of spectroscopic data, and other previously variable elements of style. It includes many improved procedures and presents procedures revised to reduce use of hazardous solvents, along with extensive hazard warnings and disposal information. Multiple indexes are provided for ease of reference.

目次

Partial table of contents: Reductive Coupling of Carbonyls to Alkenes: Adamantylideneadamantane. Reduction of Quinones with Hydriodic Acid: Benz[a]anthracene. Conversion of Ketones to Cyanohydrins: Benzophenone Cyanohydrin. Oxidation of 5-Aminotetrazoles: Benzyl Isocyanide. Cyclobutanone. Cyclobutene. Anodic Oxidation of Acids: Dimethyl Decanedioate. Diphenyl Phosphorazidate. Hexafluoroacetone. Hexamethyl Dewar Benzene. Methyl Diformylacetate. Preparation of Low-Halide Methyllithium. 2-Nitropropene. Cyanic Acid Esters from Phenols: Phenyl Cyanate. Ricinelaidic Acid Lactone. Trifluoroacetyl Triflate. Type of Reaction Index. Type of Compound Index. Formula Index. Author Index. General Index. Hazard Index. Concordance Index.

巻冊次

collective v. 8 ISBN 9780471585657

内容説明

Reflecting the increased pace of research and the many recent advances in organic chemistry, this series serves as a single-source compendium of the most up-to-date and significant procedures currently in use.

目次

Reductive Coupling of Carbonyls to Alkenes: Adamantylideneadamantane. Reduction of Quinones with Hydriodic Acid: Benz[a]anthracene. Conversion of Ketones to Cyanohydrins: Benzophenone Cyanohydrin. Oxidation of 5-Aminotetrazoles: Benzyl Isocyanide. Cyclobutanone. Cyclobutene. Anodic Oxidation of Acids: Dimethyl Decanedioate. Diphenyl Phosphorazidate. Hexafluoroacetone. Hexamethyl Dewar Benzene. Methyl Diformylacetate. Preparation of Low-Halide Methyllithium. 2-Nitropropene. Cyanic Acid Esters from Phenols: Phenyl Cyanate. Ricinelaidic Acid Lactone. Trifluoroacetyl Triflate. Type of Reaction Index. Type of Compound Index. Formula Index. Author Index. General Index. Hazard Index. Concordance Index.

巻冊次

collective v. 4 ISBN 9780471704706

内容説明

Reflecting the increased pace of research and the many recent advances in organic chemistry, this series serves as a single-source compendium of the most up-to-date and significant procedures currently in use.

目次

Chapter 1 Algebra of Vectors and Matrices Vector Spaces Chapter 2 Probability Theory, Tools and Techniques Chapter 3 Continuous Probability Models Chapter 4 The Theory of least Squares and Analysis of Variance Chapter 5 Criteria and Methods of Estimation Chapter 6 Large Sample Theory and Methods Chapter 7 Theory of Statistical Inference Chapter 8 Multivariate Analysis Publications of the Author Author Index Subject Index

巻冊次

collective v. 6 ISBN 9780471852438

内容説明

Contains the procedures previously published in annual volumes 50-59, revised and updated where necessary. Efforts have been made to standardize the style of experimental procedures and the presentation of spectroscopic data. Increasing emphasis on the toxicology of organic compounds has led to the inclusion of additional hazard warnings, particularly for benzene, hexamethylphosphoric triamide (HMPA), and methyl iodide at the many places where they appear. Some experimental procedures have been improved, references have been added, and the index has been greatly expanded and simultaneously consolidated for efficient and easy use.

目次

• [The numbers in parentheses refer to the annual volume (in boldface type) and page number where each procedure first appeared] Acylamidoalkyl Acetophenones from Substituted Phenethylamines: 2-(2-Acetamidoethyl)-4,5-dimethoxyacetophenone (56, 3) Thiol Protection with the Acetamidomethyl Group: S-Acetamidomethyl-l-cysteine Hydrochloride (59, 190) Acetic Formic Anhydride (50, 1) Acetone Hydrazone (50, 3) Preparation of Hydrazones: Acetophenone Hydrazone (50, 102) 3 -Acetoxy-5 -cyanocholestan-7-one (52, 100) p-Acetyl- -bromohydrocinnamic Acid (51, 1) , -Dehydrogenation of -Dicarbonyl Compounds by Selenoxide Elimination: 2-Acetyl-2-cyclohexen-1-one (59, 58) 2-Acetyl-1,3-cyclopentanedione (52, 1) 3-Acetyl-2,4-dimethylfuran (53, 1) 2-Acetyl-6-methoxynaphthalene (53, 5) Copper Catalyzed Arylation of -Dicarbonyl Compounds: 2-(1-Acetyl-2-oxopropyl)benzoic Acid (58, 52) 5-Acetyl- 1,2,3,4,5-pentamethylcyclopentadiene (56, 1) 2-Adamantanecarbonitrile (57, 8) Tertiary Alcohols from Hydrocarbons by Ozonation on Silica Gel: 1-Adamantanol (59, 176) Adamantanone (53, 8) Enone Reduction-Enolate Alkylation Sequence: 2-Allyl-3-methylcyclohexanone (56, 52) Preparation of N-Aminoaziridines: trans-1-Amino-2,3-diphenylaziridine, 1-Amino-2-phenylaziridine, and 1-Amino-2-phenylaziridinium Acetate (55, 114) Reduction of Ketones by Use of the Tosylhydrazone Derivatives: Androstan-17 -Ol (52, 122) Aldehydes from 4,4-Dimethyl-2-oxazoline and Grignard Reagents: o-Anisaldehyde (54, 42) [18]Annulene (54, 1) Azetidine (53, 13) Azoethane (52, 11) Diels-Alder Addition of Perchlorobenzyne: Benzobarrelene (59, 71) Benzocyclopropene (55, 12) -Chlorination of Carboxylic Acids Mediated by Chlorosulfonic Acid: -Benzoylamino- -chlorocaproic Acid (59, 20) 1-N-Acylamino-1,3-dienes from 2,4-pentadienoic Acids by the Curtius Rearrangement: Benzyl trans-1,3-Butadiene-1-carbamate (59, 1) Benzyl Chloromethyl Ether (52, 16) 1-Benzylindole (54, 58) N-Alkylindoles from the Alkylation of Sodium Indolide in Hexamethylphosphoric Triamide: 1-Benzylindole (54, 60) 3-Alkylated and 3-Acylated Indoles from a Common Precursor: 3-Benzylindole and 3-Benzoylindole (56, 8) Alkylation of Isoquinolines via 2-Benzoyl-1,2-dihydroisoquinaldonitriles: 1-Benzylisoquinoline (56, 19) The Formation and Alkylation of Specific Enolate Anions from an Unsymmetrical Ketone: 2-Benzyl-2-methylcyclohexanone and 2-Benzyl-6-methylcyclohexanone (52, 39) Sulfide Synthesis: Benzyl Sulfide (58, 138) Bicyclo[1.1.0]butane (51, 55) Boranes in Functionalization of Dienes to Cyclic Ketones: Bicyclo[3.3.1]nonan-9-one (58, 24) Bicyclo[3.2.1]octan-3-one (51, 60) Bicyclo[2.1.0]pent-2-ene (55, 15) Dehydroxylation of Phenols
• Hydrogenolysis of Phenolic Ethers: Biphenyl (51, 82) Controlled-Potential Electrolytic Reduction: 1,1-Bis(bromomethyl)cyclopropane (52, 22) Bis(trifluoromethyl)diazomethane (50, 6) Bis[2,2,2-trifluoro-1-phenyl-1-(trifluoromethyl)ethoxy] Diphenyl Sulfurane (57, 22) Acyloin Condensation in which Chlorotrimethylsilane is Used as a Trapping Agent: 1,2-Bis(trimethylsilyloxy)cyclobutene and 2-Hydroxycyclobutanone (57, 1) 2-Bornene (51, 66) Selective -Bromination of an Aralkyl Ketone with Phenyltrimethylammonium Tribromide: 2-Bromoacetyl-6-methoxynaphthalene and 2,2-Dibromoacetyl-6-methoxynaphthalene (53, 111) Mercury(II) Oxide-Modified Hunsdiecker Reaction: 1-Bromo-3-chlorocyclobutane (51, 106) para-Bromination of Aromatic Amines: 4-Bromo-N,N-dimethyl-3-(trifluoromethyl)aniline (55, 20) Bromohydrins from Alkenes and N-Bromosuccinimide in Dimethyl Sulfoxide
• erythro-2-Bromo-1,2-diphenylethanol (59, 16) Chain Elongation of Alkenes via gem-Dihalocyclopropanes: 2-Bromo-3,3-diphenyl-2-propen-1-yl acetate (56, 32) 2-Bromohexanoyl Chloride (55, 27) 1-Bromo-3-methyl-2-butanone (55, 24) trans, trans-1,3-Butadiene-1,4-diyl Diacetate (50, 24) A New Reagent for tert-Butoxycarbonylation: 2-tert-Butoxycarbonyloxyimino-2-phenylacetonitrile (59, 95) tert-Butoxycarbonyl-l-proline (53, 25) tert-Butyl Azidoformate (50, 9
• 57, 122) tert-Butylcyanoketene (55, 32) cis-4-tert-Butylcyclohexanol (50, 13) Polymeric Carbodiimide. Moffat Oxidation: 4-tert-Butylcyclohexanone (56, 99) Oxidation of Alcohols by Methyl Sulfide- N-Chlorosuccinimide- Triethylamine: 4-tert-Butylcyclohexanone (58, 122) 2-tert-Butyl-1,3-diaminopropane (53, 21) Photochemical Ring-Contraction of 2-Ethoxypyrrolin-5-ones to Cyclopropanone Derivatives: tert-Butyl N-(1-Ethoxycyclopropyl)carbamate (59, 132) Phase-Transfer Hofmann Carbylamine Reaction: tert-Butyl Isocyanide (55, 96) Sulfide Synthesis in Preparation of Unsymmetrical Dlalkyl Disulfides: sec-Butyl Isopropyl Disulfide (58, 147) 3-Butyl-2-Methylhept-1-en-3-ol (52, 19) Monoalkylation of , -Unsaturated Ketones via Metalloenamines: 1-Butyl-10-methyl- 1(9)-2-octalone (57, 69) -Diketones from Methyl Alkyl Ketones: 3-n-Butyl-2,4-pentanedione (51, 90) Secondary and Tertiary Alkyl Ketones from Carboxylic Acid Chlorides and Lithium Phenylthio(alkyl)cuprate Reagents: tert-Butyl Phenyl Ketone (55, 122) Removal of N -Benzyloxycarbonyl Groups from Sulfur-Containing Peptides by Catalytic Hydrogenation in Liquid ammonia: O-tert-Butyl-L-seryl-S-tert-butyl-l-cysteine tert-Butyl Ester (59, 159) Esterification of Hindered Alcohols: tert-Butyl p-Toluate (51, 96) Peptide Syntheses Using N-Ethyl-5-phenylisoxazolium-3'-sulfonate: Carbobenzoxy-L-asparaginyl-L-leucine Methyl Ester and N-Carbobenzoxy-3-hydroxy-L-prolylglycylglycine Ethyl Ester (56, 88) Carbonyl Cyanide (51, 70) 3-Chlorocyclobutanecarboxylic Acid (51, 73) (z)-4-Chloro-4-hexenyl Trifluoroacetate (57, 26) m-Chloroperbenzoic Acid (50, 15) 3-(4-Chlorophenyl)-5-(4-Methoxyphenyl)Isoxazole (55, 39) -Chloro Enamines, Reactive Intermediates for Synthesis: 1-Chloro-N,N,2-trimethylpropenylamine (59, 26) Modified Clemmensen Reduction: Cholestane (53, 86) Conjugate Reduction of , -Unsaturated p-Toluenesulfonylhydrazones to Alkenes with Catecholborane: 5 -Cholest-3-ene (59, 42) 5 -Cholest-3-Ene-5-Acetaldehyde (54, 71) 18-Crown-6 (57, 30) Cinnamonitrile (50, 18) Preparation of Cyano Compounds Using Alkylaluminum Intermediates: 1-Cyano-6-methoxy-3,4-Dihydronaphthalene (52, 96) Cyclobutadieneiron Tricarbonyl (50, 21) Aldehydes from acid Chlorides by Reduction of Ester-mesylates with Sodium Borohydride: Cyclobutanecarboxaldehyde (51, 11) Cyclic Ketones from 1,3-Dithiane: Cyclobutanone (51, 76) Cyclobutanone from Methylenecyclopropane via Oxaspiropentane (57, 36) Cyclobutanone Via Solvolytic Cyclization (54, 84) One-carbon Ring Expansion of Cycloalkanones to Conjugated Cycloalkenones: 2-Cyclohepten-1-one (59, 113) Nitriles from Ketones: Cyclohexanecarbonitrile (58, 101) Aldehydes from Olefins: Cyclohexanecarboxaldehyde (57, 11) Catalytic Osmium Tetroxide Oxidation of Olefins: cis-1,2-Cyclohexanediol (58, 43) Stereoselective Hydroxylation with Thallium(i) Acetate and Iodine: trans- and cis-1,2-Cyclohexanediols (59, 169) Cleavage of Methyl Ethers with Iodotrimethylsilane: Cyclohexanol from Cyclohexyl Methyl Ether (59, 35) Preparation of , -Unsaturated Aldehydes via the Wittig Reaction: Cyclohexylideneacetaldehyde (53, 104) Cyclopropenone (57, 41) Cyclopropyldiphenylsulfonium Tetrafluoroborate (54, 27) Ring Contraction via a Favorskii-Type Rearrangement: Cycloundecanone (56, 107) Hydrogenation of Aromatic Nuclei: 1-Decalol (51, 103) Oxidation with the Chromium Trioxide-Pyridine Complex Prepared in situ: 1-Decanal (55, 84) Reduction of Alkyl Halides and Tosylates with Sodium Cyanoborohydride in Hexamethylphosphoric Triamide (HMPA): A. 1-Iododecane to n-Decane B. 1-Dodecyl Tosylate to n-Dodecane (53, 107) Diamantane: Pentacyclo[7.3.1.14,12.02,7.06,11]tetradecane (53, 30) Macrocyclic Diimines: 1,10-dlazacycloeCtadecane (54, 88) Dlazoacetophenone (53, 35) 2-diazocycloalkanones: 2-diazocyclohexanone (51, 86) 2-diazopropane (50, 27) Macrocyclic Polyethers: Dibenzo-18-crown-6 Polyether and Dicyclohexyl-18-crown-6 Polyether (52, 66) 1,2-Diaroylcyclopropanes: trans-1,2-Dibenzoylcyclopropane (52, 33) ,???-Dibromodibenzyl Sulfone (50, 31) Phosphine-Nickel Complex Catalyzed Cross-Coupling of Grignard Reagents with Aryl and Alkenyl Halides: 1,2-Dibutylbenzene (58, 127) Oxidation with Bis(Salicylidene)ethylenediiminocobalt(II) (Salcomine)
• 2,6-Di-tert-butyl-p-benzoquinone (57, 78) Diazo Transfer by Means of Phase-transfer Catalysis: Di-tert-Butyl Diazomalonate (59, 66) Di-tert-butyl Dicarbonate (57, 45) cis-3,4-Dichlorocyclobutene (50, 36) cis-Dichloroalkanes from Epoxides: cis-1,2-Dichlorocyclohexane (58, 64) 2,3-Dicyanobutadiene as a Reactive Intermediate by in situ Generation from 1,2-Dicyanocyclobutene: 2,3-Dicyano-1,4,4a,9a-tetrahydrofluorene (58, 67) Dideuteriodiazomethane (53, 38) Diethylaluminum cyanide (52, 90) Diethylaminosulfur trifluoride (57, 50) Diethyl tert-Butylmalonate (50, 38) 2-Trimethylsilyloxy-1,3-butadiene as a Reactive Diene: Diethyl trans-4-Trimethylsilyloxy-4-cyclohexene-1,2-dicarboxylate (58, 163) Diethyl 2-(Cyclohexylamino)vinylphosphonate (53, 44) Radical Anion Arylation: Diethyl Phenylphosphonate (58, 134) Diethyl trans- 4-Tetrahydrophthalate (50, 43) Homogeneous Catalytic Hydrogenation: Dihydrocarvone (53, 63) trans-1,2-Dihydrophthalic Acid (50, 50) 5,6-Dihydro-2H-pyran-2-one and 2H-Pyran-2-One (56, 49) 2,4-Dimethoxybenzonitrile (50, 52) Biaryls from Simple Arenes via Organotellurium Intermediates
• 4,4'-Dimethoxy-1,1'-Biphenyl (57, 18) 6,7-Dimethoxy-3-Isochromanone (55, 45) Regioselective Mannich Condensation with Dimethyl(methylene)ammonium Trifluoroacetate: 1-Dimethylamino-4-methyl-3-pentanone (59, 153) Directed Lithiation of Aromatic Compounds: (2-Dimethylamino-5-methylphenyl)diphenylcarbinol (53, 56) Use of Dipotassium Nitrosodisulfonate (fremy's Salt): 4,5-Dimethyl-o-Benzoquinone (52, 88) 1,2-Dimethylcyclobutenes by Reductive Ring-Contraction of Sulfolanes: cis-7,8-Dimethylbicyclo[4.2.0]oct-7-Ene (57, 53) 4,4'-Dimethyl-1,1'-biphenyl (55, 48) N,N-Dimethyl-5 -cholest-3-Ene-5-acetamide (54, 77) Conversion of Esters to Amides with Dimethylaluminum Amides: N,N-Dimethylcyclohexanecarboxamide (59, 49) 4,4-Dimethyl-2-Cyclohexen-1-one (53, 48) Reductive Amination with Sodium Cyanoborohydride: N,N- Dimethylcyclohexylamine (52, 124) N,N-Dimethyldodecylamine Oxide (50, 56) Dimethyl Nitrosuccinate (57, 60) Dimethyl 2,3-Pentadienedioate (57, 62) Allylically Transposed Amines from Allylic Alcohols
• 3,7-Dimethyl-1,6-octadien-3-amine (58, 4) Bicyclic Ketones for The Synthesis of Tropinoids: 2 ,4 -Dimethyl-8-oxabicyclo[3.2.1]oct-6-en-3-one (58, 17) 2,2-Dimethyl-4-Phenylbutyric Acid (50, 58) Cyclopentenones from , '-Dibromoketones and Enamines: 2,5-Dimethyl-3-phenyl-2-cyclopenten-1-one (58, 56) Alkylations of Aldehydes via Reaction of the Magnesioenamine Salt of an Aldehyde: 2,2-Dimethyl-3-phenylpropionaldehyde (54, 46) 3,5-Dinitrobenzaldehyde (53, 52) 2,3-Diphenyl-1,3-butadiene (50, 62) Reagents for Synthesis of Organoselenium Compounds: Diphenyl Diselenide and Benzeneselenenyl Chloride (59, 141) Aromatic Hydrocarbons from Aromatic Ketones and Aldehydes: 1,1-Diphenylethane (55, 7) Nucleophilic -sec-Aminoalkylation: 2-(Diphenylhydroxymethyl)pyrrolidine (58, 113) Diphenylketene (52, 36) Alkenes via Hofmann Elimination: Use of Ion-Exchange Resin for Preparation of Quaternary Ammonium Hydroxides: Diphenylmethyl Vinyl Ether (55, 3) 2,3-Diphenylvinylene Sulfone (50, 65) 1,3-Dithiane (50, 72) 2,2'-Dithienyl Sulfide (50, 75) Selective Epoxidation of Terminal Double Bonds: 10, 11-Epoxyfarnesyl Acetate (56, 112) 1-Ethoxy-1-butyne (57, 65) Demethylation of Methyl Aryl Ethers: 4-Ethoxy-3-hydroxybenzaldehyde (56, 44) Carbine Generation by -Elimination with Lithium 2,2,6,6-Tetramethylpiperidide: 1-Ethoxy-2-p-tolylcyclopropane (58, 37) Esterification of Carboxylic Acids with Trialkyloxonium Salts
• Ethyl and Methyl 4-Acetoxybenzoates (56, 59) ortho-Alkylation of Anilines: Ethyl 4-Amino-3-Methylbenzoate (56, 15) Ethyl 5 -Cholest-3-ene-5-acetate (54, 74) Free-Radical Cyclization: Ethyl 1-Cyano-2-Methylcyclohexanecarboxylate (55, 57) 2,2-(Ethylenedithio)cyclohexanone (54, 37) A General Synthesis of 4-Isoxazolecarboxylic Esters: Ethyl 3-Ethyl-5-methyl-4-isoxazolecarboxylate (53, 59) 3-Alkyl-1-alkynes Synthesis: 3-Ethyl-1-hexyne (58, 1) -Hydroxy Esters from Ethyl Acetate and Aldehydes or Ketones: Ethyl 1-Hydroxycyclohexylacetate (53, 66) Indoles from Anilines: Ethyl 2-Methylindole-5-carboxylate (56, 72) Stereoselective Synthesis of Trisubstituted Olefins: Ethyl 4-Methyl-(E)-4,8-nonadienoate (53, 116) Metalation of 2-Methylpyridine Derivatives: Ethyl 6-Methylpyridine-2-acetate (52, 75) Ethyl 1-Naphthylacetate (50, 77) Ethyl (E)-3-Nitroacrylate [Replaced by Methyl (E)-3-Nitroacrylate] (56, 65
• replaced) -Ketoesters from Aldehydes via Diethyl Acylsuccinates: Ethyl 4-oxohexanoate (58, 79) Ethyl Pyrrole-2-Carboxylate (51, 100) Thiazoles from Ethyl Isocyanoacetate and Thiono Esters: Ethyl Thiazole-4-carboxylate (59, 183) Carboxylation of Aromatic Compounds: Ferrocenecarboxylic Acid (56, 28) Fluorinations with Pyridinium Polyhydrogen Fluoride Reagent: 1-Fluoroadamantane (58, 75) Aldehydes from Aromatic Nitriles: 4-Formylbenzenesulfonamide (51, 20) Geranyl Chloride (54, 63) Allylic Chlorides from Allylic Alcohols: Geranyl Chloride (54, 68) Glutaconaldehyde Sodium Salt From Hydrolysis of Pyridinium-1-sulfonate (59, 79) Aldehydes from Primary Alcohols by Oxidation with Chromium Trioxide: Heptanal (52, 5) Conversion of Nitro to Carbonyl by Ozonolysis of Nitronates: 2,5-Heptanedione (56, 36) Macrocyclic Polyamines: 1,4,7,10,13,16-Hexaazacyclooectadecane (58, 86) Cuprous Ion-Catalyzed Oxidative Cleavage of Aromatic o-Diamines by Oxygen:(Z,Z)-2,4-Hexadienedinitrile (57, 33) Hexafluoroacetone Imine (50, 81) 3-Trimethylsilyl-3-buten-2-one as Michael Acceptor for Conjugate Addition-Annelation: cis-4,4a,5,6,7,8-Hexahydro-4a,5-dimethyl-2(3H)-naphthalenone (58, 158) Nitrones for Intramolecular 1,3-Dipolar Cycloadditions: Hexahydro-1,3,3,6-tetramethyl-2,1-benzisoxazoline (58, 106) (E)-4-Hexen-1-ol (55, 62) Fragmentation of , -Epoxyketones to Acetylenic Aldehydes and Ketones: Preparation of 2,3-Epoxycyclohexanone and its Fragmentation to 5-Hexynal (55, 52) -Hydroxy- , -Unsaturated Aldehydes via 1,3-Bis(methylthio)allyllithium: trans-4-Hydroxy-2-hexenal (54, 19) 17 -Hydroxy-5-oxo-3,5-seco-4-norandrostane-3-carboxylic Acid (55, 67) Directed Aldol Condensations: threo-4-Hydroxy-3-phenyl-2-heptanone (54, 49) Macrolides from Cyclization of -Bromocarboxylic Acids: 11-Hydroxyundecanoic Lactone (58, 98) Direct Iodination of Polyalkylbenzenes: Iododurene (51, 94) trans-Iodopropenylation of Alkyl Halides: (E)-1-Iodo-4-phenyl-2-butene (56, 77) 2-Iodo-p-xylene (55, 70) cis- , -Unsaturated Acids: Isocrotonic Acid (53, 123) Trichloromethyl Chloroformate as a Phosgene Equivalent: 3-Isocyanatopropanoyl Chloride (59, 195) Hydroboration of Olefins: (+)-Isopinocampheol [Replaced by ( )-Isopinocampheol] (52, 59) ( )-Isopinocampheol (New) Reaction of Aryl Halides with -Allylnickel Halides: Methallylbenzene (52, 115) Sulfonyl Cyanides: Methanesulfonyl Cyanide (57, 88) 1,6-Methano[10]annulene (54, 11) Vinyl Sulfides from Thioacetals with Copper(I) Trifluoromethanesulfonate: (Z)-2-Methoxy-1-phenylthio-1,3-butadiene (59, 202) 6-Methoxy- -tetralone (51, 109) Methyl Groups by Reduction of Aromatic Carboxylic Acids with Trichlorosilane-tri-n-propylamine: 2-Methylbiphenyl (56, 83) 1-d-Aldehydes from Organometallic Reagents: 2-Methylbutanal-1-d (51, 31) Preparation of Vinyl Trifluoromethanesulfonates: 3-methyl-2-buten-2-yl Triflate (54, 79) Preparation and Reductive Cleavage of Enol Phosphates: 5-Methylcoprost-3-Ene (52, 109) Oxymercuration-Reduction: Alcohols from Olefins: 1-Methylcyclohexanol (53, 94) Reductive Cleavage of Allylic Alcohols, Ethers, or Acetates to Olefins: 3-Methylcyclohexene (56, 101) -Ketoesters to Prepare Cyclic Diketones: 2-Methyl-1,3-cyclopentanedione (58, 83) Sulfide Contraction via Alkylative Coupling: 3-Methyl-2,4-Heptanedione (55, 127) Isoxazole Annelation Reaction: 1-Methyl-4,4a,5,6,7,8-Hexahydronaphthalen-2(3H)-one (53, 70) Addition of Organolithium Reagents to Allyl Alcohol: 2-Methyl-1-Hexanol (55, 1) Conversion of Primary Alcohols to Urethanes via the Inner Salt of Methyl (carboxysulfamoyl)Triethylammonium Hydroxide: Methyl n-Hexylcarbamate (56, 40) Methyl 2-Alkynoates from 3-Alkyl-2-pyrazolin-5-ones: Methyl 2-Hexynoate (55, 73) Methyl (trans-2-Iodo-1-Tetralin)carbamate (51, 112) Methyl Nitroacetate (55, 77) Methyl (E)-3-Nitroacrylate (New) 2-Methyl-2-nitrosopropane and Its Dimer (52, 77) Nucleophilic Acylation with Disodium Tetracarbonylferrate: Methyl 7-Oxoheptanoate and Methyl 7-Oxooectanoate (59, 102) Aldehydes from Allylic Alcohols and Phenylpalladium Acetate: 2-Methyl-3-phenylpropionalde (51, 17) Endocyclic Enamine Synthesis: N-Methyl-2-phenyl- 2-tetrahydropyridine (54, 93) Hydrogenolysis of Carbon-Halogen Bonds with Chromium(II)-en Perchlorate: Naphthalene from 1-Bromonaphthalene (52, 62) Thiophenols from Phenols: 2-Naphthalenethiol (51, 139) S(-)- -(1-Naphthyl)ethylamine (55, 80) Alkyl Iodides: Neopentyl Iodide and Iodocyclohexane (51, 44) Sulfide Synthesis in Preparation of Dialkyl and Alkyl Aryl Sulfides: Neopentyl Phenyl Sulfide (58, 143) 4-Nitrobenzyl Fluoride (57, 72) 1-Nitrocyclooectene (50, 84) Formation and Photochemical Wolff Rearrangement of Cyclic -Diazo Ketones: D-Norandrost-5-en-3 -ol-16-carboxylic Acids (52, 53) Highly Reactive Magnesium for the Preparation of Griignard Reagents: 1-Norbornanecarboxylic Acid (59, 85) 9,10-Octalin (50, 88) 2,2,7,7,12,12,17,17-Octamethyl-21,22,23,24-tetraoxaperhydroquaterene (57, 74) Orcinol Monomethyl Ether (53, 90) 1,6-Oxido[10]annulene (55, 86) Cyanide-Catalyzed Conjugate Addition of Aryl Aldehydes: 4-Oxo-4-(3-pyridyl)butyronitrile (59, 53) Aldehydes from sym-Trithlane: n-Pentadecanal (51, 39) (Pentafluorophenyl)acetonitrile (57, 80) Pentafluorophenylcopper Tetramer, a Reagent for Synthesis of Fluorinated Aromatic Compounds (59, 122) trans-3-Penten-2-one (51, 115) Arene Oxide Synthesis: Phenanthrene-9,10-oxide (58, 12) Free-Radical Alkylation of Quinones: 2-Phenoxymethyl-1,4-Benzoquinone (56, 68) 3-Phenyl-2H-azirine-2-carboxaldehyde (57, 83) Phase-Transfer Alkylation of Nitriles: 2-Phenylbutyronitrile (55, 91) Directed Aldol Condensations: - Phenylcinnamaldehyde (50, 66) Aldehydes from 2-Benzyl-4,4,6-Trimethyl-5,6-dihydro-1,3(4H)-oxazine: 1-Phenylcyclopentanecarboxaldehyde (51, 24) Amines from Mixed Carboxylic-Carbonic Anhydrides: 1-Phenylcyclopentylamine (51, 48) cis-2-Phenylcyclofropanecarboxylic Acid (50, 94) Substitution of Aryl Halides with Copper(i) Acetylides: 2-Phenylfuro[3,2-b]pyridine (52, 128) Ketones and Alcohols from Organoboranes: Phenyl Heptyl Ketone, 1-Hexanol, and 1-Octanol (53, 77) 1-Phenyl-1,4-pentadiyne and 1-Phenyl-1,3-pentadiyne (50, 97) Phenylation with Diphenyliodonium Chloride
• 1-Phenyl-2,4-pentanedione (51, 128) 1-Phenyl-4-phosphorinanone (53, 98) 4-Phenyl-1,2,4-triazoline-3,5-dione (51, 121) 2-Phenyl-2-vinylbutyronitrile (55, 99) Boranes in Functionalization of Olefins to Amines: 3-Pinanamine (58, 32) Allylic Oxidation with Hydrogen Peroxide-Selenium Dioxide: trans-Pinocarveol (56, 25) Base-Induced Rearrangement of Epoxides to Allylic Alcohols: trans-Pinocarveol (53, 17) Polymeric Carbodiimide. Preparation (56, 95) Alkynes via Phase Transfer Catalyzed Dehydrohalogenation: Propiolaldehyde Diethyl Acetal (59, 10) Rearrangement of Bridgehead Alcohols to Polycyclic Ketones by Fragmentation-Cyclization: 4-Protoadamantanone (Tricyclo[4.3.1.03.8]Decan-4-One) (59, 147) Quadricyclane (51, 133) 1,2,3,4-Tetrahydro- -Carboline (51, 136) Aziridines from -Iodocarbamates: 1,2,3,4-Tetrahydronaphthalene(1,2)Imine (51, 53) 2,3,4,5-Tetrahydropyridine Trimer (56, 118) 3,3,6,6-Tetramethoxy-1,4-Cyclohexadiene (57, 92) 2,2,3,3-Tetramethyliodocyclopropane (52, 132) 4H-1,4-Thiazine l,1-Dioxide (52, 135) 2-Thiophenethiol (50, 104) p-Tolylsulfonyldiazomethane (57, 95) p-Tolylsulfonylmethyl Isocyanide (57, 102) Tri-tert-Butylcyclopropenyl Tetrafluoroborate (54, 97) Tricarbonyl[2,3,4,5- )-2,4,-Cyclohexadien-1-One]Iron and Tricarbonyl[(1,2,3,4,5- )-2-Methyoxy-2,4-Cyclohexadien-1-Yl]Iron(1+) Hexafluorophosphate(1 ) from Anisole (57, 107) Alkylation of Dimedone with a Tricarbonyl(diene)Iron Complex: Tricarbonyl[2-[2,3,4,5- )-4-Methoxy-2,4-Cyclohexadien-1-yl]-5,5-Dimethyl-1,3-Cyclohexanedione]iron (57, 16) Cyclobutadiene in Synthesis: endo-Tricyclo[4.4.0.02,5]Deca-3,8-Diene-7,10-Dione (55, 43) Trifluoroacetylation of Amines and Amino Acids Under Neutral, Mild Conditions: N-Trifluoroacetanilide and N-Trifluoroacetyl-L-Tyrosine (56, 122) Aldehydes from Acid Chlorides by Modified Rosenmund Reduction: 3,4,5-Trimethoxybenzaldehyde (51, 8) Oxidation with the Nitrosodisulfonate Radical. I. Preparation and Use of Disodium Nitrosodisulfonate: Trimethyl-p-Benzoquinone (52, 83) 2,2-(Trimethylenedithio)Cyclohexanone (54, 39) Trimethylene Dithiotosylate and Ethylene Dithiotosylate (54, 33) Trimethyloxonium Tetrafluoroborate (51, 142) 3,5,5-Trimethyl-2-(2-Oxopropyl)-2-Cyclohexen-1-One (57, 113) Aldehydes by Oxidation of Terminal Olefins with Chromyl Chloride: 2,4,4-Trimethylpentanal (51, 4) Trimethylsilyl Azide (50, 107) 3-Trimethylsilyl-3-Buten-2-One: a Michael Acceptor (58, 152) Tropolone (57, 117) Preparation of Alkenes by Reaction of Lithium Dipropenylcuprates with Alkyl Halides: (E)-2-Undecene (55, 103
• deleted) General Index Frmula Index Hazard Index Author Index Concordance Index

巻冊次

collective v. 12 ISBN 9781118117828

内容説明

Continuing the tradition of providing significant and interesting procedures, Organic Syntheses, Collective Volume XII is a compilation of revised editions of Annual Volumes 85 through 89. The contents of this volume are organized by primarily by reaction type, with the precise classification made according to the bias of the editor, who attempted to ascertain the primary purpose or utility of the procedure.

目次

Preparation of (E)-(2-Iodovinyl)Benzene from Benzyl Bromide and Diiodomethane [(E)- -Styryl Iodide] 1 Vinylation with Inexpensive Silicon-Based Reagents: Preparation of 3-Vinylquinoline and 4-Vinylbenzophenone 7 Organolithiums and Lithium 2,2,6,6-Tetramethylpiperidide in Reductive Alkylation of Epoxides: Synthesis of (E)-Alkenes [(E)-2-Methyltetradeca-1,3-Diene] 19 2-Methylenecyclopropanecarboxylic Acid Ethyl Ester 27 2-(2,2-Dibromoethenyl)-benzenamine 33 Stereoselective Nickel-Catalyzed 1,4-Hydroboration of 1,3-Dienes [(Z)-Dec-2-en-1-ol] 42 Synthesis of Ethyl 2-Ethanoyl-2-methyl-3-phenylbut-3-enoate 51 (+/-) trans-3,3'-(1,2-Cyclopropanediyl)bis-2-(E)-Propenoic Acid, Diethyl Ester: Tandem Oxidation Procedure (Top) Using Mno2 Oxidation-Stabilized Phosphorane Trapping 57 Stereoselective Synthesis of 3-Arylacrylates by Copper-Catalyzed Syn Hydroarylation [(E)-Methyl 3-phenyloct-2-enoate] 67 Tandem Nucleophilic Addition/Fragmentation of Vinylogous Acyl Triflates: 2-Methyl-2-(1-oxo-5-heptynyl)-1,3-dithiane 72 Synthesis of Ynamides by Copper-Mediated Coupling of 1,1-Dibromo-1-Alkenes with Nitrogen Nucleophiles. Preparation of 4-Methyl-N-(2-Phenylethynyl)-N-(Phenylmethyl)Benzenesulfonamide 81 Synthesis of Polyynes by In Situ Desilylative Bromination and Palladium-Catalyzed Coupling: (7-(Benzyloxy)hepta-1,3,5-triynyl)triisopropylsilane 93 Preparation of a 1-Alkoxy-1-Alkyne from Reaction of a 2,2,2-Trifluoroethyl Ether with an Alkyllithium Reagent: 1-Benzyloxymethoxy-1-Hexyne 103 An Economical Synthesis of 4-Trimethylsilyl-2-butyn-1-ol 110 Single-Step Synthesis of Alkynyl Imines from N-Vinyl and N-Aryl AmidesSynthesis of N-[1-Phenyl-3-(Trimethylsilyl)-2-Propynylidene]-Benzenamine 121 Lithiated Primary Alkyl Carbamates for the Homologation of Boronic Esters 127 Synthesis of (R)-2-Methoxy-N-(1-Phenylethyl)Acetamide via Dynamic Kinetic Resolution 138 Synthesis and Resolution of Racemic trans-2-(N-Benzyl)amino-1-cyclohexanol: Enantiomer Separation by Sequential Use of (R)- and (S)-Mandelic Acid [Cyclohexanol, 2-(N-benzyl)amino, (1S,2S)- and (1R,2R)-] 147 (Sa,S)-N-[2'-(4-Methylphenylsulfonamido)-1,1a-Binaphthyl-2-yl]pyrrolidine-2-carboxamide: An Organocatalyst for the Direct Aldol Reaction 157 Synthesis of (S)-8a-Methyl-3,4,8,8a-Tetrahydro-1,6-(2H,7H)-Naphthalenedione via N-Tosyl-(Sa)-BINAM-L-Prolinamide Organocatalysis 168 (S)-(-)-2-Allylcyclohexanone (2-Allylcyclohexan-1-one) 177 Synthesis and Diastereoselective Aldol Reactions of a Thiazolidinethione Chiral Auxiliary 187 Lithium Amides as Homochiral AmmoniaEquivalents for Conjugate Additions to , -Unsaturated Esters: Asymmetric Synthesis of (S)- -Leucine 198 Fluoride Ring-Opening Kinetic Resolution of Terminal Epoxides: Preparation of (S)-2-Fluoro-1-Phenylethanol 214 (R)-3,3'-Bis(9-Phenanthryl)-1,1'-Binaphthalene-2,2'-Diyl Hydrogen Phosphate 222 Enantioselective Three-Component Reaction for the Preparation of -Amino- -Hydroxy Esters 232 Preparation of H,4 PyrrolidineQuin-BAM(PBAM) 241 Synthesis of tert-Butyl (1S,2S)-2-Methyl-3-Oxo-1-Phenyl propylcarbamate by AsymmetricMannich Reaction 253 Preparation of (Ra)-Methyl 3-(Dimethyl(phenyl)silyl)hexa-3,4-dienoate 258 Preparation of (S)-3,3'-Bis-Morpholinomethyl-5,5',6,6',7,7',8,8'-Octahydro-1,1'-Bi-2-Naphthol 268 Catalytic Asymmetric Addition of an In-Situ Prepared Arylzinc to Cyclohexanecarboxaldehyde: (R)-(+)- -Cyclohexyl-3-Methoxy-Benzenemethanol 276 Preparation of (S)-4-Isopropyl-N-Propanoyl-1,3-Thiazolidine-2-Thione 283 Stereoselective Synthesis of Anti -Methyl- -Methoxy Carboxylic Compounds 292 Organocatalytic Enantioselective Synthesis of Bicyclic -Lactones from Aldehyde Acids via Nucleophile-Catalyzed Aldol-Lactonization (NCAL) 301 Synthesis of (+)-B-Allyldiisopinocampheylborane and Its Reaction with Aldehydes 316 Synthesis of (S,S)-Diisopropyl Tartrate (E)-Crotylboronate and Its Reaction with Aldehydes: (2R,3R,4R)-1,2-Dideoxy-2-Ethenyl-4,5-O-(1-Methylethylidene)-Xylitol 330 Benzyl Isopropoxymethyl Carbamate - An Aminomethylating Reagent for Mannich Reactions of Titanium Enolates 344 (R)-2-(Benzyloxycarbonylamino-Methyl)-3-Phenylpropanoic Acid (Z- 2hPhe-OH): Preparation of a 2-Amino Acid with the Auxiliary Dioz 350 Catalytic Enantioselective Addition of Terminal Alkynes to Aldehydes: Preparation of (S)-(-)-1,3-Diphenyl-2-propyn-1-ol and (S)-(-)-4-Methyl-1-phenyl-2-pentyn-1,4-diol 358 Preparation of (S)-tert-ButylPHOX (Oxazole, 4-(1,1-dimethylethyl) -2-[2-(diphenylphosphino)phenyl]-4,5-dihydro- (4S)-) 368 Preparation of (S)-2-Allyl-2-Methylcyclohexanone (Cyclohexanone, 2-methyl-2-(2-propen-1-yl)-, (2S)-) 379 High-Yielding, Large-Scale Synthesis of N-Protected- -Aminonitriles: tert-Butyl (1R)-2-Cyano-1-Phenylethylcarbamate 395 (3R,7aS)-3-(Trichloromethyl)Tetrahydropyrrolo[1,2-C]Oxazol-1(3H)-one: An Air and Moisture Stable Reagent for the Synthesis of Optically Active -Branched Prolines 405 Preparation of Enantioenriched Homoallylic Primary Amines 415 Synthesis of (2R,3R)-2,3-Dimethyl-1,4-Butanediol by Oxidative Homocoupling of (4S)-Isopropyl-3-Propionyl-2-Oxazolidinone[2,3-imethylbutane-1,4-diol, (2R, 3R)-] 423 OxoneR-Mediated Synthesis of Benzimidazoles from 1,2-Phenylenediamines and Aldehydes: Preparation of 2-(4-Cyano-Phenyl)-1-[2-(3,4-imethoxyphenyl)-Ethyl]-1H-Benzimidazole-5-Carboxylic Acid Ethyl Ester 435 Synthesis of a N-Mesityl-Substituted Aminoindanol-Derived Triazolium Salt [(5aS,10bR)-5a,10b-Dihydro-2-(2,4,6-trimethylphenyl)-4H,6H-indeno[2,1-b]-1,2, 4-triazolo[4,3-d]-1,4-oxazinium chloride] 446 t-Butyl as a Pyrazole Protecting Group: Preparation and Use of 1-tert-Butyl-3-Methyl-1H-Pyrazole-5-Amine 459 Microwave-Assisted Synthesis of 1,3-Dimesitylimidazolinium Chloride 470 Regioselective Synthesis of 1,3,5-Trisubstituted Pyrazoles by the Reaction of N-Monosubstituted Hydrazones with Nitroolefins 479 Synthesis of 4,5-Dimethyl-1,3-dithiol-2-one 487 Cu-Catalyzed Azide-Alkyne Cycloaddition: Preparation of Tris((1-Benzyl-1H-1,2,3-Triazolyl)Methyl)Amine 497 An Intramolecular Amination of Aryl Halides with a Combination of Copper (I) Iodide and Cesium Acetate: Preparation of 5,6-Dimethoxyindole-1,2-Dicarboxylic Acid 1-Benzyl Ester 2-Methyl Ester 504 Preparation of a Non-Symmetrical Imidazolium Salt: 1-Adamantyl-3-Mesityl-4,5-Dimethylimidazolium Tetrafluoroborate 512 Efficient Oxidative Synthesis of (-)-2-tert-Butyl-(4S)-Benzyl-(1,3)-Oxazoline 520 Synthesis of Enantiopure Di(tert-Butyl) (2S,4S)-4-Hydroxy-6-Oxo-1,2-Piperidinedicarboxylate. A Useful Building Block for the Preparation of 4-Hydroxypipecolate Derivatives 529 Convenient Preparation of 3-Ethoxycarbonyl Benzofurans from Salicylaldehydes and Ethyl Diazoacetate 537 One-Pot Multicomponent Preparation of Tetrahydropyrazoloquinolinones and Tetrahydropyrazoloquinazolinones 545 Synthesis of 2-Arylindole-4-Carboxylic Amides: [2-(4-Fluorophenyl)-1H-Indol-4-yl]-1-Pyrrolidinylmethanone 554 One-Pot Synthesis of 5H-Indazolo-[3,2-b]Benzo[d]-1,3-Oxazine: Two Efficient Preparative Methods 566 Phosphine-Catalyzed [4+2] Annulation: Synthesis of Ethyl 6-Phenyl-1-Tosyl-1,2,5,6-Tetrahydropyridine-3-Carboxylate 575 Phosphine-Catalyzed [3 + 2] Annulation: Synthesis of Ethyl 5-(tert-Butyl)-2-Phenyl-1-Tosyl-3-Pyrroline-3-Carboxylate 586 Synthesis of Substituted Indazoles via [3+2] Cycloaddition of Benzyne and Diazo Compounds [1H-indazole-3-carboxylic acid, ethyl ester] 598 Synthesis of 2,3-Disubstituted Indoles via Palladium-Catalyzed Annulation of Internal Alkynes: 3-Methyl-2-(Trimethylsilyl)Indole 606 Synthesis of Quinolines by Electrophilic Cyclization of N-(2-Alkynyl)Anilines: 3-Iodo-4-Phenylquinoline 615 Preparation of 4-Spirocyclohexyloxazolidinone by C-H Bond Nitrene Insertion [3-Oxa-1-azaspiro[4.5]decan-2-one] 626 (S)-5-Pyrrolidin-2-yl-1H-tetrazole 635 Regioselective C-4 Bromination of Oxazoles: 4-Bromo-5-(thiophen-2-yl)oxazole 648 The Preparation of (2R,5S)-2-t-Butyl-3,5-dimethylimidazolidin-4-one 656 Facile Synthesis of 2-Ethyl-3-quinolinecarboxylic Acid Hydrochloride 667 Selective Trialkylation of Cyclen with tert-Butyl Bromoacetate [1,4,7,10-Tetraazacyclododecane-1,4,7-triacetic acid, Tri-tert-butyl Ester Hydrobromide] 673 Direct Synthesis of Azaheterocycles from N-Aryl/Vinyl Amides. Synthesis of 4-(Methylthio)-2-phenylquinazoline and 4-(4-Methoxyphenyl)-2-phenylquinoline 677 Direct Synthesis of 2,5-Dihalosiloles (2,5-Dibromo-1,1-dimethyl-3,4-diphenyl-1H-silole) 688 Ligand-Free Copper(II) Oxide Nanoparticles Catalyzed Synthesis of Substituted Benzoxazoles 697 Preparation of Chiral and Achiral Triazolium Salts: Carbene Precursors with Demonstrated Synthetic Utility 703 Enantioselective Preparation of Dihydropyrimidones [(S)-1-Benzyl-6-methyl-2-oxo-4-phenyl-1, 2, 3, 4-tetrahydropyrimidine-5-carboxylic methyl ester] 712 o-Aminobenzaldehyde, Redox-Neutral Aminal Formation and Synthesis of Deoxyvasicinone 726 Pd(0)-Catalyzed Diamination of trans-1-Phenyl-1,3-butadiene with Di-tert-Butyldiaziridinone as Nitrogen Source 733 Pd(0)-Catalyzed Asymmetric Allylic and Homoallylic Diamination of 4-Phenyl-1-butene With Di-tert-Butyldiaziridinone 741 The Preparation of Indazoles via Metal Free Intramolecular Electrophilic Amination of 2-Aminophenyl Ketoximes 750 Synthesis of Pyrazolo[1,5-a]Pyridines via Azirines: Preparation of 2-(3-Bromophenyl)-6-(Trifluoromethyl) Pyrazolo[1,5-a]Pyridine 757 Preparation of 3-Alkylated Oxindoles from N-Benzyl Aniline via a Cu(II)-Mediated Anilide Cyclization Process 766 Gram Scale Catalytic Asymmetric Aziridination: Preparation of (2R,3R)-Ethyl 1-Benzhydryl-3-(4-bromophenyl)aziridine 2-carboxylate 777 Preparation of Tetrahydroisoquinoline-3-ones Via Cyclization of Phenyl Acetamides Using Eaton's Reagent 789 One-Pot Conversion of Lactam Carbamates to Cyclic Enecarbamates: Preparation of 1-tert-Butoxycarbonyl-2,3-Dihydropyrrole 797 Cyclohexene Imine (7-Aza-bicyclo[4.1.0]heptane) 803 Direct Fluorination of the Carbonyl Group of Benzophenones Using Deoxo-FluorR: Preparation of Bis(4-Fluorophenyl)difluoromethane 810 Preparation of t-Butyl-3-Bromo-5-Formylbenzoate Through SelectiveMetal-Halogen Exchange Reactions 817 Amide Formation by Decarboxylative Condensation of Hydroxylamines and -Ketoacids: N-[(1S)-1-Phenylethyl]benzeneacetamide 826 New, Convenient Route for Trifluoromethylation of Steroidal Molecules 832 Low Pressure Carbonylation of Epoxides to -Lactones 841 Preparation of Cyclobutenone 849 Safe and Scalable Preparation of Barluenga's Reagent (Bis(pyridine)iodonium(I) tetrafluoroborate) 858 Catalytic Intramolecular Friedel-Crafts Reaction of Benzyl Meldrum's Acid Derivatives: Preparation of 5,6-Dimethoxy-2-methyl-1-indanone 867 Convenient Synthesis of -Diazoacetates from -Bromoacetates and N,N'-Ditosylhydrazine: Preparation of Benzyl Diazoacetate 876 Efficient Synthesis of Oxime Using O-TBS-N-Tosylhydroxylamine: Preparation of (2Z)-4-(Benzyloxy)but-2-enal Oxime 883 Protection of Diols with 4-(tert-Butyldimethylsilyloxy)- benzylidene Acetal and its Deprotection: (4-((4R,5R)-4,5-Diphenyl-1,3-dioxolan-2-yl)phenoxy) (tert-butyl)dimethylsilane 892 Tetrakis(dimethylamino)allene 901 A Practical Synthesis of Isocyanates from Isonitriles: Ethyl 2-Isocyanatoacetate 909 Silver-Catalyzed Rearrangement of Propargylic Sulfinates: Synthesis of Allenic Sulfones 913 Preparation of 1-Monoacylglycerols via the Suzuki-Miyaura Reaction: 2,3-Dihydroxypropyl (Z)-tetradec-7-enoate 919 Dibenzo[a,e]cyclooctene: Multi-gram Synthesis of a Bidentate Ligand 934 Preparation of Isopropyl 2-Diazoacetyl(Phenyl)Carbamate 943 Preparation of Ethyl 1-Benzyl-4-Fluoropiperidine-4-Carboxylate 953 Preparation and [2+2] Cycloaddition of 1-Triisopropylsiloxy-1-Hexyne with Methyl Crotonate: 3-Butyl-4-Methyl-2-Triisopropylsiloxy-Cyclobut-2-Enecarboxylic AcidMethyl Ester 957 1,3,5-Triacetylbenzene 965 An Efficient and Scalable Ritter Reaction for the Synthesis of t-Butyl Amides 972 Palladium-Catalyzed Dehydrative Allylation of Hypophosphorous Acid with Allylic AlcoholsPreparation of Cinnamyl-H-Phosphinic Acid 979 Synthesis of Tetraorganosilanes: (Chloromethyl)Dimethylphenylsilane 987 Organocatalytic -Methylenation of Aldehydes: Preparation of 3,7-Dimethyl-2-Methylene-6-Octenal 991 Preparation of Cycloheptane-1,3-Dione via Reductive Ring Expansion of 1-Trimethylsilyloxy-7,7-dichlorobicyclo[3.2.0]heptan-6-one (Cycloheptane-1,3-dione) 997 Synthesis of Trifluoromethyl Ketones from Carboxylic Acids: 4-(3,4-Dibromophenyl)-1,1,1-trifluoro-4-methylpentan-2-one 1004 Synthesis of 2-[3,3'-Di-(tert-Butoxycarbonyl)-aminodipropylamine]-4,6,-dichloro-1,3,5-triazine as a Monomer and 1,3,5-[Tris-Piperazine]-triazine as a Core for the Large Scale Synthesis of Melamine (Triazine) Dendrimers 1012 Large Scale, Green Synthesis of a Generation-1 Melamine (Triazine) Dendrimer 1020 Synthesis of Enamides from Ketones: Preparation of N-(3,4-Dihydronaphthalene-1-yl)acetamide 1028 The Direct Acyl-Alkylation of ArynesPreparation of Methyl 2-(2-Acetylphenyl)acetate 1040 Preparation of a Trifluoromethyl Transfer Agent: 1-Trifluoromethyl-1,3-Dihydro-3,3-Dimethyl-1,2-Benziodoxole 1049 Preparation of Horner-Wadsworth-Emmons Reagent: Methyl 2-Benzyloxycarbonylamino-2-(Dimethoxyphosphinyl) acetate 1059 Enals via a Simple Two-Carbon Homologation of Aldehydes and Ketones 1067 Gold(I)-Catalyzed Decarboxylative Allylic Amination of Allylic N-Tosylcarbamates 1075 Synthesis of Cyclobutarenes by Palladium-Catalyzed C(sp3)-H Bond Arylation: Preparation of Methyl 7-Methylbicyclo[4.2.0]Octa-1,3,5-Triene-7-Carboxylate 1083 B-Protected Haloboronic Acids for Iterative Cross-Coupling 1090 Synthesis of (3-Chlorobutyl)Benzene by the Cobalt-catalyzed Hydrochlorination of 4-Phenyl-1-butene 1104 Copper-Catalyzed Three-Component Reaction of 1-Alkynes, Sulfonyl Azides, And Water: N-(4-Acetamidophenylsulfonyl)-2-Phenylacetamide 1109 Synthesis of Dimethyl 2-Phenylcyclopropane-1, 1-Dicarboxylate Using an Iodonium Ylide Derived from Dimethyl Malonate 1115 Palladium (II) Acetate-Butyl Di-1-adamantylphosphine Catalyzed Arylation of Electron-Rich HeterocyclesPreparation of 5-Phenyl-2-isobutylthiazole 1124 General Method for Copper-Catalyzed Arylation of Acidic Arene C-H BondsPreparation of 2-Chloro-5-(3-Methylphenyl)-Thiophene 1131 Rhodium-Catalyzed Enantioselective Addition of Arylboronic Acids to In Situ Generated N-Boc AryliminesPreparation of (S)-tert-Butyl (4-Chlorophenyl)(thiophen-2-yl) methylcarbamate 1138 Synthesis of 2-Aryl Pyridines by Palladium-Catalyzed Direct Arylation of Pyridine N-Oxides 1150 Nickel-Catalyzed Enantioselective Negishi Cross-Couplings of Racemic Secondary -Bromo Amides with Alkylzinc Reagents: (S)-N-Benzyl-7-cyano-2-ethyl-N-phenylheptanamide 1159 Palladium-Catalyzed Alkyl-Alkyl Suzuki Cross-Couplings of Primary Alkyl Bromides at Room Temperature: (13-Chlorotridecyloxy)triethylsilane 1166 Synthesis of Chiral Pyridine Bis(Oxazoline) Ligands for Nickel-Catalyzed Asymmetric Negishi Cross-Couplings of Secondary Allylic Chlorides with Alkylzincs: 2,6-Bis[(4R)-4,5-Dihydro-4-(2-phenylethyl)-2-oxazolyl]-Pyridine 1175 Nickel-catalyzed Asymmetric Negishi Cross-Couplings of Racemic Secondary Allylic Chlorides With Alkylzincs: (S,E)-Ethyl 6-(1,3-Dioxolan-2-yl)-4-methylhex-2-enoate 1180 Synthesis of 2-Substituted Biaryls via Cu/Pd-Catalyzed Decarboxylative Cross-Coupling of 2-Substituted Potassium Benzoates: 4-Methyl-2'-Nitrobiphenyl and 2-Acetyl-4'-Methylbiphenyl 1191 -Arylation of Esters Catalyzed by the Pd(I) Dimer [P(t-Bu)3Pd( -Br)]2 1202 Ruthenium-Catalyzed Arylation of Ortho C-H Bond in an Aromatic with an Arylboronate: 8-Phenyl-1-Tetralone 1210 Magnesiation of Weakly Activated Arenes using tmp2Mg 2LiCl: Synthesis of tert-Butyl Ethyl Phthalate 1217 Synthesis of (2R)-3-[[(1,1-Dimethylethyl) dimethylsilyl]oxy]-2-methylpropanal by Rhodium-Catalyzed Asymmetric Hydroformylation 1226 Multicomponent Synthesis of Tertiary Diarylmethylamines: 1-((4-Fluorophenyl)(4-methoxyphenyl)methyl)piperidine 1236 Anhydrous Hydration of Nitriles to Amides: p-Carbomethoxybenzamide 1246 Synthesis of 8,8-Dipropylbicyclo[4.2.0]octa-1,3,5-trien-7-one via Pd-catalyzed Intramolecular C-H Bond-Acylation 1251 Synthesis of Lithium 2-Pyridyltriolborate and Its Cross-Coupling Reaction with Aryl Halides 1261 (R)-2,2'-Binaphthoyl-(S,S)-di(1-phenylethyl) Aminophosphine. Scalable Protocols for the Syntheses of Phosphoramidite (Feringa) Ligands 1267 (R)-3-Methyl-3-Phenyl-1-Pentene Via Catalytic Asymmetric Hydrovinylation 1275 Synthesis of Aminoarenethiolato-Copper(I) Complexes 1291 The Preparation of Cyclohept-4-enones by Rhodium-Catalyzed Intermolecular [5+2] Cycloaddition 1299 Benzyl Alcohol as an Alkylating Agent Using the Ruthenium-Catalyzed Borrowing Hydrogen Strategy 1309 Palladium-Catalyzed Cross-Coupling Using an Air-Stable Trimethylaluminum SourcePreparation of Ethyl 4-Methylbenzoate 1315 One-Pot Diazotization and Heck Reaction of Methyl Anthranilate: 2-(3-Oxopropyl)benzoic AcidMethyl Ester 1325 Diphenyldiazomethane 1329 Allylic Oxidation Catalyzed by Dirhodium(II) Tetrakis[ -caprolactamate] of tert-Butyldimethylsilyl-protected trans-Dehydroandrosterone 1335 2-Iodoxy-5-Methylbenzenesulfonic Acid-Catalyzed Selective Oxidation of 4-Bromobenzyl Alcohol to 4-Bromobenzaldehyde or 4-Bromobenzoic Acid with Oxone 1348 Enantioselective Oxidation of an Alkyl Aryl Sulfide: Synthesis of (S)-(-)-Methyl p-Bromophenyl Sulfoxide 1356 tert-Butyl tert-Butyldimethylsilylglyoxylate: A Useful Conjunctive Reagent 1363 Mild and Efficient One-Pot Curtius Rearrangement: Preparation of N-tert-Butyl Adamantanyl-1-yl-carbamate 1370 The Preparation of Amides by Copper-Mediated Oxidative Coupling of Aldehydes and Amine Hydrochloride Salts 1376 Efficient One-Pot Synthesis of Bis(4-tert-Butylphenyl)iodonium Triflate 1382 Synthesis of Et2SBr*SbCl5Br and Its Use in Biomimetic Brominative Polyene Cyclizations 1388 Stereoselective Synthesis of (E)-2,3-Dibromobut-2-enoic Acid 1402 Metal-Free One-Pot Oxidative Amination of Aromatic Aldehydes: Conversion of Benzaldehyde to N-Benzoyl Pyrrolidine 1407 A Practical And Scalable Synthesis of N-Halo Compounds: 2-Chloro-6,7-dimethoxy-1,2,3,4-tetrahydroisoquinoline 1413 Mild Conversion of Tertiary Amides to Aldehydes Using Cp2Zr(H)Cl (Schwartz's Reagent) 1420 Preparation of (3,5-Dimethoxy-1-phenyl-cyclohexa-2,5-dienyl)-acetonitrile through Birch Reductive Alkylation (BRA) 1429 Preparation of N-Isopropylidene-N'-2-Nitrobenzenesulfonyl Hydrazine (IPNBSH) and Its Use in Palladium-catalyzed Synthesis of Monoalkyl DiazenesSynthesis of 9-Allylanthracene 1437 Synthesis of Spiroborate Esters from 1,2-Aminoalcohols, Ethylene Glycol and Triisopropyl Borate: Preparation of (S)-1-(1,3,2-Dioxaborolan-2-yloxy)-3-methyl-1, 1-diphenylbutan-2-amine 1449 Catalytic Enantioselective Borane Reduction of Benzyl Oximes: Preparation of (S)-1-Pyridin-3-yl-ethylamine Bis-hydrochloride 1458 Reductive Radical Decarboxylation of Aliphatic Carboxylic Acids 1473

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詳細情報

• NII書誌ID(NCID): BA03809260
• ISBN:
  • 0471079863
  • 0471409537
  • 0471704709
  • 047105707X
  • 0471852430
  • 0471515590
  • 0471585653
  • 0471242489
  • 9780471445296
  • 9780470395486
  • 9781118117828
• LCCN: 21017747
• 出版国コード: us
• タイトル言語コード: eng
• 本文言語コード: eng
• 出版地: New York ; Chichester
• ページ数/冊数: v.
• 大きさ: 24 cm
• 分類:
  • NDC8 : 434